Three-Dimensional Morphological and Chemical Evolution of Nanoporous Stainless Steel by Liquid Metal Dealloying [3D Morphological and Chemical Evolution of Nanoporous Stainless Steel by Liquid Metal Dealloying]

Zhao, Chonghang; Wada, Takeshi; De Andrade, Vincent; Williams, Garth J.; Gelb, Jeff; Li, Li; Thieme, Juergen; Kato, Hidemi; Chen-Wiegart, Yu-chen Karen

doi:10.1021/acsami.7b04659

Title: Three-Dimensional Morphological and Chemical Evolution of Nanoporous Stainless Steel by Liquid Metal Dealloying [3D Morphological and Chemical Evolution of Nanoporous Stainless Steel by Liquid Metal Dealloying]

Journal Article · Mon Sep 04 00:00:00 EDT 2017 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.7b04659· OSTI ID:1416146

^[1]; Wada, Takeshi ^[2]; De Andrade, Vincent ^[3]; Williams, Garth J. ^[4]; Gelb, Jeff ^[5]; Li, Li ^[4]; Thieme, Juergen ^[4]; Kato, Hidemi ^[2]; Chen-Wiegart, Yu-chen Karen ^[6]

Stony Brook Univ., Stony Brook, NY (United States)
Tohoku Univ., Sendai (Japan)
Argonne National Lab. (ANL), Argonne, IL (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Carl Zeiss X-ray Microscopy, Inc., Pleasanton, CA (United States)
Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Nanoporous materials, especially those fabricated by liquid metal dealloying processes, possess great potential in a wide range of applications due to their high surface area, bi-continuous structure—with both open pores for transport and solid phase for conductivity or support—and economical materials cost. Here we used x-ray nano-tomography and x-ray fluorescence microscopy to reveal the three-dimensional (3D) morphology and elemental distribution within materials. Focusing on nanoporous stainless steel, we evaluated the 3D morphology of the dealloying-front and established a quantitative processing-structure-property relationship at a later stage of dealloying. The morphological differences of samples created by liquid metal dealloying and aqueous dealloying methods were also discussed. Here, we concluded that it is particularly important to consider the dealloying, coarsening and densification mechanisms in influencing the performance-determining, critical 3D parameters such as tortuosity, pore size, porosity, curvature and interfacial shape.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0012704

OSTI ID:: 1416146

Alternate ID(s):: OSTI ID: 1434768

Report Number(s):: BNL-203491-2018-JAAM; 137284; TRN: US1800883

Journal Information:: ACS Applied Materials and Interfaces, Vol. 9, Issue 39; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 34 works

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Title: Three-Dimensional Morphological and Chemical Evolution of Nanoporous Stainless Steel by Liquid Metal Dealloying [3D Morphological and Chemical Evolution of Nanoporous Stainless Steel by Liquid Metal Dealloying]

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