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Title: Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum

Abstract

The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4$$\bar{4}$$04 are presented. The performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of theKα 1,2emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3dspectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1s -13d -1shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.

Authors:
; ; ; ; ; ORCiD logo;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1415486
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Journal of Applied Crystallography (Online)
Additional Journal Information:
Journal Volume: 49; Journal Issue: 5; Journal ID: ISSN 1600-5767
Publisher:
International Union of Crystallography
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; X-ray emission spectroscopy; X-ray optics; inelastic X-ray scattering; quartz crystals; spherical analyzers

Citation Formats

Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., and Stutz, Guillermo E. Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum. United States: N. p., 2016. Web. doi:10.1107/S1600576716010633.
Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., & Stutz, Guillermo E. Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum. United States. doi:10.1107/S1600576716010633.
Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., and Stutz, Guillermo E. Wed . "Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum". United States. doi:10.1107/S1600576716010633.
@article{osti_1415486,
title = {Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum},
author = {Honnicke, Marcelo Goncalves and Bianco, Leonardo M. and Ceppi, Sergio A. and Cusatis, Cesar and Huang, XianRong and Cai, Yong Q. and Stutz, Guillermo E.},
abstractNote = {The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4$\bar{4}$04 are presented. The performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of theKα1,2emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3dspectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1s-13d-1shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.},
doi = {10.1107/S1600576716010633},
journal = {Journal of Applied Crystallography (Online)},
issn = {1600-5767},
number = 5,
volume = 49,
place = {United States},
year = {2016},
month = {8}
}

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    Works referencing / citing this record:

    Widths of the Atomic k–n7 Levels
    journal, January 2001

    • Campbell, J. L.; Papp, Tibor
    • Atomic Data and Nuclear Data Tables, Vol. 77, Issue 1
    • DOI: 10.1006/adnd.2000.0848

    Shake process probabilities for outer-shell electrons in atoms with Z ⩽71
    journal, January 2002

    • Kochur, A. G.; Dudenko, A. I.; Petrini, D.
    • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 35, Issue 2
    • DOI: 10.1088/0953-4075/35/2/315

    High-resolution KLM Auger spectra of Ni metal excited by X-rays
    journal, March 2008

    • Egri, S.; Kövér, L.; Drube, W.
    • Journal of Electron Spectroscopy and Related Phenomena, Vol. 162, Issue 3
    • DOI: 10.1016/j.elspec.2007.12.001

    Performance of a spherically bent crystal spectrometer for inelastic scattering experiments with synchrotron X-radiation
    journal, May 1984


    A versatile medium-resolution x-ray emission spectrometer for diamond anvil cell applications
    journal, August 2013

    • Mortensen, D. R.; Seidler, G. T.; Bradley, J. A.
    • Review of Scientific Instruments, Vol. 84, Issue 8
    • DOI: 10.1063/1.4819257

    Use of synchrotron radiation in X-ray diffraction topography
    journal, September 1974


    Core-level binding energies in metals
    journal, January 1980

    • Fuggle, John C.; Mårtensson, Nils
    • Journal of Electron Spectroscopy and Related Phenomena, Vol. 21, Issue 3
    • DOI: 10.1016/0368-2048(80)85056-0

    Multielement spectrometer for efficient measurement of the momentum transfer dependence of inelastic x-ray scattering
    journal, June 2006

    • Fister, T. T.; Seidler, G. T.; Wharton, L.
    • Review of Scientific Instruments, Vol. 77, Issue 6
    • DOI: 10.1063/1.2204581

    Source effects in analyzer-based X-ray phase contrast imaging with conventional sources
    journal, November 2012

    • Hönnicke, M. G.; Manica, J.; Mazzaro, I.
    • Review of Scientific Instruments, Vol. 83, Issue 11
    • DOI: 10.1063/1.4767243

    New version: Grasp2K relativistic atomic structure package
    journal, September 2013


    Examination of Bragg backscattering from crystalline quartz
    journal, December 2005

    • Sutter, John P.; Baron, Alfred Q. R.; Ishikawa, Tetsuya
    • Journal of Physics and Chemistry of Solids, Vol. 66, Issue 12
    • DOI: 10.1016/j.jpcs.2005.09.044

    Radiative and Auger Decay Data for Modeling Nickel K Lines
    journal, December 2008

    • Palmeri, P.; Quinet, P.; Mendoza, C.
    • The Astrophysical Journal Supplement Series, Vol. 179, Issue 2
    • DOI: 10.1086/591965

    A new approach to relativistic multi-configuration quantum mechanics in titanium
    journal, October 2010


    Advances in crystal analyzers for inelastic X-ray scattering
    journal, December 2005

    • Verbeni, R.; Kocsis, M.; Huotari, S.
    • Journal of Physics and Chemistry of Solids, Vol. 66, Issue 12
    • DOI: 10.1016/j.jpcs.2005.09.079

    High-accuracy reconstruction of titanium x-ray emission spectra, including relative intensities, asymmetry and satellites, and ab initio determination of shake magnitudes for transition metals
    journal, December 2012

    • Chantler, C. T.; Lowe, J. A.; Grant, I. P.
    • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 46, Issue 1
    • DOI: 10.1088/0953-4075/46/1/015002

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    Sapphire analyzers for high-resolution X-ray spectroscopy
    journal, November 2007

    • Yavaş, Hasan; Ercan Alp, E.; Sinn, Harald
    • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 582, Issue 1
    • DOI: 10.1016/j.nima.2007.08.095

    Contribution of the [1s3d] shake process to Kα1,2 spectra in 3d elements
    journal, November 2006


    Core and Valence Structures in X-ray Emission Spectra of Chromium Materials
    journal, September 2014

    • Torres Deluigi, María; de Groot, Frank M. F.; López-Díaz, Gastón
    • The Journal of Physical Chemistry C, Vol. 118, Issue 38
    • DOI: 10.1021/jp409622r

    A seven-crystal Johann-type hard x-ray spectrometer at the Stanford Synchrotron Radiation Lightsource
    journal, May 2013

    • Sokaras, D.; Weng, T. -C.; Nordlund, D.
    • Review of Scientific Instruments, Vol. 84, Issue 5
    • DOI: 10.1063/1.4803669