skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum

Abstract

The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4$$\bar{4}$$04 are presented. The performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of theKα 1,2emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3dspectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1s -13d -1shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.

Authors:
; ; ; ; ; ORCiD logo;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1415486
DOE Contract Number:
AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Crystallography (Online); Journal Volume: 49; Journal Issue: 5
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; X-ray emission spectroscopy; X-ray optics; inelastic X-ray scattering; quartz crystals; spherical analyzers

Citation Formats

Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., and Stutz, Guillermo E. Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum. United States: N. p., 2016. Web. doi:10.1107/S1600576716010633.
Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., & Stutz, Guillermo E. Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum. United States. doi:10.1107/S1600576716010633.
Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., and Stutz, Guillermo E. Wed . "Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum". United States. doi:10.1107/S1600576716010633.
@article{osti_1415486,
title = {Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum},
author = {Honnicke, Marcelo Goncalves and Bianco, Leonardo M. and Ceppi, Sergio A. and Cusatis, Cesar and Huang, XianRong and Cai, Yong Q. and Stutz, Guillermo E.},
abstractNote = {The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4$\bar{4}$04 are presented. The performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of theKα1,2emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3dspectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1s-13d-1shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.},
doi = {10.1107/S1600576716010633},
journal = {Journal of Applied Crystallography (Online)},
number = 5,
volume = 49,
place = {United States},
year = {Wed Aug 10 00:00:00 EDT 2016},
month = {Wed Aug 10 00:00:00 EDT 2016}
}