Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand

Beattie, Ross J.; Sutton, Andrew D.; Scott, Brian L.; Clark, David L.; Kiplinger, Jaqueline L.; Gordon, John Cameron

doi:10.1016/j.jorganchem.2017.12.032

Title: Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand

Journal Article · Sat Jan 06 00:00:00 EST 2018 · Journal of Organometallic Chemistry

DOI:https://doi.org/10.1016/j.jorganchem.2017.12.032· OSTI ID:1419763

Beattie, Ross J. ^[1]; Sutton, Andrew D. ^[1]; Scott, Brian L. ^[1]; Clark, David L. ^[1]; Kiplinger, Jaqueline L. ^[1];

^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

The sterically encumbered NacNac ligand, [HC(MeCNAr)₂]^– (Ar = 2,6-i-Pr₂C₆H₃), was investigated as a platform for supporting Lu-halide complexes, sought for their potential capability of being further converted into hydrocarbyl derivatives via metathetical chemistries with alkali metal alkyls. As a result, these substituted analogs were targeted as potentially viable candidates for alkane elimination chemistries, with an eye towards the formation of an isolable Lu-alkylidene fragment.

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Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1419763

Alternate ID(s):: OSTI ID: 1548905

Report Number(s):: LA-UR-18-20120

Journal Information:: Journal of Organometallic Chemistry, Vol. 857; ISSN 0022-328X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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Cited By (1)

β-Diketiminato Rare-Earth Metal Complexes: The Influence of Monoatomic Substituents in the N-aryl Moieties on Structures and Properties: β-Diketiminato Rare-Earth Metal Complexes: The Influence of Monoatomic Substituents in the N-aryl Moieties on Structures and Properties Zhuang, Qingxiang; Mou, Zehuai; Gu, Jialu Zeitschrift für anorganische und allgemeine Chemie, Vol. 646, Issue 2 https://doi.org/10.1002/zaac.201900280	journal	January 2020

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