Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries

Chi, Xiaowei; Liang, Yanliang; Hao, Fang; Zhang, Ye; Whiteley, Justin; Dong, Hui; Hu, Pu; Lee, Sehee; Yao, Yan

doi:10.1002/ange.201712895

Title: Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All‐Solid‐State Sodium Batteries

Journal Article · Thu Feb 08 00:00:00 EST 2018 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201712895· OSTI ID:1419899

Chi, Xiaowei ^[1]; Liang, Yanliang ^[1]; Hao, Fang ^[1]; Zhang, Ye ^[1]; Whiteley, Justin ^[2]; Dong, Hui ^[1]; Hu, Pu ^[1]; Lee, Sehee ^[2];

^[1]

Department of Electrical and Computer Engineering and Materials Science and Engineering Program University of Houston Houston TX 77204 USA
Department of Mechanical Engineering University of Colorado at Boulder Boulder CO 80309 USA

Abstract All‐solid‐state sodium batteries (ASSSBs) with nonflammable electrolytes and ubiquitous sodium resource are a promising solution to the safety and cost concerns for lithium‐ion batteries. However, the intrinsic mismatch between low anodic decomposition potential of superionic sulfide electrolytes and high operating potentials of sodium‐ion cathodes leads to a volatile cathode–electrolyte interface and undesirable cell performance. Here we report a high‐capacity organic cathode, Na ₄ C ₆ O ₆ , that is chemically and electrochemically compatible with sulfide electrolytes. A bulk‐type ASSSB shows high specific capacity (184 mAh g ⁻¹ ) and one of the highest specific energies (395 Wh kg ⁻¹ ) among intercalation compound‐based ASSSBs. The capacity retentions of 76 % after 100 cycles at 0.1 C and 70 % after 400 cycles at 0.2 C represent the record stability for ASSSBs. Additionally, Na ₄ C ₆ O ₆ functions as a capable anode material, enabling a symmetric all‐organic ASSSB with Na ₄ C ₆ O ₆ as both cathode and anode materials.

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Sponsoring Organization:: USDOE

OSTI ID:: 1419899

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 130 Journal Issue: 10; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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