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Title: Quantifying small changes in uranium oxidation states using XPS of a shallow core level

Abstract

Quantification of U(iv), U(v), and U(vi) in UO 2+xusing the 5d XPS.

Authors:
ORCiD logo [1];  [1];  [2];  [3];  [1];  [4];  [5];  [6]
  1. Pacific Northwest National Laboratory; Richland; USA
  2. Center for Advanced Radiation Sources; University of Chicago; Chicago; USA
  3. Center for Advanced Radiation Sources; University of Chicago; Chicago; USA; James Franck Institute
  4. Stanford Synchrotron Radiation Lightsource; Menlo Park; USA
  5. Consultant; Austin; USA
  6. Department of Chemistry; University of North Texas; Denton; USA
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)
OSTI Identifier:
1422324
Report Number(s):
PNNL-SA-128608
Journal ID: ISSN 1463-9076; PPCPFQ; 48555; 49380; KC0302060
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Volume: 19; Journal Issue: 45; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Environmental Molecular Sciences Laboratory

Citation Formats

Ilton, Eugene S., Du, Yingge, Stubbs, Joanne E., Eng, Peter J., Chaka, Anne M., Bargar, John R., Nelin, Connie J., and Bagus, Paul S. Quantifying small changes in uranium oxidation states using XPS of a shallow core level. United States: N. p., 2017. Web. doi:10.1039/c7cp05805e.
Ilton, Eugene S., Du, Yingge, Stubbs, Joanne E., Eng, Peter J., Chaka, Anne M., Bargar, John R., Nelin, Connie J., & Bagus, Paul S. Quantifying small changes in uranium oxidation states using XPS of a shallow core level. United States. doi:10.1039/c7cp05805e.
Ilton, Eugene S., Du, Yingge, Stubbs, Joanne E., Eng, Peter J., Chaka, Anne M., Bargar, John R., Nelin, Connie J., and Bagus, Paul S. Sun . "Quantifying small changes in uranium oxidation states using XPS of a shallow core level". United States. doi:10.1039/c7cp05805e.
@article{osti_1422324,
title = {Quantifying small changes in uranium oxidation states using XPS of a shallow core level},
author = {Ilton, Eugene S. and Du, Yingge and Stubbs, Joanne E. and Eng, Peter J. and Chaka, Anne M. and Bargar, John R. and Nelin, Connie J. and Bagus, Paul S.},
abstractNote = {Quantification of U(iv), U(v), and U(vi) in UO2+xusing the 5d XPS.},
doi = {10.1039/c7cp05805e},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
issn = {1463-9076},
number = 45,
volume = 19,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Measurement of the Auger parameter and Wagner plot for uranium compounds
journal, May 2013

  • Holliday, Kiel S.; Siekhaus, Wigbert; Nelson, Art J.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 31, Issue 3
  • DOI: 10.1116/1.4793477

Structure of Biogenic Uraninite Produced by Shewanella oneidensis Strain MR-1
journal, November 2008

  • Schofield, Eleanor J.; Veeramani, Harish; Sharp, Jonathan O.
  • Environmental Science & Technology, Vol. 42, Issue 21
  • DOI: 10.1021/es800579g

XPS spectra of the compounds , and
journal, May 2009

  • Liu, J. -H.; Van den Berghe, S.; Konstantinović, M. J.
  • Journal of Solid State Chemistry, Vol. 182, Issue 5
  • DOI: 10.1016/j.jssc.2009.02.007

Covalent bonding in heavy metal oxides
journal, April 2017

  • Bagus, Paul S.; Nelin, Connie J.; Hrovat, Dave A.
  • The Journal of Chemical Physics, Vol. 146, Issue 13
  • DOI: 10.1063/1.4979018

Probing Chemical Bonding in Uranium Dioxide by Means of High-Resolution X-ray Absorption Spectroscopy
journal, December 2016

  • Butorin, Sergei M.; Modin, Anders; Vegelius, Johan R.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 51
  • DOI: 10.1021/acs.jpcc.6b09335

XPS determination of uranium oxidation states: XPS determination of uranium oxidation states
journal, October 2011

  • Ilton, Eugene S.; Bagus, Paul S.
  • Surface and Interface Analysis, Vol. 43, Issue 13
  • DOI: 10.1002/sia.3836

Multiplet splitting for the XPS of heavy elements: Dependence on oxidation state
journal, January 2016


Pentavalent Uranium Oxide via Reduction of [UO 2 ] 2+ Under Hydrothermal Reaction Conditions
journal, November 2008

  • Belai, Nebebech; Frisch, Mark; Ilton, Eugene S.
  • Inorganic Chemistry, Vol. 47, Issue 21
  • DOI: 10.1021/ic801534m

Characteristics of chemical bonding of pentavalent uranium in La-doped UO 2
journal, January 2017

  • Butorin, Sergei M.; Kvashnina, Kristina O.; Prieur, Damien
  • Chemical Communications, Vol. 53, Issue 1
  • DOI: 10.1039/C6CC07684J

Many-body effects in the 4 f x-ray photoelectron spectroscopy of the U 5 + and U 4 + free ions
journal, May 2005


Atomic many-body effects in the 4f XPS of the U5+ and U4+ cations: part II: consequences of orbital relaxation
journal, July 2007


Theoretical modeling of the uranium 4f XPS for U(VI) and U(IV) oxides
journal, December 2013

  • Bagus, Paul S.; Nelin, Connie J.; Ilton, Eugene S.
  • The Journal of Chemical Physics, Vol. 139, Issue 24
  • DOI: 10.1063/1.4846135

Chemical State of Complex Uranium Oxides
journal, December 2013


Ligand field effects on the multiplet structure of the U4f XPS of UO2
journal, March 2008


Crystal-Field and Covalency Effects in Uranates: An X-ray Spectroscopic Study
journal, June 2016

  • Butorin, Sergei M.; Kvashnina, Kristina O.; Smith, Anna L.
  • Chemistry - A European Journal, Vol. 22, Issue 28
  • DOI: 10.1002/chem.201505091

Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV
journal, January 1976


Ligand-field effects for the 3 p photoelectron spectra of Cr 2 O 3
journal, May 2004


Uranium Redox Transformations after U(VI) Coprecipitation with Magnetite Nanoparticles
journal, February 2017

  • Pidchenko, Ivan; Kvashnina, Kristina O.; Yokosawa, Tadahiro
  • Environmental Science & Technology, Vol. 51, Issue 4
  • DOI: 10.1021/acs.est.6b04035

The interpretation of XPS spectra: Insights into materials properties
journal, June 2013


UO 2 Oxidative Corrosion by Nonclassical Diffusion
journal, June 2015


XPS Study of Ion Irradiated and Unirradiated UO 2 Thin Films
journal, July 2016


Uranium(V) Incorporation Mechanisms and Stability in Fe(II)/Fe(III) (oxyhydr)Oxides
journal, September 2017

  • Roberts, Hannah E.; Morris, Katherine; Law, Gareth T. W.
  • Environmental Science & Technology Letters, Vol. 4, Issue 10
  • DOI: 10.1021/acs.estlett.7b00348