Magnetic properties of Sr3NiIrO6 and Sr3CoIrO6: Magnetic hysteresis with coercive fields of up to 55 T

Singleton, John; Kim, Jae Wook; Topping, Craig V.; Hansen, Anders; Mun, Eun -Deok; Chikara, S.; Lakis, I.; Ghannadzadeh, Saman; Goddard, Paul; Luo, Xuan; Oh, Yoon Seok; Cheong, Sang -Wook; Zapf, Vivien S.

doi:10.1103/PhysRevB.94.224408

Title: Magnetic properties of ${Sr}_{3} {NiIrO}_{6}$ and ${Sr}_{3} {CoIrO}_{6}$ : Magnetic hysteresis with coercive fields of up to 55 T

Journal Article · Thu Dec 08 00:00:00 EST 2016 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.94.224408· OSTI ID:1417167

Singleton, John ^[1]; Kim, Jae Wook ^[2]; Topping, Craig V. ^[3]; Hansen, Anders ^[2]; Mun, Eun -Deok ^[4]; Chikara, S. ^[2]; Lakis, I. ^[2]; Ghannadzadeh, Saman ^[5]; Goddard, Paul ^[6]; Luo, Xuan ^[7]; Oh, Yoon Seok ^[8]; Cheong, Sang -Wook ^[7]; Zapf, Vivien S. ^[2]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Oxford, Oxford (United Kingdom)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Oxford, Oxford (United Kingdom); Univ. of Edinburgh, Edinburgh (United Kingdom)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Simon Fraser Univ., Burnaby, BC (Canada)
Univ. of Oxford, Oxford (United Kingdom)
Univ. of Warwick, Coventry (United Kingdom)
Rutgers Univ., Piscataway, NJ (United States); Pohang Univ. of Science and Technology, Gyungbuk (Republic of Korea)
Rutgers Univ., Piscataway, NJ (United States)

Here, we report extraordinarily large magnetic hysteresis loops in the iridates Sr₃NiIrO₅ and Sr₃CoIrO₆. We find coercive magnetic fields of up to 55 T with switched magnetic moments ≈1μ_B per formula unit in Sr₃NiIrO₆ and coercive fields of up to 52 T with switched moments ≈3μ_B per formula unit in Sr₃CoIrO₆. We propose that the magnetic hysteresis involves the field-induced evolution of quasi-one-dimensional chains in a frustrated triangular configuration. In conclusion, the striking magnetic behavior is likely to be linked to the unusual spin-orbit-entangled local state of the Ir⁴⁺ ion and its potential for anisotropic exchange interactions.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1417167

Alternate ID(s):: OSTI ID: 1334853

Report Number(s):: LA-UR-17-28059; PRBMDO; TRN: US1800998

Journal Information:: Physical Review B, Vol. 94, Issue 22; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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Interplay between single-ion magnetism, single-chain magnetism and long-range ordering in the spin chain oxides Sr _4−x Ca _x Mn ₂ CoO ₉ Seikh, Md. Motin; Caignaert, Vincent; Perez, Olivier Journal of Materials Chemistry C, Vol. 6, Issue 13 https://doi.org/10.1039/c7tc05968j	journal	January 2018
The challenge of spin–orbit-tuned ground states in iridates: a key issues review Cao, Gang; Schlottmann, Pedro Reports on Progress in Physics, Vol. 81, Issue 4 https://doi.org/10.1088/1361-6633/aaa979	journal	February 2018
Partially-disordered to frozen-state crossover induced magnetocaloric properties of the antiferromagnetic one-dimensional spin-chain Sr ₃ CoIrO ₆ Krishna Murthy, J.; Nileena, N.; Vishnugopal, V. S. Materials Research Express, Vol. 6, Issue 5 https://doi.org/10.1088/2053-1591/ab03a4	journal	February 2019
Field-cooling induced giant vertical magnetization shift in frustrated low dimensional spin-chain Sr ₃ NiIrO ₆ system Krishnamurthy, J.; Anil Kumar, P. S. Materials Research Express, Vol. 6, Issue 10 https://doi.org/10.1088/2053-1591/ab3612	journal	August 2019
Fermi surface, possible unconventional fermions, and unusually robust resistive critical fields in the chiral-structured superconductor AuBe Rebar, Drew J.; Birnbaum, Serena M.; Singleton, John arXiv https://doi.org/10.48550/arxiv.1812.02830	text	January 2018
Spin-lattice and electron-phonon coupling in 3$d$/5$d$ hybrid Sr$_3$NiIrO$_6$ O'Neal, Kenneth R.; Paul, Arpita; al-Wahish, Amal arXiv https://doi.org/10.48550/arxiv.1907.09392	text	January 2019

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Title: Magnetic properties of ${Sr}_{3} {NiIrO}_{6}$ and ${Sr}_{3} {CoIrO}_{6}$ : Magnetic hysteresis with coercive fields of up to 55 T