Development and Elucidation of Superior Turnover Rates and Selectivity of Supported Molecular Catalysts

Ye, Rong; Liu, Wen‐Chi; Han, Hui‐Ling; Somorjai, Gabor A.

doi:10.1002/cctc.201701546

Title: Development and Elucidation of Superior Turnover Rates and Selectivity of Supported Molecular Catalysts

Journal Article · Tue Feb 06 00:00:00 EST 2018 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.201701546· OSTI ID:1419695

^[1]; Liu, Wen‐Chi ^[1]; Han, Hui‐Ling ^[2];

^[3]

Department of Chemistry University of California, Berkeley, Kavli Energy Nanosciences Institute at Berkeley Berkeley CA 94720 USA, Chemical Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA
Department of Chemistry University of California, Berkeley, Kavli Energy Nanosciences Institute at Berkeley Berkeley CA 94720 USA, Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA
Department of Chemistry University of California, Berkeley, Kavli Energy Nanosciences Institute at Berkeley Berkeley CA 94720 USA, Chemical Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA, Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA

Abstract Supported molecular catalysts consist of nanomaterials immobilized on a solid support. Important factors that control catalyst properties (reactivity, product selectivity, and stability) include the structure and compositions of both nanomaterials and supports. This review focuses on recent studies of supported molecular catalysts with controlled activity and selectivity in our group. We will first introduce the development of previously unexplored supported molecular catalysts. We will demonstrate the controllable selectivity of catalysts based on acidified mesoporous silica, metal‐organic frameworks (MOFs), hydrogen‐activated tungsten oxides, and noble metal doped Mn _x O _y /Na ₂ WO ₄ catalyst supported on mesoporous silica. We will then discuss advanced characterization techniques under reaction conditions, which offer mechanistic explanations of activity and selectivity of supported molecular catalysts. The applications of chemical transient kinetics (CTK) analysis, ambient pressure X‐ray photoelectron spectroscopy (APXPS), and sum‐frequency generation vibrational spectroscopy (SFG‐VS) are discussed. Next, we will describe new insights into catalysis at the nanoparticle‐support interfaces, which are catalytic environments unique to supported molecular catalysts. Examples include reactions at oxide‐metal interfaces and alcohol oxidation reactions at solid–gas and solid–liquid interfaces. Lastly, we will discuss heterogenized homogeneous catalysts and heterogenized enzyme catalysts as future directions of supported molecular catalysts.

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Sponsoring Organization:: USDOE

OSTI ID:: 1419695

Journal Information:: ChemCatChem, Journal Name: ChemCatChem Vol. 10 Journal Issue: 8; ISSN 1867-3880

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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References (71)

Trends in the catalytic reduction of CO2 by hydrogen over supported monometallic and bimetallic catalysts Porosoff, Marc D.; Chen, Jingguang G. Journal of Catalysis, Vol. 301 https://doi.org/10.1016/j.jcat.2013.01.022	journal	May 2013
Metal Nanoparticles Catalyzed Selective Carbon–Carbon Bond Activation in the Liquid Phase Ye, Rong; Yuan, Bing; Zhao, Jie Journal of the American Chemical Society, Vol. 138, Issue 27 https://doi.org/10.1021/jacs.6b03977	journal	June 2016
Heterogeneities of individual catalyst particles in space and time as monitored by spectroscopy Buurmans, Inge L. C.; Weckhuysen, Bert M. Nature Chemistry, Vol. 4, Issue 11 https://doi.org/10.1038/nchem.1478	journal	October 2012
In Situ Microscopy and Spectroscopy Applied to Surfaces at Work Han, Hui-Ling; Melaet, Gérôme; Alayoglu, Selim ChemCatChem, Vol. 7, Issue 22 https://doi.org/10.1002/cctc.201500642	journal	October 2015
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank Nature Chemistry, Vol. 6, Issue 4 https://doi.org/10.1038/nchem.1873	journal	March 2014
Molecular catalysis science: Perspective on unifying the fields of catalysis Ye, Rong; Hurlburt, Tyler J.; Sabyrov, Kairat Proceedings of the National Academy of Sciences, Vol. 113, Issue 19 https://doi.org/10.1073/pnas.1601766113	journal	April 2016
Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures Christopher, Phillip; Xin, Hongliang; Linic, Suljo Nature Chemistry, Vol. 3, Issue 6 https://doi.org/10.1038/nchem.1032	journal	May 2011
On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review Phan, Nam T. S.; Van Der Sluys, Matthew; Jones, Christopher W. Advanced Synthesis & Catalysis, Vol. 348, Issue 6 https://doi.org/10.1002/adsc.200505473	journal	April 2006
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts Matsubu, John C.; Zhang, Shuyi; DeRita, Leo Nature Chemistry, Vol. 9, Issue 2 https://doi.org/10.1038/nchem.2607	journal	September 2016
Evidence of Structure Sensitivity in the Fischer-Tropsch Reaction on Model Cobalt Nanoparticles by Time-Resolved Chemical Transient Kinetics Ralston, Walter T.; Melaet, Gérôme; Saephan, Tommy Angewandte Chemie International Edition, Vol. 56, Issue 26 https://doi.org/10.1002/anie.201701186	journal	May 2017
The selective oxidation of n-butanol to butyraldehyde by oxygen using stable Pt-based nanoparticulate catalysts: an efficient route for upgrading aqueous biobutanol Gandarias, Inaki; Nowicka, Ewa; May, Blake J. Catalysis Science & Technology, Vol. 6, Issue 12 https://doi.org/10.1039/C5CY01726B	journal	January 2016
Effect of Heteroatom Concentration in SSZ-13 on the Methanol-to-Olefins Reaction Deimund, Mark A.; Harrison, Luke; Lunn, Jonathan D. ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b01450	journal	December 2015
Metal Nanocrystals Embedded in Single Nanocrystals of MOFs Give Unusual Selectivity as Heterogeneous Catalysts Na, Kyungsu; Choi, Kyung Min; Yaghi, Omar M. Nano Letters, Vol. 14, Issue 10 https://doi.org/10.1021/nl503007h	journal	September 2014
Activation of Tungsten Oxide for Propane Dehydrogenation and Its High Catalytic Activity and Selectivity Yun, Yongju; Araujo, Joyce R.; Melaet, Gerome Catalysis Letters, Vol. 147, Issue 3 https://doi.org/10.1007/s10562-016-1915-2	journal	February 2017
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300361m	journal	April 2013
Heterogeneously Catalyzed Alcohol Oxidation for the Fine Chemical Industry Ciriminna, Rosaria; Pandarus, Valerica; Béland, Francois Organic Process Research & Development, Vol. 19, Issue 11 https://doi.org/10.1021/acs.oprd.5b00204	journal	August 2014
Oxidative coupling of methane (OCM): Effect of noble metal (M = Pt, Ir, Rh) doping on the performance of mesoporous silica MCF-17 supported MnxOy-Na2WO4 catalysts Liu, Wen-Chi; Ralston, Walter T.; Melaet, Gérôme Applied Catalysis A: General, Vol. 545 https://doi.org/10.1016/j.apcata.2017.07.017	journal	September 2017
Gas management and multiphase flow in direct alcohol fuel cells Gauthier, Eric; Benziger, Jay B. Electrochimica Acta, Vol. 128 https://doi.org/10.1016/j.electacta.2013.09.047	journal	May 2014
Polyelemental nanoparticle libraries Chen, P. -C.; Liu, X.; Hedrick, J. L. Science, Vol. 352, Issue 6293 https://doi.org/10.1126/science.aaf8402	journal	June 2016
Mesoporous Aluminosilicate Catalysts for the Selective Isomerization of n -Hexane: The Roles of Surface Acidity and Platinum Metal Musselwhite, Nathan; Na, Kyungsu; Sabyrov, Kairat Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b04808	journal	August 2015
Enantioselective catalysis with homochiral metal–organic frameworks Ma, Liqing; Abney, Carter; Lin, Wenbin Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256 https://doi.org/10.1039/b807083k	journal	January 2009
Copper Nanocrystals Encapsulated in Zr-based Metal–Organic Frameworks for Highly Selective CO ₂ Hydrogenation to Methanol Rungtaweevoranit, Bunyarat; Baek, Jayeon; Araujo, Joyce R. Nano Letters, Vol. 16, Issue 12 https://doi.org/10.1021/acs.nanolett.6b03637	journal	November 2016
Evidence of Structure Sensitivity in the Fischer-Tropsch Reaction on Model Cobalt Nanoparticles by Time-Resolved Chemical Transient Kinetics Ralston, Walter T.; Melaet, Gérôme; Saephan, Tommy Angewandte Chemie, Vol. 129, Issue 26 https://doi.org/10.1002/ange.201701186	journal	May 2017
Iron single crystals as ammonia synthesis catalysts: Effect of surface structure on catalyst activity Spencer, N. Journal of Catalysis, Vol. 74, Issue 1 https://doi.org/10.1016/0021-9517(82)90016-1	journal	March 1982
Dramatically Different Kinetics and Mechanism at Solid/Liquid and Solid/Gas Interfaces for Catalytic Isopropanol Oxidation over Size-Controlled Platinum Nanoparticles Wang, Hailiang; Sapi, Andras; Thompson, Christopher M. Journal of the American Chemical Society, Vol. 136, Issue 29 https://doi.org/10.1021/ja505641r	journal	July 2014
The Nature of the Molybdenum Surface in Iron Molybdate. The Active Phase in Selective Methanol Oxidation Brookes, Catherine; Wells, Peter P.; Dimitratos, Nikolaos The Journal of Physical Chemistry C, Vol. 118, Issue 45 https://doi.org/10.1021/jp5081753	journal	October 2014
Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water Cortright, R. D.; Davda, R. R.; Dumesic, J. A. Nature, Vol. 418, Issue 6901 https://doi.org/10.1038/nature01009	journal	August 2002
Insight into the Effect of Water on the Methanol-to-Olefins Conversion in H-SAPO-34 from Molecular Simulations and in Situ Microspectroscopy De Wispelaere, Kristof; Wondergem, Caterina S.; Ensing, Bernd ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.5b02139	journal	February 2016
Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang Nature Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/nchem.468	journal	November 2009
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO ₂ reduction in water Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao Science, Vol. 349, Issue 6253 https://doi.org/10.1126/science.aac8343	journal	August 2015
Dependence of Gas-Phase Crotonaldehyde Hydrogenation Selectivity and Activity on the Size of Pt Nanoparticles (1.7–7.1 nm) Supported on SBA-15 Grass, Michael E.; Rioux, Robert M.; Somorjai, Gabor A. Catalysis Letters, Vol. 128, Issue 1-2 https://doi.org/10.1007/s10562-008-9754-4	journal	November 2008
Site-Selective Oxidative Coupling Reactions for the Attachment of Enzymes to Glass Surfaces through DNA-Directed Immobilization Palla, Kanwal S.; Hurlburt, Tyler J.; Buyanin, Alexander M. Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b11716	journal	January 2017
Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? Xia, Younan; Xiong, Yujie; Lim, Byungkwon Angewandte Chemie International Edition, Vol. 48, Issue 1, p. 60-103 https://doi.org/10.1002/anie.200802248	journal	December 2008
Selective conversion of syngas to light olefins Jiao, F.; Li, J.; Pan, X. Science, Vol. 351, Issue 6277 https://doi.org/10.1126/science.aaf1835	journal	March 2016
Chemical Environment Control and Enhanced Catalytic Performance of Platinum Nanoparticles Embedded in Nanocrystalline Metal–Organic Frameworks Choi, Kyung Min; Na, Kyungsu; Somorjai, Gabor A. Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b03540	journal	June 2015
Effect of Acidic Properties of Mesoporous Zeolites Supporting Pt Nanoparticles on Hydrogenative Conversion of Methylcyclopentane Na, Kyungsu; Alayoglu, Selim; Ye, Rong Journal of the American Chemical Society, Vol. 136, Issue 49 https://doi.org/10.1021/ja509273h	journal	November 2014
Industrielle Anwendungen von Goldkatalysatoren Ciriminna, Rosaria; Falletta, Ermelinda; Della Pina, Cristina Angewandte Chemie, Vol. 128, Issue 46 https://doi.org/10.1002/ange.201604656	journal	September 2016
Reactivity of a Carbon-Supported Single-Site Molybdenum Dioxo Catalyst for Biodiesel Synthesis Mouat, Aidan R.; Lohr, Tracy L.; Wegener, Evan C. ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b01717	journal	September 2016
Silver and oxide hybrids of catalysts during formaldehyde production Kralj, Anita Kovač Energy, Vol. 35, Issue 6 https://doi.org/10.1016/j.energy.2010.02.052	journal	June 2010
Metal-support effects on the intramolecular selectivity of crotonaldehyde hydrogenation over platinum Vannice, M. Journal of Catalysis, Vol. 115, Issue 1 https://doi.org/10.1016/0021-9517(89)90007-9	journal	January 1989
Insights into the Mechanism of Tandem Alkene Hydroformylation over a Nanostructured Catalyst with Multiple Interfaces Su, Ji; Xie, Chenlu; Chen, Chen Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b03915	journal	September 2016
In Situ Spectroscopic Investigation into the Active Sites for Crotonaldehyde Hydrogenation at the Pt Nanoparticle–Co ₃ O ₄ Interface Kennedy, Griffin; Melaet, Gérôme; Han, Hui-Ling ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b01640	journal	September 2016
Hydrogen Transfer versus Methylation: On the Genesis of Aromatics Formation in the Methanol-To-Hydrocarbons Reaction over H-ZSM-5 Martínez-Espín, Juan S.; De Wispelaere, Kristof; Janssens, Ton V. W. ACS Catalysis, Vol. 7, Issue 9 https://doi.org/10.1021/acscatal.7b01643	journal	August 2017
Identification of single-site gold catalysis in acetylene hydrochlorination Malta, Grazia; Kondrat, Simon A.; Freakley, Simon J. Science, Vol. 355, Issue 6332 https://doi.org/10.1126/science.aal3439	journal	March 2017
Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins Torres Galvis, H. M.; Bitter, J. H.; Khare, C. B. Science, Vol. 335, Issue 6070, p. 835-838 https://doi.org/10.1126/science.1215614	journal	February 2012
Surface Science and Catalysis—Studies on the Mechanism of Ammonia Synthesis: The P. H. Emmett Award Address Ertl, G. Catalysis Reviews, Vol. 21, Issue 2 https://doi.org/10.1080/03602458008067533	journal	January 1980
Time-Resolved (2 s) Study of the Initial Steps of the Catalytic Hydrogenation of CO: From Branched Isomers to Unsaturated Molecules Melaet, Gérôme; Ralston, Walter T.; Liu, Wen-Chi The Journal of Physical Chemistry C, Vol. 118, Issue 46 https://doi.org/10.1021/jp5095917	journal	November 2014
Nanoporous Gold Catalysts for Selective Gas-Phase Oxidative Coupling of Methanol at Low Temperature Wittstock, A.; Zielasek, V.; Biener, J. Science, Vol. 327, Issue 5963 https://doi.org/10.1126/science.1183591	journal	January 2010
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials Zhang, Jie-Peng; Zhang, Yue-Biao; Lin, Jian-Bin Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200139g	journal	September 2011
High-spatial-resolution mapping of catalytic reactions on single particles Wu, Chung-Yeh; Wolf, William J.; Levartovsky, Yehonatan Nature, Vol. 541, Issue 7638 https://doi.org/10.1038/nature20795	journal	January 2017
Nanostructured materials for applications in heterogeneous catalysis Zaera, Francisco Chem. Soc. Rev., Vol. 42, Issue 7 https://doi.org/10.1039/C2CS35261C	journal	January 2013
Self-assembly of noble metal monolayers on transition metal carbide nanoparticle catalysts Hunt, S. T.; Milina, M.; Alba-Rubio, A. C. Science, Vol. 352, Issue 6288 https://doi.org/10.1126/science.aad8471	journal	May 2016
Industrial Applications of Gold Catalysis Ciriminna, Rosaria; Falletta, Ermelinda; Della Pina, Cristina Angewandte Chemie International Edition, Vol. 55, Issue 46 https://doi.org/10.1002/anie.201604656	journal	September 2016
Formkontrolle bei der Synthese von Metallnanokristallen: einfache Chemie, komplexe Physik? Xia, Younan; Xiong, Yujie; Lim, Byungkwon Angewandte Chemie, Vol. 121, Issue 1 https://doi.org/10.1002/ange.200802248	journal	December 2008
Structure Sensitivity of the Hydrogenation of Crotonaldehyde over Pt/SiO2and Pt/TiO2 Englisch, Martin; Jentys, Andreas; Lercher, Johannes A. Journal of Catalysis, Vol. 166, Issue 1 https://doi.org/10.1006/jcat.1997.1494	journal	February 1997
A Pt-Cluster-Based Heterogeneous Catalyst for Homogeneous Catalytic Reactions: X-ray Absorption Spectroscopy and Reaction Kinetic Studies of Their Activity and Stability against Leaching Li, Yimin; Liu, Jack Hung-Chang; Witham, Cole A. Journal of the American Chemical Society, Vol. 133, Issue 34 https://doi.org/10.1021/ja204191t	journal	August 2011
In Situ IR and X-ray High Spatial-Resolution Microspectroscopy Measurements of Multistep Organic Transformation in Flow Microreactor Catalyzed by Au Nanoclusters Gross, Elad; Shu, Xing-Zhong; Alayoglu, Selim Journal of the American Chemical Society, Vol. 136, Issue 9 https://doi.org/10.1021/ja412740p	journal	February 2014
The Pathway to Total Isomer Selectivity: n -Hexane Conversion (Reforming) on Platinum Nanoparticles Supported on Aluminum Modified Mesoporous Silica (MCF-17) Musselwhite, Nathan; Na, Kyungsu; Alayoglu, Selim Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja509638w	journal	November 2014
Supported Dendrimer-Encapsulated Metal Clusters: Toward Heterogenizing Homogeneous Catalysts Ye, Rong; Zhukhovitskiy, Aleksandr V.; Deraedt, Christophe V. Accounts of Chemical Research, Vol. 50, Issue 8 https://doi.org/10.1021/acs.accounts.7b00232	journal	July 2017
Comparing the Catalytic Oxidation of Ethanol at the Solid–Gas and Solid–Liquid Interfaces over Size-Controlled Pt Nanoparticles: Striking Differences in Kinetics and Mechanism Sapi, Andras; Liu, Fudong; Cai, Xiaojun Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl5035545	journal	October 2014
Hybrid training approach for artificial neural networks using genetic algorithms for rate of reaction estimation: Application to industrial methanol oxidation to formaldehyde on silver catalyst Papes Filho, Antonio Carlos; Maciel Filho, Rubens Chemical Engineering Journal, Vol. 157, Issue 2-3 https://doi.org/10.1016/j.cej.2009.12.045	journal	March 2010
Effects of Nanoparticle Size and Metal/Support Interactions in Pt-Catalyzed Methanol Oxidation Reactions in Gas and Liquid Phases Wang, Hailiang; An, Kwangjin; Sapi, Andras Catalysis Letters, Vol. 144, Issue 11 https://doi.org/10.1007/s10562-014-1347-9	journal	September 2014
Shape-selective zeolite catalysis for bioplastics production Dusselier, Michiel; Van Wouwe, Pieter; Dewaele, Annelies Science, Vol. 349, Issue 6243 https://doi.org/10.1126/science.aaa7169	journal	July 2015
New Insights into Aldol Reactions of Methyl Isocyanoacetate Catalyzed by Heterogenized Homogeneous Catalysts Ye, Rong; Zhao, Jie; Yuan, Bing Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04827	journal	December 2016
Product distribution change in the early stages of carbon monoxide hydrogenation over cobalt magnesium Fischer-Tropsch catalyst Melaet, Gérôme; Ralston, Walter T.; Liu, Wen-Chi Catalysis Today, Vol. 272 https://doi.org/10.1016/j.cattod.2016.03.027	journal	September 2016
Combining theory and experiment in electrocatalysis: Insights into materials design Seh, Zhi Wei; Kibsgaard, Jakob; Dickens, Colin F. Science, Vol. 355, Issue 6321 https://doi.org/10.1126/science.aad4998	journal	January 2017
Recent advances in catalysts for direct methanol fuel cells Zhao, Xiao; Yin, Min; Ma, Liang Energy & Environmental Science, Vol. 4, Issue 8 https://doi.org/10.1039/c1ee01307f	journal	January 2011
Alcohol Oxidation at Platinum–Gas and Platinum–Liquid Interfaces: The Effect of Platinum Nanoparticle Size, Water Coadsorption, and Alcohol Concentration Tatsumi, Hironori; Liu, Fudong; Han, Hui-Ling The Journal of Physical Chemistry C, Vol. 121, Issue 13 https://doi.org/10.1021/acs.jpcc.7b01432	journal	March 2017
Colloidal Nanocrystal Shape and Size Control: The Case of Cobalt Puntes, Victor F.; Krishnan, Kannan M.; Alivisatos, A. Paul Science, Vol. 291, Issue 5511 https://doi.org/10.1126/science.1058495	journal	March 2001
Strong metal-support interactions Tauster, S. J. Accounts of Chemical Research, Vol. 20, Issue 11 https://doi.org/10.1021/ar00143a001	journal	November 1987
Platinum and Other Transition Metal Nanoclusters (Pd, Rh) Stabilized by PAMAM Dendrimer as Excellent Heterogeneous Catalysts: Application to the Methylcyclopentane (MCP) Hydrogenative Isomerization Deraedt, Christophe; Melaet, Gérôme; Ralston, Walter T. Nano Letters, Vol. 17, Issue 3 https://doi.org/10.1021/acs.nanolett.6b05156	journal	February 2017

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