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Title: Activation of the dimers and tetramers of metal amidinate atomic layer deposition precursors upon adsorption on silicon oxide surfaces

Journal Article · · Journal of Vacuum Science and Technology A
DOI:https://doi.org/10.1116/1.4971990· OSTI ID:1421264
 [1];  [2]; ; ; ; ;  [2];  [1]
  1. Department of Chemistry, University of California, Riverside, California 92521
  2. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716

Sponsoring Organization:
USDOE
Grant/Contract Number:
FG02-03ER46599; SC0001839
OSTI ID:
1421264
Journal Information:
Journal of Vacuum Science and Technology A, Journal Name: Journal of Vacuum Science and Technology A Vol. 35 Journal Issue: 1; ISSN 0734-2101
Publisher:
American Vacuum SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 13 works
Citation information provided by
Web of Science

References (47)

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Group 11 Amidinates and Guanidinates: Potential Precursors for Vapour Deposition journal June 2011
Calibration of computationally predicted N 1s binding energies by comparison with X-ray photoelectron spectroscopy measurements journal December 2009
X-ray-Initiated Metal-Promoted Thin Film Growth journal April 2012
Atomic Layer Deposition of Ruthenium Thin Films from an Amidinate Precursor journal December 2009
Surface Chemistry of Copper(I) Acetamidinates in Connection with Atomic Layer Deposition (ALD) Processes journal July 2011
In-situ FTIR Study of Atomic Layer Deposition (ALD) of Copper Metal Films journal September 2007
Application of neutral amidines and guanidines in coordination chemistry journal January 2006
Heteroleptic iminopyrrolidinates of aluminium journal January 2010
A new mixing of Hartree–Fock and local density‐functional theories journal January 1993
Chemical Vapor Deposition of Manganese Metallic Films on Silicon Oxide Substrates journal October 2012
Mechanisms of surface reactions in thin solid film chemical deposition processes journal December 2013
Synthesis and Characterization of Copper(I) Amidinates as Precursors for Atomic Layer Deposition (ALD) of Copper Metal journal March 2005
Chemical Vapor Deposition of Iron, Iron Carbides, and Iron Nitride Films from Amidinate Precursors journal January 2010
X-ray photoelectron spectroscopic characterization of ultra-thin silicon oxide films on a Mo(100) surface journal December 1992
Ultrathin CVD Cu Seed Layer Formation Using Copper Oxynitride Deposition and Room Temperature Remote Hydrogen Plasma Reduction journal January 2008
Mechanistic Details of Atomic Layer Deposition (ALD) Processes journal September 2007
History of atomic layer deposition and its relationship with the American Vacuum Society
  • Parsons, Gregory N.; Elam, Jeffrey W.; George, Steven M.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 31, Issue 5 https://doi.org/10.1116/1.4816548
journal September 2013
Thermal chemistry of copper acetamidinate atomic layer deposition precursors on silicon oxide surfaces studied by XPS journal August 2015
Uptake of Copper Acetamidinate ALD Precursors on Nickel Surfaces journal January 2010
Advances in the Coordination Chemistry of Amidinate and Guanidinate Ligands book January 2008
Atomic Layer Deposition of Aluminum Oxide Thin Films from a Heteroleptic, Amidinate-Containing Precursor journal November 2008
Amidinates, guanidinates and iminopyrrolidinates: Understanding precursor thermolysis to design a better ligand journal December 2013
The coordination chemistry of the amidine ligand journal July 1994
Synthesis and Characterization of Volatile, Thermally Stable, Reactive Transition Metal Amidinates journal December 2003
Copper Iminopyrrolidinates: A Study of Thermal and Surface Chemistry journal January 2013
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density journal January 1988
Volatility and High Thermal Stability in Tantalum Complexes Containing Imido, Amidinate, and Halide or Dialkylamide Ligands journal June 2009
Surface and Interface Processes during Atomic Layer Deposition of Copper on Silicon Oxide journal March 2010
Vapor Deposition of Ruthenium from an Amidinate Precursor journal January 2007
Thermal Decomposition of Copper Iminopyrrolidinate Atomic Layer Deposition (ALD) Precursors on Silicon Oxide Surfaces journal June 2016
Thermal chemistry of copper(I)- N,N ′ -di- sec -butylacetamidinate on Cu(110) single-crystal surfaces
  • Ma, Qiang; Zaera, Francisco; Gordon, Roy G.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 30, Issue 1 https://doi.org/10.1116/1.3658381
journal January 2012
Affinity Scale for the Interaction of Amino Acids with Silica Surfaces journal March 2009
Heteroleptic Guanidinate- and Amidinate-Based Complexes of Hafnium as New Precursors for MOCVD of HfO2 journal March 2010
Low-Temperature Atomic Layer Deposition of High Purity, Smooth, Low Resistivity Copper Films by Using Amidinate Precursor and Hydrogen Plasma journal August 2015
Atomic layer deposition of transition metals journal October 2003
Experimental and computational investigation of chemical vapor deposition of Cu from Cu amidinate journal September 2013
Atomic Layer Deposition: An Overview journal January 2010
Atomic Layer Deposition of Ultrathin Copper Metal Films from a Liquid Copper(I) Amidinate Precursor journal January 2006
A thermal desorption and x‐ray photoelectron spectroscopy study of the surface chemistry of iron pentacarbonyl journal May 1989
Applications of Field Ionization to Mass Spectrometry journal January 1955
In Situ Infrared Characterization during Atomic Layer Deposition of Lanthanum Oxide journal December 2008
A brief review of atomic layer deposition: from fundamentals to applications journal June 2014
Preventing thermolysis: precursor design for volatile copper compounds journal January 2012
Thermal Chemistry of Cu(I)-Iminopyrrolidinate and Cu(I)-Guanidinate Atomic Layer Deposition (ALD) Precursors on Ni(110) Single-Crystal Surfaces journal August 2013
Atomic Layer Deposition of Noble Metals and Their Oxides journal September 2013

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