skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction

Authors:
 [1];  [2];  [1]; ORCiD logo [3];  [4];  [2]
  1. Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada
  2. Department of Physics and Astronomy, Johns Hopkins University, Baltimore, Maryland 21218, USA
  3. Center for Studies in Physics and Biology, The Rockefeller University, 1230 York Avenue, New York, New York 10065, USA
  4. Department of Chemical and Biomedical Engineering, FAMU-FSU College of Engineering, Tallahassee, Florida 32312, USA
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1419070
Resource Type:
Journal Article
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 148; Journal Issue: 4; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Harden, James L., Guo, Hongyu, Bertrand, Martine, Shendruk, Tyler N., Ramakrishnan, Subramanian, and Leheny, Robert L. Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction. United States: N. p., 2018. Web. doi:10.1063/1.5007038.
Harden, James L., Guo, Hongyu, Bertrand, Martine, Shendruk, Tyler N., Ramakrishnan, Subramanian, & Leheny, Robert L. Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction. United States. doi:10.1063/1.5007038.
Harden, James L., Guo, Hongyu, Bertrand, Martine, Shendruk, Tyler N., Ramakrishnan, Subramanian, and Leheny, Robert L. Sun . "Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction". United States. doi:10.1063/1.5007038.
@article{osti_1419070,
title = {Enhanced gel formation in binary mixtures of nanocolloids with short-range attraction},
author = {Harden, James L. and Guo, Hongyu and Bertrand, Martine and Shendruk, Tyler N. and Ramakrishnan, Subramanian and Leheny, Robert L.},
abstractNote = {},
doi = {10.1063/1.5007038},
journal = {Journal of Chemical Physics},
issn = {0021-9606},
number = 4,
volume = 148,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Phase separation in binary eye lens protein mixtures
journal, January 2011

  • Dorsaz, Nicolas; Thurston, George M.; Stradner, Anna
  • Soft Matter, Vol. 7, Issue 5
  • DOI: 10.1039/c0sm00156b

Scattering for mixtures of hard spheres: Comparison of total scattering intensities with model
journal, March 2006


Controlled growth of monodisperse silica spheres in the micron size range
journal, January 1968

  • Stöber, Werner; Fink, Arthur; Bohn, Ernst
  • Journal of Colloid and Interface Science, Vol. 26, Issue 1, p. 62-69
  • DOI: 10.1016/0021-9797(68)90272-5

The demixing and gas–liquid instability of a binary Yukawa fluid
journal, September 1992

  • Chen, X. S.; Forstmann, F.
  • The Journal of Chemical Physics, Vol. 97, Issue 5
  • DOI: 10.1063/1.462951

Depletion-Induced Structure and Dynamics in Bimodal Colloidal Suspensions
journal, May 2011


Dielectric relaxation and crystallization of nanophase separated 1-propanol-isoamylbromide mixture
journal, September 2007

  • Power, G.; Vij, J. K.; Johari, G. P.
  • The Journal of Chemical Physics, Vol. 127, Issue 9
  • DOI: 10.1063/1.2761898

Plastic Flow of Saturated, Consolidated Alumina Powder Compacts: Particle Size and Binary Mixtures
journal, June 1999


Phase Behaviour of Hard-Sphere Mixtures
journal, December 1994


Crystallization and phase separation in nonadditive binary hard-sphere mixtures
journal, February 2000


Comparing colloidal phase separation induced by linear polymer and by microgel particles
journal, January 2011

  • Bayliss, K.; van Duijneveldt, J. S.; Faers, M. A.
  • Soft Matter, Vol. 7, Issue 21
  • DOI: 10.1039/c1sm05917c

Structural Relaxation Dynamics in Binary Glass-Forming Molecular Liquids with Ideal and Complex Mixing Behavior
journal, March 2010

  • Wang, Li-Min; Tian, Yongjun; Liu, Riping
  • The Journal of Physical Chemistry B, Vol. 114, Issue 10
  • DOI: 10.1021/jp912223j

Viscoelasticity of a colloidal gel during dynamical arrest: Evolution through the critical gel and comparison with a soft colloidal glass
journal, September 2014

  • Negi, Ajay Singh; Redmon, Carissa G.; Ramakrishnan, Subramanian
  • Journal of Rheology, Vol. 58, Issue 5
  • DOI: 10.1122/1.4883675

Preparation and characterization of spherical monodisperse silica dispersions in nonaqueous solvents
journal, June 1981


Small-angle X-ray scattering studies of the intact eye lens: Effect of crystallin composition and concentration on microstructure
journal, June 2010

  • Mirarefi, Amir Y.; Boutet, Sébastien; Ramakrishnan, Subramanian
  • Biochimica et Biophysica Acta (BBA) - General Subjects, Vol. 1800, Issue 6
  • DOI: 10.1016/j.bbagen.2010.02.004

Colloidal Processing of Ceramics
journal, October 2000


Phase separation of asymmetric binary hard-sphere fluids
journal, April 1991


Bicontinuous and mixed gels in binary mixtures of patchy colloidal particles
journal, January 2012

  • de las Heras, Daniel; Tavares, José Maria; Telo da Gama, Margarida M.
  • Soft Matter, Vol. 8, Issue 6
  • DOI: 10.1039/c1sm06948a

Effective interaction in asymmetric charged binary mixtures: The non-monotonic behaviour with the colloidal charge
journal, November 2012

  • Peláez-Fernández, M.; Callejas-Fernández, J.; Moncho-Jordá, A.
  • The European Physical Journal E, Vol. 35, Issue 11
  • DOI: 10.1140/epje/i2012-12120-0

Mode Coupling and Dynamical Heterogeneity in Colloidal Gelation:  A Simulation Study
journal, April 2005

  • Puertas, Antonio M.; Fuchs, Matthias; Cates, Michael E.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 14
  • DOI: 10.1021/jp045595p

Area detector based photon correlation in the regime of short data batches: Data reduction for dynamic x-ray scattering
journal, September 2000

  • Lumma, D.; Lurio, L. B.; Mochrie, S. G. J.
  • Review of Scientific Instruments, Vol. 71, Issue 9
  • DOI: 10.1063/1.1287637

Depletion effects in a mixture of hard and attractive colloids
journal, March 2009

  • Lajovic, A.; Tomšič, M.; Jamnik, A.
  • The Journal of Chemical Physics, Vol. 130, Issue 10
  • DOI: 10.1063/1.3081144

Structure of Binary Liquid Mixtures. I
journal, April 1967


Colloidal Characterization and Thermodynamic Stability of Binary Eye Lens Protein Mixtures
journal, February 2009

  • Dorsaz, N.; Thurston, G. M.; Stradner, A.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 6
  • DOI: 10.1021/jp807103f

Clustering and Mechanics in Dense Depletion and Thermal Gels
journal, October 2005

  • Ramakrishnan, S.; Gopalakrishnan, V.; Zukoski, C. F.
  • Langmuir, Vol. 21, Issue 22
  • DOI: 10.1021/la050830w

Experimental Phase Diagram of a Binary Colloidal Hard-Sphere Mixture with a Large Size Ratio
journal, August 1995


Equilibrium Cluster Phases and Low-Density Arrested Disordered States: The Role of Short-Range Attraction and Long-Range Repulsion
journal, July 2004


Attractions in sterically stabilized silica dispersions
journal, December 1986


Effective forces in colloidal mixtures: From depletion attraction to accumulation repulsion
journal, June 2002


Beyond simple exponential correlation functions and equilibrium dynamics in x-ray photon correlation spectroscopy
journal, May 2010


Unusual Features of Depletion Interactions in Soft Polymer-Based Colloids Mixed with Linear Homopolymers
journal, February 2010


Preparation of monodisperse silica particles: Control of size and mass fraction
journal, August 1988

  • Bogush, G. H.; Tracy, M. A.; Zukoski, C. F.
  • Journal of Non-Crystalline Solids, Vol. 104, Issue 1, p. 95-106
  • DOI: 10.1016/0022-3093(88)90187-1

Dynamic Scaling of Colloidal Gel Formation at Intermediate Concentrations
journal, October 2017


Gelation in mixtures of polymers and bidisperse colloids
journal, January 2016


Equilibrium Thermodynamic Properties of the Mixture of Hard Spheres
journal, February 1971

  • Mansoori, G. A.; Carnahan, N. F.; Starling, K. E.
  • The Journal of Chemical Physics, Vol. 54, Issue 4
  • DOI: 10.1063/1.1675048

XPCS: Nanoscale motion and rheology
journal, February 2012


Effect of residual attractive interactions in size asymmetric colloidal mixtures: Theoretical analysis and predictions
journal, July 2010

  • Germain, Ph.
  • The Journal of Chemical Physics, Vol. 133, Issue 4
  • DOI: 10.1063/1.3456734

Perturbation theory for mixtures of simple liquids
journal, December 1973


Exact Solution of Generalized Percus-Yevick Equation for a Mixture of Hard Spheres
journal, February 1964


Hard‐Sphere Equation of State
journal, July 1970

  • Boublík, Tomáš
  • The Journal of Chemical Physics, Vol. 53, Issue 1
  • DOI: 10.1063/1.1673824

General purpose molecular dynamics simulations fully implemented on graphics processing units
journal, May 2008

  • Anderson, Joshua A.; Lorenz, Chris D.; Travesset, A.
  • Journal of Computational Physics, Vol. 227, Issue 10
  • DOI: 10.1016/j.jcp.2008.01.047

Gelation of particles with short-range attraction
journal, May 2008

  • Lu, Peter J.; Zaccarelli, Emanuela; Ciulla, Fabio
  • Nature, Vol. 453, Issue 7194
  • DOI: 10.1038/nature06931

Rheology of suspensions of weakly attractive particles: Approach to gelation
journal, November 1998

  • Rueb, C. J.; Zukoski, C. F.
  • Journal of Rheology, Vol. 42, Issue 6
  • DOI: 10.1122/1.550966

Structure and dynamics of concentrated dispersions of polystyrene latex spheres in glycerol: Static and dynamic x-ray scattering
journal, December 2000


Equilibrium cluster formation in concentrated protein solutions and colloids
journal, November 2004

  • Stradner, Anna; Sedgwick, Helen; Cardinaux, Frédéric
  • Nature, Vol. 432, Issue 7016
  • DOI: 10.1038/nature03109

Rheological Behavior of Slurries and Consolidated Bodies Containing Mixed Silicon Nitride Networks
journal, August 2000


Publisher's Note: Thermodynamic instabilities of a binary mixture of sticky hard spheres [Phys. Rev. E 72 , 011503 (2005)]
journal, August 2005


Polydisperse systems: Statistical thermodynamics, with applications to several models including hard and permeable spheres
journal, October 1982

  • Salacuse, J. J.; Stell, G.
  • The Journal of Chemical Physics, Vol. 77, Issue 7
  • DOI: 10.1063/1.444274

Analytic methods for the Percus-Yevick hard sphere correlation functions
journal, January 2009


Colloidal gels—low-density disordered solid-like states
journal, April 2004

  • Trappe, Veronique; Sandkühler, Peter
  • Current Opinion in Colloid & Interface Science, Vol. 8, Issue 6
  • DOI: 10.1016/j.cocis.2004.01.002

Simulating asymmetric colloidal mixture with adhesive hard sphere model
journal, June 2008

  • Jamnik, A.
  • The Journal of Chemical Physics, Vol. 128, Issue 23
  • DOI: 10.1063/1.2939120

Equilibrium Route to Colloidal Gelation: Mixtures of Hard-Sphere-Like Colloids
journal, February 2009


Colloidal gelation of oppositely charged particles
journal, January 2012

  • Russell, Emily R.; Sprakel, Joris; Kodger, Thomas E.
  • Soft Matter, Vol. 8, Issue 33
  • DOI: 10.1039/c2sm25901j

Dynamical Arrest in Attractive Colloids: The Effect of Long-Range Repulsion
journal, May 2005

  • Campbell, Andrew I.; Anderson, Valerie J.; van Duijneveldt, Jeroen S.
  • Physical Review Letters, Vol. 94, Issue 20
  • DOI: 10.1103/physrevlett.94.208301

Glasslike Arrest in Spinodal Decomposition as a Route to Colloidal Gelation
journal, December 2005


Gel formation and aging in weakly attractive nanocolloid suspensions at intermediate concentrations
journal, October 2011

  • Guo, Hongyu; Ramakrishnan, S.; Harden, James L.
  • The Journal of Chemical Physics, Vol. 135, Issue 15
  • DOI: 10.1063/1.3653380

Connecting nanoscale motion and rheology of gel-forming colloidal suspensions
journal, May 2010


Large attractive depletion interactions in soft repulsive–sphere binary mixtures
journal, December 2007

  • Cinacchi, Giorgio; Martínez-Ratón, Yuri; Mederos, Luis
  • The Journal of Chemical Physics, Vol. 127, Issue 21
  • DOI: 10.1063/1.2804330

Anomalous Component Dynamics of a Binary Mixture of Associating Glass-Forming Liquids
journal, February 2011

  • Wang, Li-Min; Tian, Yongjun; Liu, Riping
  • The Journal of Physical Chemistry B, Vol. 115, Issue 4
  • DOI: 10.1021/jp1101362

Distribution functions of multi-component fluid mixtures of hard spheres
journal, August 1972


Universal non-diffusive slow dynamics in aging soft matter
journal, September 2002

  • Cipelletti, Luca; Ramos, Laurence; Manley, S.
  • Faraday Discussions, Vol. 123
  • DOI: 10.1039/b204495a

Viscoelastic properties of colloidal gels
journal, March 1997

  • Rueb, C. J.; Zukoski, C. F.
  • Journal of Rheology, Vol. 41, Issue 2
  • DOI: 10.1122/1.550812

Microstructure and Rheology of Thermoreversible Nanoparticle Gels
journal, August 2006

  • Ramakrishnan, S.; Zukoski, C. F.
  • Langmuir, Vol. 22, Issue 18
  • DOI: 10.1021/la060168j

Dynamical Arrest Transition in Nanoparticle Dispersions with Short-Range Interactions
journal, March 2011


Strong scaling of general-purpose molecular dynamics simulations on GPUs
journal, July 2015

  • Glaser, Jens; Nguyen, Trung Dac; Anderson, Joshua A.
  • Computer Physics Communications, Vol. 192
  • DOI: 10.1016/j.cpc.2015.02.028

Entropically Driven Surface Phase Separation in Binary Colloidal Mixtures
journal, January 1994


Microscopic theory of gelation and elasticity in polymer–particle suspensions
journal, April 2004

  • Chen, Yeng-Long; Schweizer, Kenneth S.
  • The Journal of Chemical Physics, Vol. 120, Issue 15
  • DOI: 10.1063/1.1683077

Arrested demixing opens route to bigels
journal, November 2012

  • Varrato, F.; Di Michele, L.; Belushkin, M.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 47
  • DOI: 10.1073/pnas.1214971109

Phase diagram of highly asymmetric binary hard-sphere mixtures
journal, May 1999


Anomalous dynamical light scattering in soft glassy gels
journal, November 2001

  • Bouchaud, J. -P.; Pitard, E.
  • The European Physical Journal E, Vol. 6, Issue 3
  • DOI: 10.1007/s101890170005

Kinetic arrest and glass-glass transition in short-ranged attractive colloids
journal, November 2006


Colloidal gels: equilibrium and non-equilibrium routes
journal, July 2007


Phase diagrams of nearly-hard-sphere binary colloids
journal, October 1995


A density-functional theory study of microphase formation in binary Gaussian mixtures
journal, June 2012