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Title: Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand

Abstract

The sterically encumbered NacNac ligand, [HC(MeCNAr) 2] (Ar = 2,6- i-Pr 2C 6H 3), was investigated as a platform for supporting Lu-halide complexes, sought for their potential capability of being further converted into hydrocarbyl derivatives via metathetical chemistries with alkali metal alkyls. As a result, these substituted analogs were targeted as potentially viable candidates for alkane elimination chemistries, with an eye towards the formation of an isolable Lu-alkylidene fragment.

Authors:
 [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Laboratory Directed Research and Development (LDRD) Program
OSTI Identifier:
1419763
Report Number(s):
LA-UR-18-20120
Journal ID: ISSN 0022-328X
Grant/Contract Number:  
AC52-06NA25396
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Organometallic Chemistry
Additional Journal Information:
Journal Volume: 857; Journal ID: ISSN 0022-328X
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Inorganic and Physical Chemistry; Organic Chemistry

Citation Formats

Beattie, Ross J., Sutton, Andrew D., Scott, Brian L., Clark, David L., Kiplinger, Jaqueline L., and Gordon, John Cameron. Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand. United States: N. p., 2018. Web. doi:10.1016/j.jorganchem.2017.12.032.
Beattie, Ross J., Sutton, Andrew D., Scott, Brian L., Clark, David L., Kiplinger, Jaqueline L., & Gordon, John Cameron. Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand. United States. doi:10.1016/j.jorganchem.2017.12.032.
Beattie, Ross J., Sutton, Andrew D., Scott, Brian L., Clark, David L., Kiplinger, Jaqueline L., and Gordon, John Cameron. Sat . "Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand". United States. doi:10.1016/j.jorganchem.2017.12.032.
@article{osti_1419763,
title = {Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand},
author = {Beattie, Ross J. and Sutton, Andrew D. and Scott, Brian L. and Clark, David L. and Kiplinger, Jaqueline L. and Gordon, John Cameron},
abstractNote = {The sterically encumbered NacNac ligand, [HC(MeCNAr)2]– (Ar = 2,6-i-Pr2C6H3), was investigated as a platform for supporting Lu-halide complexes, sought for their potential capability of being further converted into hydrocarbyl derivatives via metathetical chemistries with alkali metal alkyls. As a result, these substituted analogs were targeted as potentially viable candidates for alkane elimination chemistries, with an eye towards the formation of an isolable Lu-alkylidene fragment.},
doi = {10.1016/j.jorganchem.2017.12.032},
journal = {Journal of Organometallic Chemistry},
number = ,
volume = 857,
place = {United States},
year = {Sat Jan 06 00:00:00 EST 2018},
month = {Sat Jan 06 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on January 6, 2019
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