Development of nanosized lanthanum strontium aluminum manganite as electrodes for potentiometric oxygen sensor

Mullen, Max R.; Spirig, John V.; Hoy, Julia; Routbort, Jules L.; Singh, Dileep; Dutta, Prabir K.

doi:10.1016/j.snb.2014.07.027

Title: Development of nanosized lanthanum strontium aluminum manganite as electrodes for potentiometric oxygen sensor

Journal Article · Fri Jul 18 00:00:00 EDT 2014 · Sensors and Actuators. B, Chemical

DOI:https://doi.org/10.1016/j.snb.2014.07.027· OSTI ID:1418478

Mullen, Max R. ^[1]; Spirig, John V. ^[1]; Hoy, Julia ^[1]; Routbort, Jules L. ^[2]; Singh, Dileep ^[2]; Dutta, Prabir K. ^[1]

The Ohio State Univ., Columbus, OH (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States)

Nanocrystalline La_0.8Sr_0.2Al_0.9Mn_0.1O₃ (LSAM) was synthesized by a microwave-assisted citrate method, and characterized by electron microscopy and X-ray diffraction. Electrical behavior of LSAM was investigated by impedance spectroscopy and activation energy of conduction was obtained. Joining of sintered bodies of LSAM and yttria-stabilized tetragonal zirconia polycrystals (YTZP), an extensively studied oxygen ion conducting electrolyte, was examined by isostatic hot pressing methods. Characteristics of the joining region were evaluated with microprobe Raman spectroscopy, and products formed at the interface, primarily strontium zirconate, was confirmed by examination of high temperature chemical reaction between LSAM and YTZP powders. Finally, the electrical properties of the LSAM were exploited for development of a high temperature oxygen sensor in which LSAM functioned as the electrode and YTZP as electrolyte.

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Research Organization:: The Ohio State Univ., Columbus, OH (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE

DOE Contract Number:: NSF-PFI 1318136

OSTI ID:: 1418478

Journal Information:: Sensors and Actuators. B, Chemical, Vol. 203, Issue C; ISSN 0925-4005

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

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