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Title: Vertical changes of the Co and Mn speciation along a lateritic regolith developed on peridotites (New Caledonia)

Abstract

Because they can host significant amounts of Co, the Mn-oxides are commonly considered as the major Co-bearing mineral species in lateritic environments. However, little is known about the process leading to the formation and/or the weathering of these Co-rich Mn-oxides. This lack of knowledge is mainly due to the fact that Co concentrations are too low in primary silicates for classical speciation analysis. In this study, we investigated both Co and Mn speciation in a 64 m thick lateritic regolith developed upon peridotites in New Caledonia, by combining High Energy Resolution Fluorescence Detection X-ray absorption Near Edge Structure (HERFD-XANES) spectroscopy at the Co K-edge with classical XANES spectroscopy at the Mn K-edge, bulk chemistry (ICP) and mineralogy (XRD). The results obtained provide new insights into the evolution of Co and Mn speciation as a function of the weathering stages. Co and Mn primarily occur as Co(II) and Mn(II,III) in olivine and serpentine in the bedrock. During the first weathering stage, these forms of Co and Mn are progressively oxidized toward Co(III) and Mn(III,IV), which occur mainly as Co(III)-bearing Mn(III/IV)-oxides in the transition between the saprolite and the laterite. In the uppermost lateritic horizons, long-time weathering resulted in a strong leachingmore » of Co and Mn, and the remaining of these elements occurs as Co(II) and Mn(III) substituting for Fe(III) in goethite. Finally, this latter scavenging process emphasizes the importance of Fe-oxides for the long-term stabilization of Co and Mn in such deeply weathered laterites.« less

Authors:
 [1];  [2];  [3];  [4];  [3];  [5];  [6];  [3];  [3]
  1. Univ. Pierre et Marie Curie, Paris (France); Aix-Marseille Univ., and CNRS/IN2P3, Aix-en-Provence (France); Ecole Polytechnique Federale Lausanne (Switzlerland). Environmental Microbiology Lab. (EML)
  2. Univ. Pierre et Marie Curie, Paris (France); French Research Inst. for Development, Noumea (New Caledonia)
  3. Univ. Pierre et Marie Curie, Paris (France)
  4. Univ. Pierre et Marie Curie, Paris (France); SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
  5. Grenoble Observatory for Sciences of the Universe, Grenoble (France); European Synchrotron Radiation Facility (ESRF), Grenoble (France)
  6. Sincrotrone Trieste (ELETTRA), Trieste (Italy)
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1419928
Grant/Contract Number:
AC02-76SF00515
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Geochimica et Cosmochimica Acta
Additional Journal Information:
Journal Volume: 217; Journal Issue: C; Journal ID: ISSN 0016-7037
Publisher:
The Geochemical Society; The Meteoritical Society
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; Laterite; Cobalt; Manganese; Speciation; Weathering; X-ray absorption spectroscopy

Citation Formats

Dublet, Gabrielle, Juillot, Farid, Brest, Jessica, Noël, Vincent, Fritsch, Emmanuel, Proux, Olivier, Olivi, Luca, Ploquin, Florian, and Morin, Guillaume. Vertical changes of the Co and Mn speciation along a lateritic regolith developed on peridotites (New Caledonia). United States: N. p., 2017. Web. doi:10.1016/j.gca.2017.07.010.
Dublet, Gabrielle, Juillot, Farid, Brest, Jessica, Noël, Vincent, Fritsch, Emmanuel, Proux, Olivier, Olivi, Luca, Ploquin, Florian, & Morin, Guillaume. Vertical changes of the Co and Mn speciation along a lateritic regolith developed on peridotites (New Caledonia). United States. doi:10.1016/j.gca.2017.07.010.
Dublet, Gabrielle, Juillot, Farid, Brest, Jessica, Noël, Vincent, Fritsch, Emmanuel, Proux, Olivier, Olivi, Luca, Ploquin, Florian, and Morin, Guillaume. Fri . "Vertical changes of the Co and Mn speciation along a lateritic regolith developed on peridotites (New Caledonia)". United States. doi:10.1016/j.gca.2017.07.010.
@article{osti_1419928,
title = {Vertical changes of the Co and Mn speciation along a lateritic regolith developed on peridotites (New Caledonia)},
author = {Dublet, Gabrielle and Juillot, Farid and Brest, Jessica and Noël, Vincent and Fritsch, Emmanuel and Proux, Olivier and Olivi, Luca and Ploquin, Florian and Morin, Guillaume},
abstractNote = {Because they can host significant amounts of Co, the Mn-oxides are commonly considered as the major Co-bearing mineral species in lateritic environments. However, little is known about the process leading to the formation and/or the weathering of these Co-rich Mn-oxides. This lack of knowledge is mainly due to the fact that Co concentrations are too low in primary silicates for classical speciation analysis. In this study, we investigated both Co and Mn speciation in a 64 m thick lateritic regolith developed upon peridotites in New Caledonia, by combining High Energy Resolution Fluorescence Detection X-ray absorption Near Edge Structure (HERFD-XANES) spectroscopy at the Co K-edge with classical XANES spectroscopy at the Mn K-edge, bulk chemistry (ICP) and mineralogy (XRD). The results obtained provide new insights into the evolution of Co and Mn speciation as a function of the weathering stages. Co and Mn primarily occur as Co(II) and Mn(II,III) in olivine and serpentine in the bedrock. During the first weathering stage, these forms of Co and Mn are progressively oxidized toward Co(III) and Mn(III,IV), which occur mainly as Co(III)-bearing Mn(III/IV)-oxides in the transition between the saprolite and the laterite. In the uppermost lateritic horizons, long-time weathering resulted in a strong leaching of Co and Mn, and the remaining of these elements occurs as Co(II) and Mn(III) substituting for Fe(III) in goethite. Finally, this latter scavenging process emphasizes the importance of Fe-oxides for the long-term stabilization of Co and Mn in such deeply weathered laterites.},
doi = {10.1016/j.gca.2017.07.010},
journal = {Geochimica et Cosmochimica Acta},
number = C,
volume = 217,
place = {United States},
year = {Fri Jul 21 00:00:00 EDT 2017},
month = {Fri Jul 21 00:00:00 EDT 2017}
}

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