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Title: Unraveling the Molecular Weight Dependence of Interfacial Interactions in Poly(2-vinylpyridine)/Silica Nanocomposites

Abstract

In this paper, the structure and polymer–nanoparticle interactions among physically adsorbed poly(2-vinylpyridine) chains on the surface of silica nanoparticles (NPs) were systematically studied as a function of molecular weight (MW) by sum frequency generation (SFG) and X-ray photoelectron (XPS) spectroscopies. Analysis of XPS data identified hydrogen bonds between the polymer and NPs, while SFG evaluated the change in the number of free OH sites on the NP’s surface. Our data revealed that the hydrogen bonds and amount of the free ¯OH sites have a significant dependence on the polymer’s MW. Finally, these results provide clear experimental evidence that the interaction of physically adsorbed chains with nanoparticles is strongly MW dependent and aids in unraveling the microscopic mechanism responsible for the strong MW dependence of dynamics of the interfacial layer in polymer nanocomposites.

Authors:
 [1];  [2];  [3];  [3];  [4];  [3];  [1];  [1];  [3];  [5];  [6]
  1. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
  2. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
  5. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry. Dept. of Physics and Astronomy
  6. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
OSTI Identifier:
1422573
Alternate Identifier(s):
OSTI ID: 1347340
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ACS Macro Letters
Additional Journal Information:
Journal Volume: 6; Journal Issue: 2; Journal ID: ISSN 2161-1653
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats

Voylov, Dmitry N., Holt, Adam P., Doughty, Benjamin, Bocharova, Vera, Meyer, Harry M., Cheng, Shiwang, Martin, Halie, Dadmun, Mark, Kisliuk, Alexander, Sokolov, Alexei P., and Oak Ridge National Lab. Unraveling the Molecular Weight Dependence of Interfacial Interactions in Poly(2-vinylpyridine)/Silica Nanocomposites. United States: N. p., 2017. Web. doi:10.1021/acsmacrolett.6b00915.
Voylov, Dmitry N., Holt, Adam P., Doughty, Benjamin, Bocharova, Vera, Meyer, Harry M., Cheng, Shiwang, Martin, Halie, Dadmun, Mark, Kisliuk, Alexander, Sokolov, Alexei P., & Oak Ridge National Lab. Unraveling the Molecular Weight Dependence of Interfacial Interactions in Poly(2-vinylpyridine)/Silica Nanocomposites. United States. doi:10.1021/acsmacrolett.6b00915.
Voylov, Dmitry N., Holt, Adam P., Doughty, Benjamin, Bocharova, Vera, Meyer, Harry M., Cheng, Shiwang, Martin, Halie, Dadmun, Mark, Kisliuk, Alexander, Sokolov, Alexei P., and Oak Ridge National Lab. Tue . "Unraveling the Molecular Weight Dependence of Interfacial Interactions in Poly(2-vinylpyridine)/Silica Nanocomposites". United States. doi:10.1021/acsmacrolett.6b00915. https://www.osti.gov/servlets/purl/1422573.
@article{osti_1422573,
title = {Unraveling the Molecular Weight Dependence of Interfacial Interactions in Poly(2-vinylpyridine)/Silica Nanocomposites},
author = {Voylov, Dmitry N. and Holt, Adam P. and Doughty, Benjamin and Bocharova, Vera and Meyer, Harry M. and Cheng, Shiwang and Martin, Halie and Dadmun, Mark and Kisliuk, Alexander and Sokolov, Alexei P. and Oak Ridge National Lab.},
abstractNote = {In this paper, the structure and polymer–nanoparticle interactions among physically adsorbed poly(2-vinylpyridine) chains on the surface of silica nanoparticles (NPs) were systematically studied as a function of molecular weight (MW) by sum frequency generation (SFG) and X-ray photoelectron (XPS) spectroscopies. Analysis of XPS data identified hydrogen bonds between the polymer and NPs, while SFG evaluated the change in the number of free OH sites on the NP’s surface. Our data revealed that the hydrogen bonds and amount of the free ¯OH sites have a significant dependence on the polymer’s MW. Finally, these results provide clear experimental evidence that the interaction of physically adsorbed chains with nanoparticles is strongly MW dependent and aids in unraveling the microscopic mechanism responsible for the strong MW dependence of dynamics of the interfacial layer in polymer nanocomposites.},
doi = {10.1021/acsmacrolett.6b00915},
journal = {ACS Macro Letters},
number = 2,
volume = 6,
place = {United States},
year = {Tue Jan 10 00:00:00 EST 2017},
month = {Tue Jan 10 00:00:00 EST 2017}
}

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