Crystal Structure Evolution and Notable Thermal Expansion in Hybrid Perovskites Formamidinium Tin Iodide and Formamidinium Lead Bromide

Schueller, Emily C.; Laurita, Geneva; Fabini, Douglas H.; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.; Seshadri, Ram

doi:10.1021/acs.inorgchem.7b02576

Title: Crystal Structure Evolution and Notable Thermal Expansion in Hybrid Perovskites Formamidinium Tin Iodide and Formamidinium Lead Bromide

Journal Article · Fri Oct 13 00:00:00 EDT 2017 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.7b02576· OSTI ID:1419872

Schueller, Emily C. ^[1];

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Materials Department and Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States
Department of Chemistry and Biochemistry, Bates College, Lewiston, Maine 04240, United States
Department of Chemistry and Argonne-Northwestern Solar Energy Research Center, Northwestern University, Evanston, Illinois 60208, United States
Materials Department and Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States; Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 1419872

Journal Information:: Inorganic Chemistry, Vol. 57, Issue 2; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: ENGLISH

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Quasicubic model for metal halide perovskite nanocrystals Sercel, Peter C.; Lyons, John L.; Bernstein, Noam The Journal of Chemical Physics, Vol. 151, Issue 23 https://doi.org/10.1063/1.5127528	journal	December 2019
Interplay of Structural and Optoelectronic Properties in Formamidinium Mixed Tin-Lead Triiodide Perovskites Parrott, Elizabeth S.; Green, Thomas; Milot, Rebecca L. Advanced Functional Materials, Vol. 28, Issue 33 https://doi.org/10.1002/adfm.201802803	journal	June 2018
Lead-free hybrid ferroelectric material based on formamidine: [NH ₂ CHNH ₂ ] ₃ Bi ₂ I ₉ Szklarz, Przemysław; Gągor, Anna; Jakubas, Ryszard Journal of Materials Chemistry C, Vol. 7, Issue 10 https://doi.org/10.1039/c8tc06458j	journal	January 2019
The phase diagram of a mixed halide (Br, I) hybrid perovskite obtained by synchrotron X-ray diffraction Lehmann, Frederike; Franz, Alexandra; Többens, Daniel M. RSC Advances, Vol. 9, Issue 20 https://doi.org/10.1039/c8ra09398a	journal	January 2019
Robust Tin-Based Perovskite Solar Cells with Hybrid Organic Cations to Attain Efficiency Approaching 10% Jokar, Efat; Chien, Cheng-Hsun; Tsai, Cheng-Min Advanced Materials, Vol. 31, Issue 2 https://doi.org/10.1002/adma.201804835	journal	November 2018
The Effects of Doping Density and Temperature on the Optoelectronic Properties of Formamidinium Tin Triiodide Thin Films Milot, Rebecca L.; Klug, Matthew T.; Davies, Christopher L. Advanced Materials, Vol. 30, Issue 44 https://doi.org/10.1002/adma.201804506	journal	September 2018
The ground exciton state of formamidinium lead bromide perovskite nanocrystals is a singlet dark state Tamarat, Philippe; Bodnarchuk, Maryna I.; Trebbia, Jean-Baptiste Nature Materials, Vol. 18, Issue 7 https://doi.org/10.1038/s41563-019-0364-x	journal	May 2019
Enhancing exciton binding energy and photoluminescence of formamidinium lead bromide by reducing its dimensions to 2D nanoplates for producing efficient light emitting diodes Li, Feiming; Yang, Lan; Cai, Zhixiong Nanoscale, Vol. 10, Issue 44 https://doi.org/10.1039/c8nr04986f	journal	January 2018
Tracking Structural Phase Transitions in Lead‐Halide Perovskites by Means of Thermal Expansion Keshavarz, Masoumeh; Ottesen, Martin; Wiedmann, Steffen Advanced Materials https://doi.org/10.1002/adma.201900521	journal	April 2019
Stable Cesium Formamidinium Lead Halide Perovskites: A Comparison of Photophysics and Phase Purity in Thin Films and Single Crystals Groeneveld, Bart G. H. M.; Adjokatse, Sampson; Nazarenko, Olga Energy Technology, Vol. 8, Issue 4 https://doi.org/10.1002/ente.201901041	journal	April 2020
The distinctive phase stability and defect physics in CsPbI ₂ Br perovskite Chen, Yuxuan; Shi, Tingting; Liu, Pengyi Journal of Materials Chemistry A, Vol. 7, Issue 35 https://doi.org/10.1039/c9ta04839a	journal	January 2019
Tracking Structural Phase Transitions in Lead‐Halide Perovskites by Means of Thermal Expansion Keshavarz, Masoumeh; Ottesen, Martin; Wiedmann, Steffen Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-04498	text	January 2019
Stable Cesium Formamidinium Lead Halide Perovskites: A Comparison of Photophysics and Phase Purity in Thin Films and Single Crystals Groeneveld, Bart G. H. M.; Adjokatse, Sampson; Nazarenko, Olga ETH Zurich https://doi.org/10.3929/ethz-b-000380421	text	January 2020
Exploration of Near-Infrared-Emissive Colloidal Multinary Lead Halide Perovskite Nanocrystals Using an Automated Microfluidic Platform Lignos, Ioannis; Morad, Viktoriia; Shynkarenko, Yevhen ACS Nano, Vol. 12, Issue 6 https://doi.org/10.1021/acsnano.8b01122	journal	May 2018
Direct evidence of weakly dispersed and strongly anharmonic optical phonons in hybrid perovskites Ferreira, A. C.; Paofai, S.; Létoublon, A. arXiv https://doi.org/10.48550/arxiv.2001.05445	text	January 2020

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Title: Crystal Structure Evolution and Notable Thermal Expansion in Hybrid Perovskites Formamidinium Tin Iodide and Formamidinium Lead Bromide

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