Quantum thermodynamics from the nonequilibrium dynamics of open systems: Energy, heat capacity, and the third law
Abstract
In a series of papers, we intend to take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations, and the laws of thermodynamics become well defined and viable for quantum manybody systems. We first describe how an opensystem nonequilibrium dynamics (ONEq) approach is different from the closed combined system + environment in a global thermal state (CGTs) setup. Only after the open system equilibrates will it be amenable to conventional thermodynamics descriptions, thus quantum thermodynamics (QTD) comes at the end rather than assumed in the beginning. The linkage between the two comes from the reduced density matrix of ONEq in that stage having the same form as that of the system in the CGTs. We see the opensystem approach having the advantage of dealing with nonequilibrium processes as many experiments in the near future will call for. Because it spells out the conditions of QTD's existence, it can also aid us in addressing the basic issues in quantum thermodynamics from first principles in a systematic way. We then study one broad class of open quantum systems where the full nonequilibrium dynamics can be solved exactly, that of the quantummore »
 Authors:
 Fudan Univ., Shanghai (China)
 National Cheng Kung Univ., Tainan (Taiwan)
 Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
 Fudan Univ., Shanghai (China); Univ. of Maryland, College Park, MD (United States)
 Publication Date:
 Research Org.:
 Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
 Sponsoring Org.:
 USDOE
 OSTI Identifier:
 1419751
 Report Number(s):
 LAUR1721711
Journal ID: ISSN 24700045; PLEEE8
 Grant/Contract Number:
 AC5206NA25396
 Resource Type:
 Journal Article: Accepted Manuscript
 Journal Name:
 Physical Review E
 Additional Journal Information:
 Journal Volume: 97; Journal Issue: 1; Journal ID: ISSN 24700045
 Publisher:
 American Physical Society (APS)
 Country of Publication:
 United States
 Language:
 English
 Subject:
 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; Mathematics
Citation Formats
Hsiang, Jen Tsung, Chou, Chung Hsien, Subasi, Yigit, and Hu, Bei Lok. Quantum thermodynamics from the nonequilibrium dynamics of open systems: Energy, heat capacity, and the third law. United States: N. p., 2018.
Web. doi:10.1103/PhysRevE.97.012135.
Hsiang, Jen Tsung, Chou, Chung Hsien, Subasi, Yigit, & Hu, Bei Lok. Quantum thermodynamics from the nonequilibrium dynamics of open systems: Energy, heat capacity, and the third law. United States. doi:10.1103/PhysRevE.97.012135.
Hsiang, Jen Tsung, Chou, Chung Hsien, Subasi, Yigit, and Hu, Bei Lok. 2018.
"Quantum thermodynamics from the nonequilibrium dynamics of open systems: Energy, heat capacity, and the third law". United States.
doi:10.1103/PhysRevE.97.012135.
@article{osti_1419751,
title = {Quantum thermodynamics from the nonequilibrium dynamics of open systems: Energy, heat capacity, and the third law},
author = {Hsiang, Jen Tsung and Chou, Chung Hsien and Subasi, Yigit and Hu, Bei Lok},
abstractNote = {In a series of papers, we intend to take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations, and the laws of thermodynamics become well defined and viable for quantum manybody systems. We first describe how an opensystem nonequilibrium dynamics (ONEq) approach is different from the closed combined system + environment in a global thermal state (CGTs) setup. Only after the open system equilibrates will it be amenable to conventional thermodynamics descriptions, thus quantum thermodynamics (QTD) comes at the end rather than assumed in the beginning. The linkage between the two comes from the reduced density matrix of ONEq in that stage having the same form as that of the system in the CGTs. We see the opensystem approach having the advantage of dealing with nonequilibrium processes as many experiments in the near future will call for. Because it spells out the conditions of QTD's existence, it can also aid us in addressing the basic issues in quantum thermodynamics from first principles in a systematic way. We then study one broad class of open quantum systems where the full nonequilibrium dynamics can be solved exactly, that of the quantum Brownian motion of N strongly coupled harmonic oscillators, interacting strongly with a scalarfield environment. In this paper, we focus on the internal energy, heat capacity, and the third law. We show for this class of physical models, amongst other findings, the extensive property of the internal energy, the positivity of the heat capacity, and the validity of the third law from the perspective of the behavior of the heat capacity toward zero temperature. These conclusions obtained from exact solutions and quantitative analysis clearly disprove claims of negative specific heat in such systems and dispel allegations that in such systems the validity of the third law of thermodynamics relies on quantum entanglement. They are conceptually and factually unrelated issues. As a result, entropy and entanglement will be the main theme of our second paper on this subject matter.},
doi = {10.1103/PhysRevE.97.012135},
journal = {Physical Review E},
number = 1,
volume = 97,
place = {United States},
year = 2018,
month = 1
}

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