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Sulfur containing nanoporous materials, nanoparticles, methods and applications

Patent ·
OSTI ID:1418805
Sulfur containing nanoparticles that may be used within cathode electrodes within lithium ion batteries include in a first instance porous carbon shape materials (i.e., either nanoparticle shapes or "bulk" shapes that are subsequently ground to nanoparticle shapes) that are infused with a sulfur material. A synthetic route to these carbon and sulfur containing nanoparticles may use a template nanoparticle to form a hollow carbon shape shell, and subsequent dissolution of the template nanoparticle prior to infusion of the hollow carbon shape shell with a sulfur material. Sulfur infusion into other porous carbon shapes that are not hollow is also contemplated. A second type of sulfur containing nanoparticle includes a metal oxide material core upon which is located a shell layer that includes a vulcanized polymultiene polymer material and ion conducting polymer material. The foregoing sulfur containing nanoparticle materials provide the electrodes and lithium ion batteries with enhanced performance.
Research Organization:
Cornell University, Ithaca, NY (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0001086
Assignee:
Cornell University (Ithaca, NY)
Patent Number(s):
9,882,199
Application Number:
13/884,314
OSTI ID:
1418805
Country of Publication:
United States
Language:
English

References (11)

Porous hollow carbon nanotube composite cages journal January 2006
Controllable Synthesis of Hierarchical Nanostructured Hollow Core/Mesopore Shell Carbon for Electrochemical Hydrogen Storage journal October 2008
Fraction of effective sulfur crosslinking in polybutadiene rubber vulcanizates journal September 1965
Carbon spheres journal September 2010
Lithium storage in conductive sulfur-containing polymers journal November 2004
Sulfur–carbon composite electrode for all-solid-state Li/S battery with Li2S–P2S5 solid electrolyte journal July 2011
Nano-wire networks of sulfur–polypyrrole composite cathode materials for rechargeable lithium batteries journal December 2008
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries journal May 2009
Sulfur–carbon nano-composite as cathode for rechargeable lithium battery based on gel electrolyte journal June 2002
Synthesis of CoOOH Hierarchically Hollow Spheres by Nanorod Self-Assembly through Bubble Templating journal March 2008
Effect of Multiwalled Carbon Nanotubes on Electrochemical Properties of Lithium/Sulfur Rechargeable Batteries journal January 2003

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