A New Insight into Cross-Sensitivity to Humidity of SnO2 Sensor

Zhu, He; Li, Qiang; Ren, Yang; Gao, Qilong; Chen, Jun; Wang, Na; Deng, Jinxia; Xing, Xianran

doi:10.1002/smll.201703974

Title: A New Insight into Cross-Sensitivity to Humidity of SnO₂ Sensor

Journal Article · Mon Jan 29 00:00:00 EST 2018 · Small

DOI:https://doi.org/10.1002/smll.201703974· OSTI ID:1471538

Zhu, He ^[1]; Li, Qiang ^[1]; Ren, Yang ^[2]; Gao, Qilong ^[1]; Chen, Jun ^[1]; Wang, Na ^[1]; Deng, Jinxia ^[1]; Xing, Xianran ^[1]

Univ. of Science and Technology Beijing, Beijing (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

Abstract The efficiency of gas sensors varies enormously from fundamental study to practical application. This big gap comes mainly from the complex and unpredictable effect of atmospheric environment, especially in humidity. Here, the cross‐sensitivity to humidity of a SnO ₂ sensor from local structural and lattice evolutions is studied. The sensing response of ethanol is found to be efficiently activated by adsorbing trace of water but inhibited as humidity increases. By X‐ray diffraction, pair distribution function of synchrotron and ab initio calculations, the independent effect of water and ethanol on lattice and local structure are clearly revealed, which elucidate the intricate sensing reactions. The formation of hydrogen bonds and repulsion of ethoxides play key roles in the structural distortions, and also in adsorption energies that are critical to the sensitive behavior. The results show the sensor performance coupled with local structural evolution, which provides a new insight into the controversial effects of humidity on SnO ₂ sensors.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities

Grant/Contract Number:: AC02-06CH11357; AC02‐06CH11357

OSTI ID:: 1471538

Alternate ID(s):: OSTI ID: 1418415

Journal Information:: Small, Vol. 14, Issue 13; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 33 works

Citation information provided by
Web of Science

References (44)

Interfacial oxidation–dehydration induced formation of porous SnO2 hollow nanospheres and their gas sensing properties Ma, Xicheng; Song, Haiyan; Guan, Congsheng Sensors and Actuators B: Chemical, Vol. 177 https://doi.org/10.1016/j.snb.2012.10.127	journal	February 2013
Hydration and Thermal Expansion in Anatase Nanoparticles Zhu, He; Li, Qiang; Ren, Yang Advanced Materials, Vol. 28, Issue 32 https://doi.org/10.1002/adma.201600973	journal	June 2016
Detection of CO and O2 Using Tin Oxide Nanowire Sensors Kolmakov, A.; Zhang, Y.; Cheng, G. Advanced Materials, Vol. 15, Issue 12 https://doi.org/10.1002/adma.200304889	journal	June 2003
Basic interpretation of thick film gas sensors for atmospheric application Carotta, Maria Cristina; Benetti, Michele; Ferrari, Elena Sensors and Actuators B: Chemical, Vol. 126, Issue 2 https://doi.org/10.1016/j.snb.2007.04.016	journal	October 2007
Pd Size Effect on the Gas Sensing Properties of Pd-Loaded SnO ₂ in Humid Atmosphere Ma, Nan; Suematsu, Koichi; Yuasa, Masayoshi ACS Applied Materials & Interfaces, Vol. 7, Issue 28 https://doi.org/10.1021/acsami.5b04380	journal	July 2015
Effect of Water Vapor on Pd-Loaded SnO ₂ Nanoparticles Gas Sensor Ma, Nan; Suematsu, Koichi; Yuasa, Masayoshi ACS Applied Materials & Interfaces, Vol. 7, Issue 10 https://doi.org/10.1021/am509082w	journal	March 2015
Experimental and theoretical studies on noble metal decorated tin oxide flower-like nanorods with high ethanol sensing performance Kaneti, Yusuf V.; Yue, Jeffrey; Moriceau, Julien Sensors and Actuators B: Chemical, Vol. 219 https://doi.org/10.1016/j.snb.2015.04.136	journal	November 2015
Entropic contributions enhance polarity compensation for CeO2(100) surfaces Capdevila-Cortada, Marçal; López, Núria Nature Materials, Vol. 16, Issue 3 https://doi.org/10.1038/nmat4804	journal	November 2016
The adsorption of H2O on TiO2 and SnO2(110) studied by first-principles calculations Goniakowski, J.; Gillan, M. J. Surface Science, Vol. 350, Issue 1-3 https://doi.org/10.1016/0039-6028(95)01252-4	journal	April 1996
Polarity in Oxide Nano-objects Noguera, Claudine; Goniakowski, Jacek Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr3003032	journal	December 2012
The surface and materials science of tin oxide Batzill, Matthias; Diebold, Ulrike Progress in Surface Science, Vol. 79, Issue 2-4, p. 47-154 https://doi.org/10.1016/j.progsurf.2005.09.002	journal	January 2005
High-Sensitivity Humidity Sensor Based on a Single SnO ₂ Nanowire Kuang, Qin; Lao, Changshi; Wang, Zhong Lin Journal of the American Chemical Society, Vol. 129, Issue 19 https://doi.org/10.1021/ja070788m	journal	May 2007
Small hydrocarbon adsorbates on SnO2(110) surfaces: Density functional theory study Viitala, M.; Cramariuc, O.; Rantala, T. T. Surface Science, Vol. 602, Issue 18 https://doi.org/10.1016/j.susc.2008.08.001	journal	September 2008
The selective detection of C2H5OH using SnO2–ZnO thin film gas sensors prepared by combinatorial solution deposition Kim, Ki-Won; Cho, Pyeong-Seok; Kim, Sun-Jung Sensors and Actuators B: Chemical, Vol. 123, Issue 1 https://doi.org/10.1016/j.snb.2006.08.028	journal	April 2007
Sensing Mechanism of SnO ₂ (110) Surface to CO: Density Functional Theory Calculations Wang, Xiaofeng; Qin, Hongwei; Chen, Yanping The Journal of Physical Chemistry C, Vol. 118, Issue 49 https://doi.org/10.1021/jp501880r	journal	November 2014
Gas-phase-dependent properties of $Sn O_{2}$ (110), (100), and (101) single-crystal surfaces: Structure, composition, and electronic properties Batzill, Matthias; Katsiev, Khabibulakh; Burst, James M. Physical Review B, Vol. 72, Issue 16 https://doi.org/10.1103/PhysRevB.72.165414	journal	October 2005
The Role of NiO Doping in Reducing the Impact of Humidity on the Performance of SnO2-Based Gas Sensors: Synthesis Strategies, and Phenomenological and Spectroscopic Studies Kim, Hae-Ryong; Haensch, Alexander; Kim, Il-Doo Advanced Functional Materials, Vol. 21, Issue 23 https://doi.org/10.1002/adfm.201101154	journal	September 2011
Highly sensitive carbon nanotubes–SnO2 nanocomposite sensor for acetone detection in diabetes mellitus breath Salehi, Sara; Nikan, Ehsan; Khodadadi, Abbas Ali Sensors and Actuators B: Chemical, Vol. 205 https://doi.org/10.1016/j.snb.2014.08.082	journal	December 2014
Ceria-doped SnO2 sensor highly selective to ethanol in humid air Pourfayaz, F.; Mortazavi, Y.; Khodadadi, A. Sensors and Actuators B: Chemical, Vol. 130, Issue 2 https://doi.org/10.1016/j.snb.2007.10.018	journal	March 2008
Fundamental studies on SnO2 by means of simultaneous work function change and conduction measurements Sahm, T.; Gurlo, A.; Bârsan, N. Thin Solid Films, Vol. 490, Issue 1 https://doi.org/10.1016/j.tsf.2005.04.013	journal	October 2005
Materials and Transducers Toward Selective Wireless Gas Sensing Potyrailo, Radislav A.; Surman, Cheryl; Nagraj, Nandini Chemical Reviews, Vol. 111, Issue 11, p. 7315-7354 https://doi.org/10.1021/cr2000477	journal	November 2011
A Solution-Phase, Precursor Route to Polycrystalline SnO₂ Nanowires That Can Be Used for Gas Sensing under Ambient Conditions Wang, Yuliang; Jiang, Xuchuan; Xia, Younan Journal of the American Chemical Society, Vol. 125, Issue 52, p. 16176-16177 https://doi.org/10.1021/ja037743f	journal	December 2003
Water pre-adsorption effect on room temperature SnO2 nanobelt ethanol sensitivity in oxygen-deficient conditions Li, M.; Qiao, L. J.; Chu, W. Y. Sensors and Actuators B: Chemical, Vol. 158, Issue 1 https://doi.org/10.1016/j.snb.2011.06.031	journal	November 2011
Hydrothermal Synthesis of SnO ₂ Nanoparticles and Their Gas-Sensing of Alcohol Chiu, Hui-Chi; Yeh, Chen-Sheng The Journal of Physical Chemistry C, Vol. 111, Issue 20 https://doi.org/10.1021/jp0688355	journal	May 2007
Ternary Pt/Rh/SnO₂ electrocatalysts for oxidizing ethanol to CO₂ Kowal, A.; Li, M.; Shao, M. Nature Materials, Vol. 8, Issue 4, p. 325-330 https://doi.org/10.1038/nmat2359	journal	January 2009
SnO2: A comprehensive review on structures and gas sensors Das, Soumen; Jayaraman, V. Progress in Materials Science, Vol. 66 https://doi.org/10.1016/j.pmatsci.2014.06.003	journal	October 2014
Adsorption of the OH Group on SnO ₂ (110) Oxygen Bridges: A Molecular Dynamics and Density Functional Theory Study Yue, Jeffrey; Jiang, Xuchuan; Yu, Aibing The Journal of Physical Chemistry C, Vol. 117, Issue 19 https://doi.org/10.1021/jp4022294	journal	May 2013
Moisture influence and geometry effect of Au and Pt electrodes on CO sensing response of SnO2 microsensors based on sol–gel thin film Capone, S.; Siciliano, P.; Quaranta, F. Sensors and Actuators B: Chemical, Vol. 77, Issue 1-2 https://doi.org/10.1016/S0925-4005(01)00754-7	journal	June 2001
Large-Scale, Solution-Phase Growth of Single-Crystalline SnO ₂ Nanorods Cheng, Bin; Russell, Joette M. Journal of the American Chemical Society, Vol. 126, Issue 19 https://doi.org/10.1021/ja0493244	journal	May 2004
Free Energy and Electronic Properties of Water Adsorption on the SnO ₂ (110) Surface Santarossa, Gianluca; Hahn, Konstanze; Baiker, Alfons Langmuir, Vol. 29, Issue 18 https://doi.org/10.1021/la400313a	journal	April 2013
Sensitive Room-Temperature H ₂ S Gas Sensors Employing SnO ₂ Quantum Wire/Reduced Graphene Oxide Nanocomposites Song, Zhilong; Wei, Zeru; Wang, Baocun Chemistry of Materials, Vol. 28, Issue 4 https://doi.org/10.1021/acs.chemmater.5b04850	journal	February 2016
The structure of the stoichiometric and reduced SnO2(110) surface Manassidis, I.; Goniakowski, J.; Kantorovich, L. N. Surface Science, Vol. 339, Issue 3 https://doi.org/10.1016/0039-6028(95)00677-X	journal	October 1995
Two-dimensional net-like SnO ₂ /ZnO heteronanostructures for high-performance H ₂ S gas sensor Fu, Diyu; Zhu, Chunling; Zhang, Xitian Journal of Materials Chemistry A, Vol. 4, Issue 4 https://doi.org/10.1039/C5TA09190J	journal	January 2016
Metal Chelation Assisted In Situ Migration and Functionalization of Catalysts on Peapod-Like Hollow SnO ₂ toward a Superior Chemical Sensor Jang, Ji-Soo; Yu, Sunmoon; Choi, Seon-Jin Small, Vol. 12, Issue 43 https://doi.org/10.1002/smll.201602204	journal	September 2016
Role of surface hydroxyl groups in promoting room temperature CO sensing by Pd-modified nanocrystalline SnO2 Marikutsa, Artem V.; Rumyantseva, Marina N.; Yashina, Lada V. Journal of Solid State Chemistry, Vol. 183, Issue 10 https://doi.org/10.1016/j.jssc.2010.07.017	journal	October 2010
Interplay between Water and ${TiO}_{2}$ Anatase (101) Surface with Subsurface Oxygen Vacancy Li, Yadong; Gao, Yi Physical Review Letters, Vol. 112, Issue 20 https://doi.org/10.1103/PhysRevLett.112.206101	journal	May 2014
Synthesis of Tin Dioxide Octahedral Nanoparticles with Exposed High-Energy {221} Facets and Enhanced Gas-Sensing Properties Han, Xiguang; Jin, Mingshang; Xie, Shuifen Angewandte Chemie International Edition, Vol. 48, Issue 48 https://doi.org/10.1002/anie.200903926	journal	November 2009
Thermodynamic argument about SnO2 nanoribbon growth Beltrán, A.; Andrés, J.; Longo, E. Applied Physics Letters, Vol. 83, Issue 4 https://doi.org/10.1063/1.1594837	journal	July 2003
Facile Fabrication of MoS ₂ -Modified SnO ₂ Hybrid Nanocomposite for Ultrasensitive Humidity Sensing Zhang, Dongzhi; Sun, Yan’e; Li, Peng ACS Applied Materials & Interfaces, Vol. 8, Issue 22 https://doi.org/10.1021/acsami.6b02206	journal	May 2016
An excellent humidity sensor based on In–SnO ₂ loaded mesoporous graphitic carbon nitride Malik, Ritu; Tomer, Vijay K.; Chaudhary, Vandna Journal of Materials Chemistry A, Vol. 5, Issue 27 https://doi.org/10.1039/C7TA02860A	journal	January 2017
Ultra-fast responding and recovering C2H5OH sensors using SnO2 hollow spheres prepared and activated by Ni templates Kim, Hae-Ryong; Choi, Kwon-Il; Kim, Kang-Min Chemical Communications, Vol. 46, Issue 28 https://doi.org/10.1039/c0cc00213e	journal	January 2010
Comparisons of Multilayer H ₂ O Adsorption onto the (110) Surfaces of α-TiO ₂ and SnO ₂ as Calculated with Density Functional Theory Bandura, Andrei V.; Kubicki, James D.; Sofo, Jorge O. The Journal of Physical Chemistry B, Vol. 112, Issue 37 https://doi.org/10.1021/jp711763y	journal	September 2008
Effects of cobalt doping on nitric oxide, acetone and ethanol sensing performances of FSP-made SnO2 nanoparticles Punginsang, M.; Wisitsora-at, A.; Tuantranont, A. Sensors and Actuators B: Chemical, Vol. 210 https://doi.org/10.1016/j.snb.2015.01.028	journal	April 2015
Some Theorems on the Free Energies of Crystal Surfaces Herring, Conyers Physical Review, Vol. 82, Issue 1 https://doi.org/10.1103/PhysRev.82.87	journal	April 1951

Cited By (5)

Oxygen adsorption on ZrO2-loaded SnO2 gas sensors in humid atmosphere Suematsu, Koichi; Uchino, Hotaka; Mizukami, Takaharu Journal of Materials Science, Vol. 54, Issue 4 https://doi.org/10.1007/s10853-018-3020-y	journal	October 2018
Synthesis, structure, and gas sensing of icicle-like NiO/In2O3 nanocomposites Lee, Ou-Hsiang; Tseng, Wenjea J. Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 16 https://doi.org/10.1007/s10854-019-01888-8	journal	July 2019
Growth mechanism of SnC ₂ H ₄ O ₂ nanowires prepared by the polyol process as SnO ₂ precursor nanowires Park, DongKook; Lee, Man Sig RSC Advances, Vol. 9, Issue 6 https://doi.org/10.1039/c8ra09738k	journal	January 2019
Heptazine based organic framework as a chemiresistive sensor for ammonia detection at room temperature Sharma, Nidhi; Sharma, Neha; Srinivasan, Parthasarathy Journal of Materials Chemistry A, Vol. 6, Issue 38 https://doi.org/10.1039/c8ta06937a	journal	January 2018
SnO ₂ nanosheets with multifunctional properties for flexible gas-sensors and UVA light detectors Radović, Marko; Dubourg, Georges; Dohčević-Mitrović, Zorana Journal of Physics D: Applied Physics, Vol. 52, Issue 38 https://doi.org/10.1088/1361-6463/ab2d1b	journal	July 2019

Figures / Tables (2)

Figure 1(p. 12)

Figure 3(p. 14)

Similar Records

Novel chemoresistive CH₄ sensor with 10 ppm sensitivity based on multiwalled carbon nanotubes functionalized with SnO₂ nanocrystals

Journal Article · Mon Nov 30 00:00:00 EST 2015 · Journal of Vacuum Science and Technology A · OSTI ID:1471538

Humayun, Md Tanim; Divan, Ralu; Liu, Yuzi; +3 more

Novel chemoresistive CH₄ sensor with 10 ppm sensitivity based on multiwalled carbon nanotubes functionalized with SnO₂ nanocrystals

Journal Article · Fri Jan 01 00:00:00 EST 2016 · Journal of Vacuum Science and Technology A · OSTI ID:1471538

Humayun, Md Tanim; Divan, Ralu; Liu, Yuzi; +3 more

Structural, optical and ethanol sensing properties of Cu-doped SnO{sub 2} nanowires

Journal Article · Thu Apr 24 00:00:00 EDT 2014 · AIP Conference Proceedings · OSTI ID:1471538

Johari, Anima; Sharma, Manish; Johari, Anoopshi; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ethanol sensors
humidity effect
local structures
nanosized SnO2
thermal expansion

Title: A New Insight into Cross-Sensitivity to Humidity of SnO2 Sensor

Citation Formats