Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman
Abstract
Raman spectra and velocimetry of shocked PBX 9502 (plastic bonded explosive composed of 95% triaminotrinitrobenzene (TATB) and 5% 3M Company Kel F-800 polymer binder) are reported with the Stokes/anti-Stokes ratio used to determine temperature after the shock reflects from a lithium fluoride window. Final pressures up to 14.5 GPa were tested, but the pressure induced absorption of TATB caused the Raman signal to decrease exponentially with pressure. The reflected shock temperature could be determined to 7 GPa, with an average increase of 14.9 K/GPa. Suggestions to adapt the technique to permit thermometry at higher temperatures are discussed, as are comparisons to a recently proposed equation of state for PBX 9502.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1481130
- Alternate Identifier(s):
- OSTI ID: 1417941
- Report Number(s):
- LA-UR-17-30515
Journal ID: ISSN 0021-8979
- Grant/Contract Number:
- AC52-06NA25396
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 123; Journal Issue: 4; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Explosives; PBX 9502; shock; temperature; Raman
Citation Formats
Mcgrane, Shawn David, Aslam, Tariq Dennis, Pierce, Timothy Henry, Hare, Steven John, and Byers, Mark Ellis. Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman. United States: N. p., 2018.
Web. doi:10.1063/1.5016287.
Mcgrane, Shawn David, Aslam, Tariq Dennis, Pierce, Timothy Henry, Hare, Steven John, & Byers, Mark Ellis. Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman. United States. https://doi.org/10.1063/1.5016287
Mcgrane, Shawn David, Aslam, Tariq Dennis, Pierce, Timothy Henry, Hare, Steven John, and Byers, Mark Ellis. 2018.
"Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman". United States. https://doi.org/10.1063/1.5016287. https://www.osti.gov/servlets/purl/1481130.
@article{osti_1481130,
title = {Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman},
author = {Mcgrane, Shawn David and Aslam, Tariq Dennis and Pierce, Timothy Henry and Hare, Steven John and Byers, Mark Ellis},
abstractNote = {Raman spectra and velocimetry of shocked PBX 9502 (plastic bonded explosive composed of 95% triaminotrinitrobenzene (TATB) and 5% 3M Company Kel F-800 polymer binder) are reported with the Stokes/anti-Stokes ratio used to determine temperature after the shock reflects from a lithium fluoride window. Final pressures up to 14.5 GPa were tested, but the pressure induced absorption of TATB caused the Raman signal to decrease exponentially with pressure. The reflected shock temperature could be determined to 7 GPa, with an average increase of 14.9 K/GPa. Suggestions to adapt the technique to permit thermometry at higher temperatures are discussed, as are comparisons to a recently proposed equation of state for PBX 9502.},
doi = {10.1063/1.5016287},
url = {https://www.osti.gov/biblio/1481130},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 4,
volume = 123,
place = {United States},
year = {Wed Jan 24 00:00:00 EST 2018},
month = {Wed Jan 24 00:00:00 EST 2018}
}
Web of Science
Works referenced in this record:
Single-pulse Raman scattering study of triaminotrinitrobenzene under shock compression
journal, October 1988
- Trott, Wayne M.; Renlund, Anita M.
- The Journal of Physical Chemistry, Vol. 92, Issue 21
Temperature measurement of carbon tetrachloride under laser shock compression by nanosecond Raman spectroscopy
journal, September 2007
- Sato, Akira; Oguchi, Shiro; Nakamura, Kazutaka G.
- Chemical Physics Letters, Vol. 445, Issue 1-3
Optimization of the Rolling-Circle Filter for Raman Background Subtraction
journal, March 2006
- Brandt, N. N.; Brovko, O. O.; Chikishev, A. Y.
- Applied Spectroscopy, Vol. 60, Issue 3
Phenomenological model of shock initiation in heterogeneous explosives
journal, January 1980
- Lee, E. L.; Tarver, C. M.
- Physics of Fluids, Vol. 23, Issue 12
Quantitative Tradeoffs between Spatial, Temporal, and Thermometric Resolution of Nonresonant Raman Thermometry for Dynamic Experiments
journal, November 2014
- McGrane, Shawn D.; Moore, David S.; Goodwin, Peter M.
- Applied Spectroscopy, Vol. 68, Issue 11
Equation of state and reaction rate for condensed-phase explosives
journal, September 2005
- Wescott, B. L.; Stewart, D. Scott; Davis, W. C.
- Journal of Applied Physics, Vol. 98, Issue 5
Compact system for high-speed velocimetry using heterodyne techniques
journal, August 2006
- Strand, O. T.; Goosman, D. R.; Martinez, C.
- Review of Scientific Instruments, Vol. 77, Issue 8
Front curvature analysis and detonation shock dynamics calibration for pure and sensitized nitromethane
conference, January 2000
- Hill, L. G.
- Shock compression of condensed matter, AIP Conference Proceedings
The SURF model and the curvature effect for PBX 9502
journal, December 2012
- Menikoff, Ralph; Shaw, M. Sam
- Combustion Theory and Modelling, Vol. 16, Issue 6
Use of time-resolved Raman scattering to determine temperatures in shocked carbon tetrachloride
journal, May 1997
- Pangilinan, G. I.; Gupta, Y. M.
- Journal of Applied Physics, Vol. 81, Issue 10
Measurements of shock initiation in the tri-amino-tri-nitro-benzene based explosive PBX 9502: Wave forms from embedded gauges and comparison of four different material lots
journal, June 2006
- Gustavsen, R. L.; Sheffield, S. A.; Alcon, R. R.
- Journal of Applied Physics, Vol. 99, Issue 11
Kinetics in Solids
journal, October 1997
- Vyazovkin, S.; Wight, C. A.
- Annual Review of Physical Chemistry, Vol. 48, Issue 1
In-situ Raman spectroscopy and high-speed photography of a shocked triaminotrinitrobenzene based explosive
journal, January 2015
- Saint-Amans, C.; Hébert, P.; Doucet, M.
- Journal of Applied Physics, Vol. 117, Issue 2
Erratum: “ In-situ Raman spectroscopy and high-speed photography of a shocked triaminotrinitrobenzene based explosive” [J. Appl. Phys. 117 , 023102 (2015)]
journal, March 2015
- Saint-Amans, C.; Hébert, P.; Doucet, M.
- Journal of Applied Physics, Vol. 117, Issue 10
Ignition Chemistry in HMX from Thermal Explosion to Detonation
conference, January 2002
- Henson, Bryan F.
- Shock Compression of Condensed Matter - 2001: 12th APS Topical Conference, AIP Conference Proceedings
Raman spectroscopy study of laser-shocked tatb-based explosives
conference, January 2012
- Hebert, Philippe; Bouyer, Viviane; Doucet, Michel
- SHOCK COMPRESSION OF CONDENSED MATTER - 2011: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings
Effect of diethylenetriamine on the structure of detonation waves in nitromethane
journal, July 2013
- Utkin, A. V.; Mochalova, V. M.; Logvinenko, A. A.
- Combustion, Explosion, and Shock Waves, Vol. 49, Issue 4
Direct Measurement of Ultrafast Multiphonon Up-Pumping in High Explosives
journal, August 1994
- Chen, Sheah; Tolbert, William A.; Dlott, Dana D.
- The Journal of Physical Chemistry, Vol. 98, Issue 32
The reactants equation of state for the tri-amino-tri-nitro-benzene (TATB) based explosive PBX 9502
journal, July 2017
- Aslam, Tariq D.
- Journal of Applied Physics, Vol. 122, Issue 3
High Pressure Hugoniot and Reaction Rate Measurements in PBX9501
conference, January 2004
- Sheffield, S. A.
- SHOCK COMPRESSION OF CONDENSED MATTER - 2003: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings
Determining the refractive index of shocked [100] lithium fluoride to the limit of transmissibility
journal, July 2014
- Rigg, P. A.; Knudson, M. D.; Scharff, R. J.
- Journal of Applied Physics, Vol. 116, Issue 3
Light Scattering in Solids II
book, January 1982
- Cardona, Manuel; Güntherodt, Gernot
- Topics in Applied Physics, Vol. 50
Effect of a chemical inhomogeneity on steady-state detonation velocity
journal, January 1980
- Engelke, Ray
- Physics of Fluids, Vol. 23, Issue 5, Article No. 875
Light Scattering in Solids II
journal, December 1982
- Wilkinson, G. R.
- Optica Acta: International Journal of Optics, Vol. 29, Issue 12
Works referencing / citing this record:
Shock temperature dependent rate law for plastic bonded explosives
journal, April 2018
- Aslam, Tariq D.
- Journal of Applied Physics, Vol. 123, Issue 14
Dynamic absorption in optical pyrometry of hot spots in plastic-bonded triaminotrinitrobenzene
journal, May 2019
- Bassett, Will P.; Johnson, Belinda P.; Dlott, Dana D.
- Applied Physics Letters, Vol. 114, Issue 19