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Title: Sulfur containing nanoporous materials, nanoparticles, methods and applications

Patent ·
OSTI ID:1418805

Sulfur containing nanoparticles that may be used within cathode electrodes within lithium ion batteries include in a first instance porous carbon shape materials (i.e., either nanoparticle shapes or "bulk" shapes that are subsequently ground to nanoparticle shapes) that are infused with a sulfur material. A synthetic route to these carbon and sulfur containing nanoparticles may use a template nanoparticle to form a hollow carbon shape shell, and subsequent dissolution of the template nanoparticle prior to infusion of the hollow carbon shape shell with a sulfur material. Sulfur infusion into other porous carbon shapes that are not hollow is also contemplated. A second type of sulfur containing nanoparticle includes a metal oxide material core upon which is located a shell layer that includes a vulcanized polymultiene polymer material and ion conducting polymer material. The foregoing sulfur containing nanoparticle materials provide the electrodes and lithium ion batteries with enhanced performance.

Research Organization:
Cornell Univ., Ithaca, NY (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0001086
Assignee:
Cornell University (Ithaca, NY)
Patent Number(s):
9,882,199
Application Number:
13/884,314
OSTI ID:
1418805
Resource Relation:
Patent File Date: 2011 Nov 08
Country of Publication:
United States
Language:
English

References (24)

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Lithium-sulfur battery patent-application February 2005
Negative electrode for lithium metal battery and lithium metal battery comprising the same patent-application May 2005
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Controllable Synthesis of Porous Carbon Spheres, and Electrochemical Applications Thereof patent-application April 2011
Autogenic Pressure Reactions For Battery Materials Manufacture patent-application May 2011
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Synthesis of CoOOH Hierarchically Hollow Spheres by Nanorod Self-Assembly through Bubble Templating journal March 2008
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