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Title: Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

Abstract

Metal–organic layers stabilize Fe IIor Co II-terpyridine diradical complexes to catalyze alkylazide C sp3–H amination and benzylic C–H borylation, respectively.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [2];  [3]; ORCiD logo [2]; ORCiD logo [4]
  1. Department of Chemistry; University of Chicago; Chicago; USA
  2. Collaborative Innovation Center of Chemistry for Energy Materials; State Key Laboratory of Physical Chemistry of Solid Surfaces; Department of Chemistry; College of Chemistry and Chemical Engineering; Xiamen University
  3. Research Computing Center; University of North Carolina; USA
  4. Department of Chemistry; University of Chicago; Chicago; USA; Collaborative Innovation Center of Chemistry for Energy Materials
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
UNIVERSITYFOREIGN
OSTI Identifier:
1416577
Resource Type:
Journal Article
Resource Relation:
Journal Name: Chemical Science; Journal Volume: 9; Journal Issue: 1
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Lin, Zekai, Thacker, Nathan C., Sawano, Takahiro, Drake, Tasha, Ji, Pengfei, Lan, Guangxu, Cao, Lingyun, Liu, Shubin, Wang, Cheng, and Lin, Wenbin. Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation. United States: N. p., 2017. Web. doi:10.1039/C7SC03537C.
Lin, Zekai, Thacker, Nathan C., Sawano, Takahiro, Drake, Tasha, Ji, Pengfei, Lan, Guangxu, Cao, Lingyun, Liu, Shubin, Wang, Cheng, & Lin, Wenbin. Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation. United States. doi:10.1039/C7SC03537C.
Lin, Zekai, Thacker, Nathan C., Sawano, Takahiro, Drake, Tasha, Ji, Pengfei, Lan, Guangxu, Cao, Lingyun, Liu, Shubin, Wang, Cheng, and Lin, Wenbin. Mon . "Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation". United States. doi:10.1039/C7SC03537C.
@article{osti_1416577,
title = {Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation},
author = {Lin, Zekai and Thacker, Nathan C. and Sawano, Takahiro and Drake, Tasha and Ji, Pengfei and Lan, Guangxu and Cao, Lingyun and Liu, Shubin and Wang, Cheng and Lin, Wenbin},
abstractNote = {Metal–organic layers stabilize FeIIor CoII-terpyridine diradical complexes to catalyze alkylazide Csp3–H amination and benzylic C–H borylation, respectively.},
doi = {10.1039/C7SC03537C},
journal = {Chemical Science},
number = 1,
volume = 9,
place = {United States},
year = {Mon Oct 30 00:00:00 EDT 2017},
month = {Mon Oct 30 00:00:00 EDT 2017}
}