Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction

doi:10.1063/1.5007038

Title: Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction

Authors:

Harden, James L. ^[1]; Guo, Hongyu ^[2]; Bertrand, Martine ^[1];

^[3]; Ramakrishnan, Subramanian ^[4]; Leheny, Robert L. ^[2]

Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada
Department of Physics and Astronomy, Johns Hopkins University, Baltimore, Maryland 21218, USA
Center for Studies in Physics and Biology, The Rockefeller University, 1230 York Avenue, New York, New York 10065, USA
Department of Chemical and Biomedical Engineering, FAMU-FSU College of Engineering, Tallahassee, Florida 32312, USA

Publication Date:: 2018-01-28

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1419070

Resource Type:: Journal Article

Journal Name:: Journal of Chemical Physics

Additional Journal Information:: Journal Volume: 148; Journal Issue: 4; Journal ID: ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: ENGLISH

Citation Formats


                    Harden, James L., Guo, Hongyu, Bertrand, Martine, Shendruk, Tyler N., Ramakrishnan, Subramanian, and Leheny, Robert L. Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction.  United States: N. p., 2018. 
        Web.  doi:10.1063/1.5007038.

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                    Harden, James L., Guo, Hongyu, Bertrand, Martine, Shendruk, Tyler N., Ramakrishnan, Subramanian, & Leheny, Robert L. Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction.  United States.  doi:10.1063/1.5007038.

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                    Harden, James L., Guo, Hongyu, Bertrand, Martine, Shendruk, Tyler N., Ramakrishnan, Subramanian, and Leheny, Robert L. Sun .  
        "Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction".  United States.  doi:10.1063/1.5007038.

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@article{osti_1419070,

  title        = {Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction},

  author       = {Harden, James L. and Guo, Hongyu and Bertrand, Martine and Shendruk, Tyler N. and Ramakrishnan, Subramanian and Leheny, Robert L.},

  abstractNote = {},

  doi          = {10.1063/1.5007038},

  journal      = {Journal of Chemical Physics},

  issn         = {0021-9606},

  number       = 4,

  volume       = 148,

  place        = {United States},

  year         = {2018},

  month        = {1}

}

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DOI: 10.1063/1.5007038

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Works referenced in this record:

Phase separation in binary eye lens protein mixtures
journal, January 2011

Dorsaz, Nicolas; Thurston, George M.; Stradner, Anna
Soft Matter, Vol. 7, Issue 5
DOI: 10.1039/c0sm00156b

Scattering for mixtures of hard spheres: Comparison of total scattering intensities with model
journal, March 2006

Anderson, B. J.; Gopalakrishnan, V.; Ramakrishnan, S.
Physical Review E, Vol. 73, Issue 3
DOI: 10.1103/physreve.73.031407

Controlled growth of monodisperse silica spheres in the micron size range
journal, January 1968

Stöber, Werner; Fink, Arthur; Bohn, Ernst
Journal of Colloid and Interface Science, Vol. 26, Issue 1, p. 62-69
DOI: 10.1016/0021-9797(68)90272-5

The demixing and gas–liquid instability of a binary Yukawa fluid
journal, September 1992

Chen, X. S.; Forstmann, F.
The Journal of Chemical Physics, Vol. 97, Issue 5
DOI: 10.1063/1.462951

Depletion-Induced Structure and Dynamics in Bimodal Colloidal Suspensions
journal, May 2011

Sikorski, M.; Sandy, A. R.; Narayanan, S.
Physical Review Letters, Vol. 106, Issue 18
DOI: 10.1103/physrevlett.106.188301

Dielectric relaxation and crystallization of nanophase separated 1-propanol-isoamylbromide mixture
journal, September 2007

Power, G.; Vij, J. K.; Johari, G. P.
The Journal of Chemical Physics, Vol. 127, Issue 9
DOI: 10.1063/1.2761898

Plastic Flow of Saturated, Consolidated Alumina Powder Compacts: Particle Size and Binary Mixtures
journal, June 1999

Franks, George V.; Lange, Fred F.
Journal of the American Ceramic Society, Vol. 82, Issue 6
DOI: 10.1111/j.1151-2916.1999.tb01965.x

Phase Behaviour of Hard-Sphere Mixtures
journal, December 1994

Poon, W. C. K.; Warren, P. B.
Europhysics Letters (EPL), Vol. 28, Issue 7
DOI: 10.1209/0295-5075/28/7/010

Crystallization and phase separation in nonadditive binary hard-sphere mixtures
journal, February 2000

Louis, A. A.; Finken, R.; Hansen, J. P.
Physical Review E, Vol. 61, Issue 2
DOI: 10.1103/physreve.61.r1028

Comparing colloidal phase separation induced by linear polymer and by microgel particles
journal, January 2011

Bayliss, K.; van Duijneveldt, J. S.; Faers, M. A.
Soft Matter, Vol. 7, Issue 21
DOI: 10.1039/c1sm05917c

Structural Relaxation Dynamics in Binary Glass-Forming Molecular Liquids with Ideal and Complex Mixing Behavior
journal, March 2010

Wang, Li-Min; Tian, Yongjun; Liu, Riping
The Journal of Physical Chemistry B, Vol. 114, Issue 10
DOI: 10.1021/jp912223j

Viscoelasticity of a colloidal gel during dynamical arrest: Evolution through the critical gel and comparison with a soft colloidal glass
journal, September 2014

Negi, Ajay Singh; Redmon, Carissa G.; Ramakrishnan, Subramanian
Journal of Rheology, Vol. 58, Issue 5
DOI: 10.1122/1.4883675

Preparation and characterization of spherical monodisperse silica dispersions in nonaqueous solvents
journal, June 1981

Van Helden, A. K.; Jansen, J. W.; Vrij, A.
Journal of Colloid and Interface Science, Vol. 81, Issue 2
DOI: 10.1016/0021-9797(81)90417-3

Small-angle X-ray scattering studies of the intact eye lens: Effect of crystallin composition and concentration on microstructure
journal, June 2010

Mirarefi, Amir Y.; Boutet, Sébastien; Ramakrishnan, Subramanian
Biochimica et Biophysica Acta (BBA) - General Subjects, Vol. 1800, Issue 6
DOI: 10.1016/j.bbagen.2010.02.004

Colloidal Processing of Ceramics
journal, October 2000

Lewis, Jennifer A.
Journal of the American Ceramic Society, Vol. 83, Issue 10
DOI: 10.1111/j.1151-2916.2000.tb01560.x

Phase separation of asymmetric binary hard-sphere fluids
journal, April 1991

Biben, Thierry; Hansen, Jean-Pierre
Physical Review Letters, Vol. 66, Issue 17
DOI: 10.1103/physrevlett.66.2215

Bicontinuous and mixed gels in binary mixtures of patchy colloidal particles
journal, January 2012

de las Heras, Daniel; Tavares, José Maria; Telo da Gama, Margarida M.
Soft Matter, Vol. 8, Issue 6
DOI: 10.1039/c1sm06948a

Effective interaction in asymmetric charged binary mixtures: The non-monotonic behaviour with the colloidal charge
journal, November 2012

Peláez-Fernández, M.; Callejas-Fernández, J.; Moncho-Jordá, A.
The European Physical Journal E, Vol. 35, Issue 11
DOI: 10.1140/epje/i2012-12120-0

Mode Coupling and Dynamical Heterogeneity in Colloidal Gelation: A Simulation Study ^†
journal, April 2005

Puertas, Antonio M.; Fuchs, Matthias; Cates, Michael E.
The Journal of Physical Chemistry B, Vol. 109, Issue 14
DOI: 10.1021/jp045595p

Area detector based photon correlation in the regime of short data batches: Data reduction for dynamic x-ray scattering
journal, September 2000

Lumma, D.; Lurio, L. B.; Mochrie, S. G. J.
Review of Scientific Instruments, Vol. 71, Issue 9
DOI: 10.1063/1.1287637

Effect of repulsive and attractive interactions on depletion forces in colloidal suspensions: A density functional theory treatment
journal, September 2004

Egorov, S. A.
Physical Review E, Vol. 70, Issue 3
DOI: 10.1103/physreve.70.031402

Depletion effects in a mixture of hard and attractive colloids
journal, March 2009

Lajovic, A.; Tomšič, M.; Jamnik, A.
The Journal of Chemical Physics, Vol. 130, Issue 10
DOI: 10.1063/1.3081144

Structure of Binary Liquid Mixtures. I
journal, April 1967

Ashcroft, N. W.; Langreth, David C.
Physical Review, Vol. 156, Issue 3
DOI: 10.1103/physrev.156.685

Colloidal Characterization and Thermodynamic Stability of Binary Eye Lens Protein Mixtures
journal, February 2009

Dorsaz, N.; Thurston, G. M.; Stradner, A.
The Journal of Physical Chemistry B, Vol. 113, Issue 6
DOI: 10.1021/jp807103f

Clustering and Mechanics in Dense Depletion and Thermal Gels ^†
journal, October 2005

Ramakrishnan, S.; Gopalakrishnan, V.; Zukoski, C. F.
Langmuir, Vol. 21, Issue 22
DOI: 10.1021/la050830w

Experimental Phase Diagram of a Binary Colloidal Hard-Sphere Mixture with a Large Size Ratio
journal, August 1995

Imhof, A.; Dhont, J. K. G.
Physical Review Letters, Vol. 75, Issue 8
DOI: 10.1103/physrevlett.75.1662

Equilibrium Cluster Phases and Low-Density Arrested Disordered States: The Role of Short-Range Attraction and Long-Range Repulsion
journal, July 2004

Sciortino, Francesco; Mossa, Stefano; Zaccarelli, Emanuela
Physical Review Letters, Vol. 93, Issue 5
DOI: 10.1103/physrevlett.93.055701

Attractions in sterically stabilized silica dispersions
journal, December 1986

Jansen, J. W.; de Kruif, C. G.; Vrij, A.
Journal of Colloid and Interface Science, Vol. 114, Issue 2
DOI: 10.1016/0021-9797(86)90433-9

Effective forces in colloidal mixtures: From depletion attraction to accumulation repulsion
journal, June 2002

Louis, A. A.; Allahyarov, E.; Löwen, H.
Physical Review E, Vol. 65, Issue 6
DOI: 10.1103/physreve.65.061407

Beyond simple exponential correlation functions and equilibrium dynamics in x-ray photon correlation spectroscopy
journal, May 2010

Madsen, Anders; Leheny, Robert L.; Guo, Hongyu
New Journal of Physics, Vol. 12, Issue 5
DOI: 10.1088/1367-2630/12/5/055001

Unusual Features of Depletion Interactions in Soft Polymer-Based Colloids Mixed with Linear Homopolymers
journal, February 2010

Camargo, Manuel; Likos, Christos N.
Physical Review Letters, Vol. 104, Issue 7
DOI: 10.1103/physrevlett.104.078301

Preparation of monodisperse silica particles: Control of size and mass fraction
journal, August 1988

Bogush, G. H.; Tracy, M. A.; Zukoski, C. F.
Journal of Non-Crystalline Solids, Vol. 104, Issue 1, p. 95-106
DOI: 10.1016/0022-3093(88)90187-1

Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations
journal, October 2017

Zhang, Qingteng; Bahadur, Divya; Dufresne, Eric M.
Physical Review Letters, Vol. 119, Issue 17
DOI: 10.1103/physrevlett.119.178006

Gelation in mixtures of polymers and bidisperse colloids
journal, January 2016

Pandey, Rahul; Conrad, Jacinta C.
Physical Review E, Vol. 93, Issue 1
DOI: 10.1103/physreve.93.012610

Equilibrium Thermodynamic Properties of the Mixture of Hard Spheres
journal, February 1971

Mansoori, G. A.; Carnahan, N. F.; Starling, K. E.
The Journal of Chemical Physics, Vol. 54, Issue 4
DOI: 10.1063/1.1675048

XPCS: Nanoscale motion and rheology
journal, February 2012

Leheny, Robert L.
Current Opinion in Colloid & Interface Science, Vol. 17, Issue 1
DOI: 10.1016/j.cocis.2011.11.002

Effect of residual attractive interactions in size asymmetric colloidal mixtures: Theoretical analysis and predictions
journal, July 2010

Germain, Ph.
The Journal of Chemical Physics, Vol. 133, Issue 4
DOI: 10.1063/1.3456734

Perturbation theory for mixtures of simple liquids
journal, December 1973

Lee, L. L.; Levesque, D.
Molecular Physics, Vol. 26, Issue 6
DOI: 10.1080/00268977300102531

Exact Solution of Generalized Percus-Yevick Equation for a Mixture of Hard Spheres
journal, February 1964

Lebowitz, J. L.
Physical Review, Vol. 133, Issue 4A
DOI: 10.1103/physrev.133.a895

Hard‐Sphere Equation of State
journal, July 1970

Boublík, Tomáš
The Journal of Chemical Physics, Vol. 53, Issue 1
DOI: 10.1063/1.1673824

General purpose molecular dynamics simulations fully implemented on graphics processing units
journal, May 2008

Anderson, Joshua A.; Lorenz, Chris D.; Travesset, A.
Journal of Computational Physics, Vol. 227, Issue 10
DOI: 10.1016/j.jcp.2008.01.047

Gelation of particles with short-range attraction
journal, May 2008

Lu, Peter J.; Zaccarelli, Emanuela; Ciulla, Fabio
Nature, Vol. 453, Issue 7194
DOI: 10.1038/nature06931

Rheology of suspensions of weakly attractive particles: Approach to gelation
journal, November 1998

Rueb, C. J.; Zukoski, C. F.
Journal of Rheology, Vol. 42, Issue 6
DOI: 10.1122/1.550966

Structure and dynamics of concentrated dispersions of polystyrene latex spheres in glycerol: Static and dynamic x-ray scattering
journal, December 2000

Lumma, D.; Lurio, L. B.; Borthwick, M. A.
Physical Review E, Vol. 62, Issue 6
DOI: 10.1103/physreve.62.8258

Equilibrium cluster formation in concentrated protein solutions and colloids
journal, November 2004

Stradner, Anna; Sedgwick, Helen; Cardinaux, Frédéric
Nature, Vol. 432, Issue 7016
DOI: 10.1038/nature03109

Rheological Behavior of Slurries and Consolidated Bodies Containing Mixed Silicon Nitride Networks
journal, August 2000

Fisher, Matthew L.; Lange, Fred F.
Journal of the American Ceramic Society, Vol. 83, Issue 8
DOI: 10.1111/j.1151-2916.2000.tb01482.x

Publisher's Note: Thermodynamic instabilities of a binary mixture of sticky hard spheres [Phys. Rev. E 72 , 011503 (2005)]
journal, August 2005

Fantoni, Riccardo; Gazzillo, Domenico; Giacometti, Achille
Physical Review E, Vol. 72, Issue 2
DOI: 10.1103/physreve.72.029904

Polydisperse systems: Statistical thermodynamics, with applications to several models including hard and permeable spheres
journal, October 1982

Salacuse, J. J.; Stell, G.
The Journal of Chemical Physics, Vol. 77, Issue 7
DOI: 10.1063/1.444274

Analytic methods for the Percus-Yevick hard sphere correlation functions
journal, January 2009

Henderson,
Condensed Matter Physics, Vol. 12, Issue 2
DOI: 10.5488/cmp.12.2.127

Colloidal gels—low-density disordered solid-like states
journal, April 2004

Trappe, Veronique; Sandkühler, Peter
Current Opinion in Colloid & Interface Science, Vol. 8, Issue 6
DOI: 10.1016/j.cocis.2004.01.002

Simulating asymmetric colloidal mixture with adhesive hard sphere model
journal, June 2008

Jamnik, A.
The Journal of Chemical Physics, Vol. 128, Issue 23
DOI: 10.1063/1.2939120

Equilibrium Route to Colloidal Gelation: Mixtures of Hard-Sphere-Like Colloids
journal, February 2009

Germain, Ph.; Amokrane, S.
Physical Review Letters, Vol. 102, Issue 5
DOI: 10.1103/physrevlett.102.058301

Colloidal gelation of oppositely charged particles
journal, January 2012

Russell, Emily R.; Sprakel, Joris; Kodger, Thomas E.
Soft Matter, Vol. 8, Issue 33
DOI: 10.1039/c2sm25901j

Dynamical Arrest in Attractive Colloids: The Effect of Long-Range Repulsion
journal, May 2005

Campbell, Andrew I.; Anderson, Valerie J.; van Duijneveldt, Jeroen S.
Physical Review Letters, Vol. 94, Issue 20
DOI: 10.1103/physrevlett.94.208301

Glasslike Arrest in Spinodal Decomposition as a Route to Colloidal Gelation
journal, December 2005

Manley, S.; Wyss, H. M.; Miyazaki, K.
Physical Review Letters, Vol. 95, Issue 23
DOI: 10.1103/physrevlett.95.238302

Gel formation and aging in weakly attractive nanocolloid suspensions at intermediate concentrations
journal, October 2011

Guo, Hongyu; Ramakrishnan, S.; Harden, James L.
The Journal of Chemical Physics, Vol. 135, Issue 15
DOI: 10.1063/1.3653380

Delayed sedimentation of transient gels in colloid–polymer mixtures: dark-field observation, rheology and dynamic light scattering studies
journal, January 1999

Poon, W. C. K.; Starrs, L.; Meeker, S. P.
Faraday Discussions, Vol. 112
DOI: 10.1039/a900664h

Connecting nanoscale motion and rheology of gel-forming colloidal suspensions
journal, May 2010

Guo, Hongyu; Ramakrishnan, S.; Harden, James L.
Physical Review E, Vol. 81, Issue 5
DOI: 10.1103/physreve.81.050401

Large attractive depletion interactions in soft repulsive–sphere binary mixtures
journal, December 2007

Cinacchi, Giorgio; Martínez-Ratón, Yuri; Mederos, Luis
The Journal of Chemical Physics, Vol. 127, Issue 21
DOI: 10.1063/1.2804330

Anomalous Component Dynamics of a Binary Mixture of Associating Glass-Forming Liquids
journal, February 2011

Wang, Li-Min; Tian, Yongjun; Liu, Riping
The Journal of Physical Chemistry B, Vol. 115, Issue 4
DOI: 10.1021/jp1101362

Distribution functions of multi-component fluid mixtures of hard spheres
journal, August 1972

Grundke, E. W.; Henderson, D.
Molecular Physics, Vol. 24, Issue 2
DOI: 10.1080/00268977200101431

Universal non-diffusive slow dynamics in aging soft matter
journal, September 2002

Cipelletti, Luca; Ramos, Laurence; Manley, S.
Faraday Discussions, Vol. 123
DOI: 10.1039/b204495a

Gelation and phase coexistence in colloidal suspensions with short-range forces: Generic behavior versus specificity
journal, January 2010

Germain, Ph.; Amokrane, S.
Physical Review E, Vol. 81, Issue 1
DOI: 10.1103/physreve.81.011407

Viscoelastic properties of colloidal gels
journal, March 1997

Rueb, C. J.; Zukoski, C. F.
Journal of Rheology, Vol. 41, Issue 2
DOI: 10.1122/1.550812

Microstructure and Rheology of Thermoreversible Nanoparticle Gels
journal, August 2006

Ramakrishnan, S.; Zukoski, C. F.
Langmuir, Vol. 22, Issue 18
DOI: 10.1021/la060168j

Dynamical Arrest Transition in Nanoparticle Dispersions with Short-Range Interactions
journal, March 2011

Eberle, Aaron P. R.; Wagner, Norman J.; Castañeda-Priego, Ramón
Physical Review Letters, Vol. 106, Issue 10
DOI: 10.1103/physrevlett.106.105704

Strong scaling of general-purpose molecular dynamics simulations on GPUs
journal, July 2015

Glaser, Jens; Nguyen, Trung Dac; Anderson, Joshua A.
Computer Physics Communications, Vol. 192
DOI: 10.1016/j.cpc.2015.02.028

Entropically Driven Surface Phase Separation in Binary Colloidal Mixtures
journal, January 1994

Kaplan, P. D.; Rouke, J. L.; Yodh, A. G.
Physical Review Letters, Vol. 72, Issue 4
DOI: 10.1103/physrevlett.72.582

Microscopic theory of gelation and elasticity in polymer–particle suspensions
journal, April 2004

Chen, Yeng-Long; Schweizer, Kenneth S.
The Journal of Chemical Physics, Vol. 120, Issue 15
DOI: 10.1063/1.1683077

Arrested demixing opens route to bigels
journal, November 2012

Varrato, F.; Di Michele, L.; Belushkin, M.
Proceedings of the National Academy of Sciences, Vol. 109, Issue 47
DOI: 10.1073/pnas.1214971109

Phase diagram of highly asymmetric binary hard-sphere mixtures
journal, May 1999

Dijkstra, Marjolein; van Roij, René; Evans, Robert
Physical Review E, Vol. 59, Issue 5
DOI: 10.1103/physreve.59.5744

Effective interaction between large colloidal particles immersed in a bidisperse suspension of short-ranged attractive colloids
journal, October 2009

Jamnik, A.
The Journal of Chemical Physics, Vol. 131, Issue 16
DOI: 10.1063/1.3253694

Anomalous dynamical light scattering in soft glassy gels
journal, November 2001

Bouchaud, J. -P.; Pitard, E.
The European Physical Journal E, Vol. 6, Issue 3
DOI: 10.1007/s101890170005

Kinetic arrest and glass-glass transition in short-ranged attractive colloids
journal, November 2006

Sztucki, M.; Narayanan, T.; Belina, G.
Physical Review E, Vol. 74, Issue 5
DOI: 10.1103/physreve.74.051504

Colloidal gels: equilibrium and non-equilibrium routes
journal, July 2007

Zaccarelli, Emanuela
Journal of Physics: Condensed Matter, Vol. 19, Issue 32
DOI: 10.1088/0953-8984/19/32/323101

Phase diagrams of nearly-hard-sphere binary colloids
journal, October 1995

Dinsmore, A. D.; Yodh, A. G.; Pine, D. J.
Physical Review E, Vol. 52, Issue 4
DOI: 10.1103/physreve.52.4045

A density-functional theory study of microphase formation in binary Gaussian mixtures
journal, June 2012

Carta, M.; Pini, D.; Parola, A.
Journal of Physics: Condensed Matter, Vol. 24, Issue 28
DOI: 10.1088/0953-8984/24/28/284106

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Title: Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction

Citation Formats

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Structure of Binary Liquid Mixtures. I journal, April 1967

Colloidal Characterization and Thermodynamic Stability of Binary Eye Lens Protein Mixtures journal, February 2009

Clustering and Mechanics in Dense Depletion and Thermal Gels † journal, October 2005

Experimental Phase Diagram of a Binary Colloidal Hard-Sphere Mixture with a Large Size Ratio journal, August 1995

Equilibrium Cluster Phases and Low-Density Arrested Disordered States: The Role of Short-Range Attraction and Long-Range Repulsion journal, July 2004

Attractions in sterically stabilized silica dispersions journal, December 1986

Effective forces in colloidal mixtures: From depletion attraction to accumulation repulsion journal, June 2002

Beyond simple exponential correlation functions and equilibrium dynamics in x-ray photon correlation spectroscopy journal, May 2010

Unusual Features of Depletion Interactions in Soft Polymer-Based Colloids Mixed with Linear Homopolymers journal, February 2010

Preparation of monodisperse silica particles: Control of size and mass fraction journal, August 1988

Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations journal, October 2017

Gelation in mixtures of polymers and bidisperse colloids journal, January 2016

Equilibrium Thermodynamic Properties of the Mixture of Hard Spheres journal, February 1971

XPCS: Nanoscale motion and rheology journal, February 2012

Effect of residual attractive interactions in size asymmetric colloidal mixtures: Theoretical analysis and predictions journal, July 2010

Perturbation theory for mixtures of simple liquids journal, December 1973

Exact Solution of Generalized Percus-Yevick Equation for a Mixture of Hard Spheres journal, February 1964

Hard‐Sphere Equation of State journal, July 1970

General purpose molecular dynamics simulations fully implemented on graphics processing units journal, May 2008

Gelation of particles with short-range attraction journal, May 2008

Rheology of suspensions of weakly attractive particles: Approach to gelation journal, November 1998

Structure and dynamics of concentrated dispersions of polystyrene latex spheres in glycerol: Static and dynamic x-ray scattering journal, December 2000

Equilibrium cluster formation in concentrated protein solutions and colloids journal, November 2004

Rheological Behavior of Slurries and Consolidated Bodies Containing Mixed Silicon Nitride Networks journal, August 2000

Publisher's Note: Thermodynamic instabilities of a binary mixture of sticky hard spheres [Phys. Rev. E 72 , 011503 (2005)] journal, August 2005

Polydisperse systems: Statistical thermodynamics, with applications to several models including hard and permeable spheres journal, October 1982

Analytic methods for the Percus-Yevick hard sphere correlation functions journal, January 2009

Colloidal gels—low-density disordered solid-like states journal, April 2004

Simulating asymmetric colloidal mixture with adhesive hard sphere model journal, June 2008

Equilibrium Route to Colloidal Gelation: Mixtures of Hard-Sphere-Like Colloids journal, February 2009

Colloidal gelation of oppositely charged particles journal, January 2012

Dynamical Arrest in Attractive Colloids: The Effect of Long-Range Repulsion journal, May 2005

Glasslike Arrest in Spinodal Decomposition as a Route to Colloidal Gelation journal, December 2005

Gel formation and aging in weakly attractive nanocolloid suspensions at intermediate concentrations journal, October 2011

Delayed sedimentation of transient gels in colloid–polymer mixtures: dark-field observation, rheology and dynamic light scattering studies journal, January 1999

Connecting nanoscale motion and rheology of gel-forming colloidal suspensions journal, May 2010

Large attractive depletion interactions in soft repulsive–sphere binary mixtures journal, December 2007

Anomalous Component Dynamics of a Binary Mixture of Associating Glass-Forming Liquids journal, February 2011

Distribution functions of multi-component fluid mixtures of hard spheres journal, August 1972

Universal non-diffusive slow dynamics in aging soft matter journal, September 2002

Gelation and phase coexistence in colloidal suspensions with short-range forces: Generic behavior versus specificity journal, January 2010

Viscoelastic properties of colloidal gels journal, March 1997

Microstructure and Rheology of Thermoreversible Nanoparticle Gels journal, August 2006

Dynamical Arrest Transition in Nanoparticle Dispersions with Short-Range Interactions journal, March 2011

Strong scaling of general-purpose molecular dynamics simulations on GPUs journal, July 2015

Entropically Driven Surface Phase Separation in Binary Colloidal Mixtures journal, January 1994

Microscopic theory of gelation and elasticity in polymer–particle suspensions journal, April 2004

Arrested demixing opens route to bigels journal, November 2012

Phase diagram of highly asymmetric binary hard-sphere mixtures journal, May 1999

Effective interaction between large colloidal particles immersed in a bidisperse suspension of short-ranged attractive colloids journal, October 2009

Anomalous dynamical light scattering in soft glassy gels journal, November 2001

Kinetic arrest and glass-glass transition in short-ranged attractive colloids journal, November 2006

Colloidal gels: equilibrium and non-equilibrium routes journal, July 2007

Phase diagrams of nearly-hard-sphere binary colloids journal, October 1995

A density-functional theory study of microphase formation in binary Gaussian mixtures journal, June 2012

Phase separation in binary eye lens protein mixtures
journal, January 2011

Scattering for mixtures of hard spheres: Comparison of total scattering intensities with model
journal, March 2006

Controlled growth of monodisperse silica spheres in the micron size range
journal, January 1968

The demixing and gas–liquid instability of a binary Yukawa fluid
journal, September 1992

Depletion-Induced Structure and Dynamics in Bimodal Colloidal Suspensions
journal, May 2011

Dielectric relaxation and crystallization of nanophase separated 1-propanol-isoamylbromide mixture
journal, September 2007

Plastic Flow of Saturated, Consolidated Alumina Powder Compacts: Particle Size and Binary Mixtures
journal, June 1999

Phase Behaviour of Hard-Sphere Mixtures
journal, December 1994

Crystallization and phase separation in nonadditive binary hard-sphere mixtures
journal, February 2000

Comparing colloidal phase separation induced by linear polymer and by microgel particles
journal, January 2011

Structural Relaxation Dynamics in Binary Glass-Forming Molecular Liquids with Ideal and Complex Mixing Behavior
journal, March 2010

Viscoelasticity of a colloidal gel during dynamical arrest: Evolution through the critical gel and comparison with a soft colloidal glass
journal, September 2014

Preparation and characterization of spherical monodisperse silica dispersions in nonaqueous solvents
journal, June 1981

Small-angle X-ray scattering studies of the intact eye lens: Effect of crystallin composition and concentration on microstructure
journal, June 2010

Colloidal Processing of Ceramics
journal, October 2000

Phase separation of asymmetric binary hard-sphere fluids
journal, April 1991

Bicontinuous and mixed gels in binary mixtures of patchy colloidal particles
journal, January 2012

Effective interaction in asymmetric charged binary mixtures: The non-monotonic behaviour with the colloidal charge
journal, November 2012

Mode Coupling and Dynamical Heterogeneity in Colloidal Gelation: A Simulation Study ^†
journal, April 2005

Area detector based photon correlation in the regime of short data batches: Data reduction for dynamic x-ray scattering
journal, September 2000

Effect of repulsive and attractive interactions on depletion forces in colloidal suspensions: A density functional theory treatment
journal, September 2004

Depletion effects in a mixture of hard and attractive colloids
journal, March 2009

Structure of Binary Liquid Mixtures. I
journal, April 1967

Colloidal Characterization and Thermodynamic Stability of Binary Eye Lens Protein Mixtures
journal, February 2009

Clustering and Mechanics in Dense Depletion and Thermal Gels ^†
journal, October 2005

Experimental Phase Diagram of a Binary Colloidal Hard-Sphere Mixture with a Large Size Ratio
journal, August 1995

Equilibrium Cluster Phases and Low-Density Arrested Disordered States: The Role of Short-Range Attraction and Long-Range Repulsion
journal, July 2004

Attractions in sterically stabilized silica dispersions
journal, December 1986

Effective forces in colloidal mixtures: From depletion attraction to accumulation repulsion
journal, June 2002

Beyond simple exponential correlation functions and equilibrium dynamics in x-ray photon correlation spectroscopy
journal, May 2010

Unusual Features of Depletion Interactions in Soft Polymer-Based Colloids Mixed with Linear Homopolymers
journal, February 2010

Preparation of monodisperse silica particles: Control of size and mass fraction
journal, August 1988

Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations
journal, October 2017

Gelation in mixtures of polymers and bidisperse colloids
journal, January 2016

Equilibrium Thermodynamic Properties of the Mixture of Hard Spheres
journal, February 1971

XPCS: Nanoscale motion and rheology
journal, February 2012

Effect of residual attractive interactions in size asymmetric colloidal mixtures: Theoretical analysis and predictions
journal, July 2010

Perturbation theory for mixtures of simple liquids
journal, December 1973

Exact Solution of Generalized Percus-Yevick Equation for a Mixture of Hard Spheres
journal, February 1964

Hard‐Sphere Equation of State
journal, July 1970

General purpose molecular dynamics simulations fully implemented on graphics processing units
journal, May 2008

Gelation of particles with short-range attraction
journal, May 2008

Rheology of suspensions of weakly attractive particles: Approach to gelation
journal, November 1998

Structure and dynamics of concentrated dispersions of polystyrene latex spheres in glycerol: Static and dynamic x-ray scattering
journal, December 2000

Equilibrium cluster formation in concentrated protein solutions and colloids
journal, November 2004

Rheological Behavior of Slurries and Consolidated Bodies Containing Mixed Silicon Nitride Networks
journal, August 2000

Publisher's Note: Thermodynamic instabilities of a binary mixture of sticky hard spheres [Phys. Rev. E 72 , 011503 (2005)]
journal, August 2005

Polydisperse systems: Statistical thermodynamics, with applications to several models including hard and permeable spheres
journal, October 1982

Analytic methods for the Percus-Yevick hard sphere correlation functions
journal, January 2009

Colloidal gels—low-density disordered solid-like states
journal, April 2004

Simulating asymmetric colloidal mixture with adhesive hard sphere model
journal, June 2008

Equilibrium Route to Colloidal Gelation: Mixtures of Hard-Sphere-Like Colloids
journal, February 2009

Colloidal gelation of oppositely charged particles
journal, January 2012

Dynamical Arrest in Attractive Colloids: The Effect of Long-Range Repulsion
journal, May 2005

Glasslike Arrest in Spinodal Decomposition as a Route to Colloidal Gelation
journal, December 2005

Gel formation and aging in weakly attractive nanocolloid suspensions at intermediate concentrations
journal, October 2011

Delayed sedimentation of transient gels in colloid–polymer mixtures: dark-field observation, rheology and dynamic light scattering studies
journal, January 1999

Connecting nanoscale motion and rheology of gel-forming colloidal suspensions
journal, May 2010

Large attractive depletion interactions in soft repulsive–sphere binary mixtures
journal, December 2007

Anomalous Component Dynamics of a Binary Mixture of Associating Glass-Forming Liquids
journal, February 2011

Distribution functions of multi-component fluid mixtures of hard spheres
journal, August 1972

Universal non-diffusive slow dynamics in aging soft matter
journal, September 2002

Gelation and phase coexistence in colloidal suspensions with short-range forces: Generic behavior versus specificity
journal, January 2010

Viscoelastic properties of colloidal gels
journal, March 1997

Microstructure and Rheology of Thermoreversible Nanoparticle Gels
journal, August 2006

Dynamical Arrest Transition in Nanoparticle Dispersions with Short-Range Interactions
journal, March 2011

Strong scaling of general-purpose molecular dynamics simulations on GPUs
journal, July 2015

Entropically Driven Surface Phase Separation in Binary Colloidal Mixtures
journal, January 1994

Microscopic theory of gelation and elasticity in polymer–particle suspensions
journal, April 2004

Arrested demixing opens route to bigels
journal, November 2012

Phase diagram of highly asymmetric binary hard-sphere mixtures
journal, May 1999

Effective interaction between large colloidal particles immersed in a bidisperse suspension of short-ranged attractive colloids
journal, October 2009

Anomalous dynamical light scattering in soft glassy gels
journal, November 2001

Kinetic arrest and glass-glass transition in short-ranged attractive colloids
journal, November 2006

Colloidal gels: equilibrium and non-equilibrium routes
journal, July 2007

Phase diagrams of nearly-hard-sphere binary colloids
journal, October 1995

A density-functional theory study of microphase formation in binary Gaussian mixtures
journal, June 2012