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Title: Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity

Abstract

Water oxidation is catalysed in Nature by a redox cofactor embedded in a hydrogen-bonded network designed to orchestrate proton transfer throughout the challenging 4 electron reaction.

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Irvine, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1420343
Grant/Contract Number:  
SC0012150
Resource Type:
Journal Article: Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 10; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Khosrowabadi Kotyk, Juliet F., Hanna, Caitlin M., Combs, Rebecca L., Ziller, Joseph W., and Yang, Jenny Y. Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity. United Kingdom: N. p., 2018. Web. doi:10.1039/C7SC04960A.
Khosrowabadi Kotyk, Juliet F., Hanna, Caitlin M., Combs, Rebecca L., Ziller, Joseph W., & Yang, Jenny Y. Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity. United Kingdom. doi:10.1039/C7SC04960A.
Khosrowabadi Kotyk, Juliet F., Hanna, Caitlin M., Combs, Rebecca L., Ziller, Joseph W., and Yang, Jenny Y. Mon . "Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity". United Kingdom. doi:10.1039/C7SC04960A.
@article{osti_1420343,
title = {Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity},
author = {Khosrowabadi Kotyk, Juliet F. and Hanna, Caitlin M. and Combs, Rebecca L. and Ziller, Joseph W. and Yang, Jenny Y.},
abstractNote = {Water oxidation is catalysed in Nature by a redox cofactor embedded in a hydrogen-bonded network designed to orchestrate proton transfer throughout the challenging 4 electron reaction.},
doi = {10.1039/C7SC04960A},
journal = {Chemical Science},
number = 10,
volume = 9,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1039/C7SC04960A

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Works referenced in this record:

Electrocatalytic Water Oxidation Beginning with the Cobalt Polyoxometalate [Co4(H2O)2(PW9O34)2]10–: Identification of Heterogeneous CoOx as the Dominant Catalyst
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Concerted O atom-proton transfer in the O--O bond forming step in water oxidation
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