Nucleophilic substitution between polysulfides and binders unexpectedly stabilizing lithium sulfur battery
Abstract
Polysulfide shuttling has been the primary cause of failure in lithium-sulfur (Li-S) battery cycling. In this paper, we demonstrate an nucleophilic substitution reaction between polysulfides and binder functional groups can unexpectedly immobilizes the polysulfides. The substitution reaction is verified by UV–visible spectra and X-ray photoelectron spectra. The immobilization of polysulfide is in situ monitored by synchrotron based sulfur K-edge X-ray absorption spectra. The resulting electrodes exhibit initial capacity up to 20.4 mAh/cm2, corresponding to 1199.1 mAh/g based on a micron-sulfur mass loading of 17.0 mg/cm2. The micron size sulfur transformed into nano layer coating on the cathode binder during cycling. Directly usage of nano-size sulfur promotes higher capacity of 33.7 mAh/cm2, which is the highest areal capacity reported in Li-S battery. Finally, this enhance performance is due to the reduced shuttle effect by covalently binding of the polysulfide with the polymer binder.
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Applied Energy Materials Group. Energy Storage and Distributed Resources Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
- Wuhan Univ. of Technology (China). State Key Lab. of Advanced Technology for Materials Synthesis and Processing
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China; National Natural Science Fund for Distinguished Young Scholars (China)
- OSTI Identifier:
- 1417600
- Alternate Identifier(s):
- OSTI ID: 1396405
- Grant/Contract Number:
- AC02-05CH11231; 2016YFA0202603; 51425204
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Nano Energy
- Additional Journal Information:
- Journal Volume: 38; Journal ID: ISSN 2211-2855
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; nucleophilic substitution; poly(vinyl sulfate); carrageenan; chemical binding; high loading electrodes; lithium sulfur battery
Citation Formats
Ling, Min, Zhang, Liang, Zheng, Tianyue, Feng, Jun, Guo, Jinghua, Mai, Liqiang, and Liu, Gao. Nucleophilic substitution between polysulfides and binders unexpectedly stabilizing lithium sulfur battery. United States: N. p., 2017.
Web. doi:10.1016/j.nanoen.2017.05.020.
Ling, Min, Zhang, Liang, Zheng, Tianyue, Feng, Jun, Guo, Jinghua, Mai, Liqiang, & Liu, Gao. Nucleophilic substitution between polysulfides and binders unexpectedly stabilizing lithium sulfur battery. United States. https://doi.org/10.1016/j.nanoen.2017.05.020
Ling, Min, Zhang, Liang, Zheng, Tianyue, Feng, Jun, Guo, Jinghua, Mai, Liqiang, and Liu, Gao. 2017.
"Nucleophilic substitution between polysulfides and binders unexpectedly stabilizing lithium sulfur battery". United States. https://doi.org/10.1016/j.nanoen.2017.05.020. https://www.osti.gov/servlets/purl/1417600.
@article{osti_1417600,
title = {Nucleophilic substitution between polysulfides and binders unexpectedly stabilizing lithium sulfur battery},
author = {Ling, Min and Zhang, Liang and Zheng, Tianyue and Feng, Jun and Guo, Jinghua and Mai, Liqiang and Liu, Gao},
abstractNote = {Polysulfide shuttling has been the primary cause of failure in lithium-sulfur (Li-S) battery cycling. In this paper, we demonstrate an nucleophilic substitution reaction between polysulfides and binder functional groups can unexpectedly immobilizes the polysulfides. The substitution reaction is verified by UV–visible spectra and X-ray photoelectron spectra. The immobilization of polysulfide is in situ monitored by synchrotron based sulfur K-edge X-ray absorption spectra. The resulting electrodes exhibit initial capacity up to 20.4 mAh/cm2, corresponding to 1199.1 mAh/g based on a micron-sulfur mass loading of 17.0 mg/cm2. The micron size sulfur transformed into nano layer coating on the cathode binder during cycling. Directly usage of nano-size sulfur promotes higher capacity of 33.7 mAh/cm2, which is the highest areal capacity reported in Li-S battery. Finally, this enhance performance is due to the reduced shuttle effect by covalently binding of the polysulfide with the polymer binder.},
doi = {10.1016/j.nanoen.2017.05.020},
url = {https://www.osti.gov/biblio/1417600},
journal = {Nano Energy},
issn = {2211-2855},
number = ,
volume = 38,
place = {United States},
year = {Wed May 10 00:00:00 EDT 2017},
month = {Wed May 10 00:00:00 EDT 2017}
}
Web of Science
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