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Title: Cross-linked polymeric membranes for carbon dioxide separation

Abstract

A membrane useful in gas separation, the membrane comprising a cross-linked polysiloxane structure having a cross-link density of about 0.1.times.10.sup.-5 mol/cm.sup.3 to about 6.times.10.sup.-5 mol/cm.sup.3, where, in particular embodiments, the cross-linked polysiloxane structure has the following general structure: ##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are independently selected from hydrocarbon groups having at least 1 and up to 6 carbon atoms; A.sup.1 and A.sup.2 are independently selected from cyclic hydrocarbon groups; L.sup.1 and L.sup.2 are linking groups or covalent bonds; n is an integer of at least 1; r and s are independently selected from integers of at least 1; and p is an integer of at least 10. The invention also includes methods for making and using the above-described membranes for gas separation.

Inventors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1417966
Patent Number(s):
9,873,094
Application Number:
14/826,338
Assignee:
UT-Battelle, LLC (Oak Ridge, TN); University of Tennessee Research Foundation (Knoxville, TN)
DOE Contract Number:  
AC05-00OR22725
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Aug 14
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Hong, Tao, Chatterjee, Sabornie, Mahurin, Shannon Mark, Long, Brian Keith, Jiang, De-en, Mays, Jimmy Wayne, Sokolov, Alexei P., and Saito, Tomonori. Cross-linked polymeric membranes for carbon dioxide separation. United States: N. p., 2018. Web.
Hong, Tao, Chatterjee, Sabornie, Mahurin, Shannon Mark, Long, Brian Keith, Jiang, De-en, Mays, Jimmy Wayne, Sokolov, Alexei P., & Saito, Tomonori. Cross-linked polymeric membranes for carbon dioxide separation. United States.
Hong, Tao, Chatterjee, Sabornie, Mahurin, Shannon Mark, Long, Brian Keith, Jiang, De-en, Mays, Jimmy Wayne, Sokolov, Alexei P., and Saito, Tomonori. Tue . "Cross-linked polymeric membranes for carbon dioxide separation". United States. https://www.osti.gov/servlets/purl/1417966.
@article{osti_1417966,
title = {Cross-linked polymeric membranes for carbon dioxide separation},
author = {Hong, Tao and Chatterjee, Sabornie and Mahurin, Shannon Mark and Long, Brian Keith and Jiang, De-en and Mays, Jimmy Wayne and Sokolov, Alexei P. and Saito, Tomonori},
abstractNote = {A membrane useful in gas separation, the membrane comprising a cross-linked polysiloxane structure having a cross-link density of about 0.1.times.10.sup.-5 mol/cm.sup.3 to about 6.times.10.sup.-5 mol/cm.sup.3, where, in particular embodiments, the cross-linked polysiloxane structure has the following general structure: ##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are independently selected from hydrocarbon groups having at least 1 and up to 6 carbon atoms; A.sup.1 and A.sup.2 are independently selected from cyclic hydrocarbon groups; L.sup.1 and L.sup.2 are linking groups or covalent bonds; n is an integer of at least 1; r and s are independently selected from integers of at least 1; and p is an integer of at least 10. The invention also includes methods for making and using the above-described membranes for gas separation.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {1}
}

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Works referenced in this record:

Synthesis of High Molecular Weight Poly[3-{tris(trimethylsiloxy)silyl}tricyclononenes-7] and Their Gas Permeation Properties
journal, September 2011

  • Bermeshev, Maxim V.; Syromolotov, Aleksander V.; Gringolts, Maria L.
  • Macromolecules, Vol. 44, Issue 17, p. 6637-6640
  • DOI: 10.1021/ma201486d

An Efficient Polymer Molecular Sieve for Membrane Gas Separations
journal, January 2013


The group separation of the rare-earth elements and yttrium from geologic materials by cation-exchange chromatography
journal, August 1984


Advances in high permeability polymeric membrane materials for CO2 separations
journal, January 2012

  • Du, Naiying; Park, Ho Bum; Dal-Cin, Mauro M.
  • Energy & Environmental Science, Vol. 5, Issue 6, p. 7306-7322
  • DOI: 10.1039/C1EE02668B

Polymer nanosieve membranes for CO2-capture applications
journal, April 2011

  • Du, Naiying; Park, Ho Bum; Robertson, Gilles P.
  • Nature Materials, Vol. 10, Issue 5, p. 372-375
  • DOI: 10.1038/nmat2989

Addition-Type Polynorbornenes with Si(CH3)3 Side Groups:  Synthesis, Gas Permeability, and Free Volume
journal, October 2006

  • Finkelshtein, E. Sh.; Makovetskii, K. L.; Gringolts, M. L.
  • Macromolecules, Vol. 39, Issue 20, p. 7022-7029
  • DOI: 10.1021/ma061215h

Ring Opening Metathesis Polymerization of Norbornene and Derivatives by the Triply Bonded Ditungsten Complex Na[W2(µ-Cl)3Cl4(THF)2]·(THF)3
journal, November 2012

  • Floros, Georgios; Saragas, Nikolaos; Paraskevopoulou, Patrina
  • Polymers, Vol. 4, Issue 4, p. 1657-1673
  • DOI: 10.3390/polym4041657

Unprecedented high-temperature CO2 selectivity in N2-phobic nanoporous covalent organic polymers
journal, January 2013

  • Patel, Hasmukh A.; Hyun Je, Sang; Park, Joonho
  • Nature Communications, Vol. 4, Article No. 1357
  • DOI: 10.1038/ncomms2359

Ab Initio Screening of CO2-philic Groups
journal, April 2015

  • Tian, Ziqi; Saito, Tomonori; Jiang, De-en
  • The Journal of Physical Chemistry A, Vol. 119, Issue 16, p. 3848-3852
  • DOI: 10.1021/acs.jpca.5b01892