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Title: Effect of composition on the structure of lithium- and manganese-rich transition metal oxides

Abstract

In this work, we establish a definitive structural model for lithium- and manganese-rich transition metal oxides and demonstrate the effect of composition on their bulk as well as the surface structure.

Authors:
ORCiD logo [1];  [2];  [3];  [2];  [2];  [4];  [5];  [5];  [5]
  1. Energy Storage and Distributed Resources Division; Lawrence Berkeley National Laboratory; Berkeley; USA; SuperSTEM
  2. SuperSTEM; Daresbury; UK
  3. National Center for Electron Microscopy; Molecular Foundry; Lawrence Berkeley National Laboratory; Berkeley; USA
  4. Erich Schmid Institute of Materials Science; Austrian Academy of Sciences; Leoben; Austria
  5. Envia Systems; Newark; USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); Engineering and Physical Science Research Council (EFRC)
OSTI Identifier:
1420189
Grant/Contract Number:  
EE0006443; AC02-05CH11231
Resource Type:
Journal Article: Published Article
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 4; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Shukla, Alpesh Khushalchand, Ramasse, Quentin M., Ophus, Colin, Kepaptsoglou, Despoina Maria, Hage, Fredrik S., Gammer, Christoph, Bowling, Charles, Gallegos, Pedro Alejandro Hernández, and Venkatachalam, Subramanian. Effect of composition on the structure of lithium- and manganese-rich transition metal oxides. United Kingdom: N. p., 2018. Web. doi:10.1039/C7EE02443F.
Shukla, Alpesh Khushalchand, Ramasse, Quentin M., Ophus, Colin, Kepaptsoglou, Despoina Maria, Hage, Fredrik S., Gammer, Christoph, Bowling, Charles, Gallegos, Pedro Alejandro Hernández, & Venkatachalam, Subramanian. Effect of composition on the structure of lithium- and manganese-rich transition metal oxides. United Kingdom. doi:10.1039/C7EE02443F.
Shukla, Alpesh Khushalchand, Ramasse, Quentin M., Ophus, Colin, Kepaptsoglou, Despoina Maria, Hage, Fredrik S., Gammer, Christoph, Bowling, Charles, Gallegos, Pedro Alejandro Hernández, and Venkatachalam, Subramanian. Wed . "Effect of composition on the structure of lithium- and manganese-rich transition metal oxides". United Kingdom. doi:10.1039/C7EE02443F.
@article{osti_1420189,
title = {Effect of composition on the structure of lithium- and manganese-rich transition metal oxides},
author = {Shukla, Alpesh Khushalchand and Ramasse, Quentin M. and Ophus, Colin and Kepaptsoglou, Despoina Maria and Hage, Fredrik S. and Gammer, Christoph and Bowling, Charles and Gallegos, Pedro Alejandro Hernández and Venkatachalam, Subramanian},
abstractNote = {In this work, we establish a definitive structural model for lithium- and manganese-rich transition metal oxides and demonstrate the effect of composition on their bulk as well as the surface structure.},
doi = {10.1039/C7EE02443F},
journal = {Energy & Environmental Science},
number = 4,
volume = 11,
place = {United Kingdom},
year = {Wed Jan 10 00:00:00 EST 2018},
month = {Wed Jan 10 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1039/C7EE02443F

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

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Works referenced in this record:

Comments on the structural complexity of lithium-rich Li1+xM1−xO2 electrodes (M=Mn, Ni, Co) for lithium batteries
journal, September 2006

  • Thackeray, M. M.; Kang, S.-H.; Johnson, C. S.
  • Electrochemistry Communications, Vol. 8, Issue 9, p. 1531-1538
  • DOI: 10.1016/j.elecom.2006.06.030

Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment
journal, April 2009