Stabilizing liquid drops of arbitrary shape by the interfacial jamming of nanoparticles

Russell, Thomas P.; Cui, Mengmeng; Emrick, Todd

Title: Stabilizing liquid drops of arbitrary shape by the interfacial jamming of nanoparticles

Patent · Tue Jan 30 00:00:00 EST 2018

OSTI ID:1418993

Russell, Thomas P.; Cui, Mengmeng; Emrick, Todd

A stabilized assembly including a first liquid phase of non-spherical droplets in a second liquid phase, wherein the second liquid phase is immiscible with the first phase, and nanoparticle surfactants assembled at an interface of the non-spherical droplets and the second phase is disclosed. The nanoparticle surfactants include nanoparticles and end-functionalized polymers that can interact through ligand type interactions, and the first phase is stabilized by a disordered, jammed layer of nanoparticle surfactants. A method of preparing a stabilized assembly is also disclosed.

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Research Organization:: The University of Massachusetts, Boston, MA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-04ER46126

Assignee:: THE UNIVERSITY OF MASSACHUSETTS (Boston, MA)

Patent Number(s):: 9,878,296

Application Number:: 14/509,609

OSTI ID:: 1418993

Resource Relation:: Patent File Date: 2014 Oct 08

Country of Publication:: United States

Language:: English

References (20)

Additive particles having superhydrophobic characteristics and coatings and methods of making and using the same Koene, Bryan; Rogers, Martin Emerson; Gunter, Jonas C. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8202614 US Patent Document 8,202,614	patent	June 2012
Liquid-liquid interfacial nanoparticle assemblies Emrick, Todd S.; Russell, Thomas P.; Dinsmore, Anthony D. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040202682 US Patent Application 10/753868; 20040202682	patent-application	October 2004
Shape-Changing Droplet Spicer, Patrick Thomas; Caggioni, Marco; Lenis-Abril, Jessica https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150105347 US Patent Application 14/056160; 20150105347	patent-application	April 2015
Universal robotic gripper based on the jamming of granular material Brown, E.; Rodenberg, N.; Amend, J. Proceedings of the National Academy of Sciences, Vol. 107, Issue 44, p. 18809-18814 https://doi.org/10.1073/pnas.1003250107	journal	October 2010
Stabilizing Liquid Drops in Nonequilibrium Shapes by the Interfacial Jamming of Nanoparticles Cui, M.; Emrick, T.; Russell, T. P. Science, Vol. 342, Issue 6157, p. 460-463 https://doi.org/10.1126/science.1242852	journal	October 2013
Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles Dinsmore, A. D.; Hsu, M. F.; Nikolaides, M. G. Science, Vol. 298, Issue 5595, p. 1006-1009 https://doi.org/10.1126/science.1074868	journal	November 2002
A computational analysis of electrohydrodynamics of a leaky dielectric drop in an electric field Feng, James Q.; Scott, Timothy C. Journal of Fluid Mechanics, Vol. 311, p. 289-326 https://doi.org/10.1017/S0022112096002601	journal	March 1996
Deformation and breakup of Newtonian and non-Newtonian conducting drops in an electric field Ha, Jong-Wook; Yang, Seung-Man Journal of Fluid Mechanics, Vol. 405, p. 131-156 https://doi.org/10.1017/S0022112099007223	journal	February 2000
Bicontinuous emulsions stabilized solely by colloidal particles Herzig, E. M.; White, K. A.; Schofield, A. B. Nature Materials, Vol. 6, Issue 12, p. 966-971 https://doi.org/10.1038/nmat2055	journal	November 2007
Nanoparticle Assembly and Transport at Liquid-Liquid Interfaces Lin, Y.; Skaff, H.; Emrick, T. Science, Vol. 299, Issue 5604, p. 226-229 https://doi.org/10.1126/science.1078616	journal	January 2003
Arrested coalescence in Pickering emulsions Pawar, Amar B.; Caggioni, Marco; Ergun, Roja Soft Matter, Vol. 7, Issue 17, p. 7710-7716 https://doi.org/10.1039/c1sm05457k	journal	January 2011
Electrohydrodynamics: The Taylor-Melcher Leaky Dielectric Model Saville, D. A. Annual Review of Fluid Mechanics, Vol. 29, Issue 1, p. 27-64 https://doi.org/10.1146/annurev.fluid.29.1.27	journal	January 1997
Drops with conical ends in electric and magnetic fields Stone, H. A.; Lister, J. R.; Brenner, M. P. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 455, Issue 1981, p. 329-347 https://doi.org/10.1098/rspa.1999.0316	journal	January 1999
Colloidal Jamming at Interfaces: A Route to Fluid-Bicontinuous Gels Stratford, K.; Adhikari, R.; Pagonabarraga, I. Science, Vol. 309, Issue 5744, p. 2198-2201 https://doi.org/10.1126/science.1116589	journal	September 2005
Mechanics of Interfacial Composite Materials Subramaniam, Anand Bala; Abkarian, Manouk; Mahadevan, L. Langmuir, Vol. 22, Issue 24, p. 10204-10208 https://doi.org/10.1021/la061475s	journal	November 2006
Colloid science: Non-spherical bubbles Bala Subramaniam, Anand; Abkarian, Manouk; Mahadevan, L. Nature, Vol. 438, Issue 7070, p. 930-930 https://doi.org/10.1038/438930a	journal	December 2005
Disintegration of Water Drops in an Electric Field Taylor, G. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 280, Issue 1382, p. 383-397 https://doi.org/10.1098/rspa.1964.0151	journal	July 1964
Three-Dimensional Real-Time Tracking of Nanoparticles at an Oil–Water Interface Du, Kan; Liddle, J. Alexander; Berglund, Andrew J. Langmuir, Vol. 28, Issue 25, p. 9181-9188 https://doi.org/10.1021/la300292r	journal	June 2012
The electrohydrodynamic deformation of drops suspended in liquids in steady and oscillatory electric fields Vizika, O.; Saville, D. A. Journal of Fluid Mechanics, Vol. 239, p. 1-21 https://doi.org/10.1017/S0022112092004294	journal	June 1992
One-Step Fabrication of Supramolecular Microcapsules from Microfluidic Droplets Zhang, J.; Coulston, R. J.; Jones, S. T. Science, Vol. 335, Issue 6069, p. 690-694 https://doi.org/10.1126/science.1215416	journal	February 2012

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