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Title: Sinter-Resistant Platinum Catalyst Supported by Metal-Organic Framework

Authors:
 [1];  [2];  [3];  [4]; ORCiD logo [5];  [6];  [7];  [3];  [4];  [5];  [2];  [5];  [6];  [5];  [4];  [3];  [3];  [8];  [2];  [9] more »; ORCiD logo [10] « less
  1. Materials Science Division, Argonne National Lab, 9700 S Cass Ave. Argonne IL 60439 USA, Nanophotonics Center, Korea Institute of Science and Technology, Seoul 02792 South Korea
  2. Department of Chemistry, Northwestern University, 2145 Sheridan Rd. Evanston IL 60208 USA
  3. Institute for Integrated Catalysis, Pacific Northwest National Lab, P.O. Box 999 Richland WA 99352 USA
  4. X-ray Science Division, Argonne National Lab, 9700 S Cass Ave. Argonne IL 60439 USA
  5. Department of Chemistry, University of Minnesota, 207 Pleasant St. SE Minneapolis MN 55455 USA
  6. Chemical and Biomolecular Engineering, Clemson University, 205 Earle Hall Clemson SC 29634 USA
  7. Chemical Sciences and Engineering Division, Argonne National Lab, 9700 S. Cass Ave. Argonne IL 60439 USA
  8. Institute for Integrated Catalysis, Pacific Northwest National Lab, P.O. Box 999 Richland WA 99352 USA, Department of Chemistry and Catalysis Research Institute, Technische Universität München, Lichtenbergstrasse 4 85748 Garching Germany
  9. Materials Science Division, Argonne National Lab, 9700 S Cass Ave. Argonne IL 60439 USA, Department of Chemistry, Northwestern University, 2145 Sheridan Rd. Evanston IL 60208 USA
  10. Materials Science Division, Argonne National Lab, 9700 S Cass Ave. Argonne IL 60439 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1415320
Grant/Contract Number:
#DE-SC0012702
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Volume: 130; Journal Issue: 4; Related Information: CHORUS Timestamp: 2018-01-16 11:14:31; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Kim, In Soo, Li, Zhanyong, Zheng, Jian, Platero-Prats, Ana E., Mavrandonakis, Andreas, Pellizzeri, Steven, Ferrandon, Magali, Vjunov, Aleksei, Gallington, Leighanne C., Webber, Thomas E., Vermeulen, Nicolaas A., Penn, R. Lee, Getman, Rachel B., Cramer, Christopher J., Chapman, Karena W., Camaioni, Donald M., Fulton, John L., Lercher, Johannes A., Farha, Omar K., Hupp, Joseph T., and Martinson, Alex B. F.. Sinter-Resistant Platinum Catalyst Supported by Metal-Organic Framework. Germany: N. p., 2018. Web. doi:10.1002/ange.201708092.
Kim, In Soo, Li, Zhanyong, Zheng, Jian, Platero-Prats, Ana E., Mavrandonakis, Andreas, Pellizzeri, Steven, Ferrandon, Magali, Vjunov, Aleksei, Gallington, Leighanne C., Webber, Thomas E., Vermeulen, Nicolaas A., Penn, R. Lee, Getman, Rachel B., Cramer, Christopher J., Chapman, Karena W., Camaioni, Donald M., Fulton, John L., Lercher, Johannes A., Farha, Omar K., Hupp, Joseph T., & Martinson, Alex B. F.. Sinter-Resistant Platinum Catalyst Supported by Metal-Organic Framework. Germany. doi:10.1002/ange.201708092.
Kim, In Soo, Li, Zhanyong, Zheng, Jian, Platero-Prats, Ana E., Mavrandonakis, Andreas, Pellizzeri, Steven, Ferrandon, Magali, Vjunov, Aleksei, Gallington, Leighanne C., Webber, Thomas E., Vermeulen, Nicolaas A., Penn, R. Lee, Getman, Rachel B., Cramer, Christopher J., Chapman, Karena W., Camaioni, Donald M., Fulton, John L., Lercher, Johannes A., Farha, Omar K., Hupp, Joseph T., and Martinson, Alex B. F.. 2018. "Sinter-Resistant Platinum Catalyst Supported by Metal-Organic Framework". Germany. doi:10.1002/ange.201708092.
@article{osti_1415320,
title = {Sinter-Resistant Platinum Catalyst Supported by Metal-Organic Framework},
author = {Kim, In Soo and Li, Zhanyong and Zheng, Jian and Platero-Prats, Ana E. and Mavrandonakis, Andreas and Pellizzeri, Steven and Ferrandon, Magali and Vjunov, Aleksei and Gallington, Leighanne C. and Webber, Thomas E. and Vermeulen, Nicolaas A. and Penn, R. Lee and Getman, Rachel B. and Cramer, Christopher J. and Chapman, Karena W. and Camaioni, Donald M. and Fulton, John L. and Lercher, Johannes A. and Farha, Omar K. and Hupp, Joseph T. and Martinson, Alex B. F.},
abstractNote = {},
doi = {10.1002/ange.201708092},
journal = {Angewandte Chemie},
number = 4,
volume = 130,
place = {Germany},
year = 2018,
month = 1
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on January 2, 2019
Publisher's Accepted Manuscript

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  • Developing supported single-site catalysts is an important goal in heterogeneous catalysis, since the well-defined active sites afford opportunities for detailed mechanistic studies, thereby facilitating the design of improved catalysts. We present herein a method for installing Ni ions uniformly and precisely on the node of a Zr-based MOF, NU-1000, in high density and large quantity (denoted as Ni-AIM) using atomic layer deposition (ALD) in a metal–organic framework (MOF) (AIM). Ni-AIM is demonstrated to be an efficient gas-phase hydrogenation catalyst upon activation. The structure of the active sites in Ni-AIM is proposed, revealing its single-site nature. More importantly, due to themore » organic linker used to construct the MOF support, the Ni ions stay isolated throughout the hydrogenation catalysis, in accord with its long-term stability. A quantum chemical characterization of the catalyst and the catalytic process complements the experimental results. With validation of computational modeling protocols, we further targeted ethylene oligomerization catalysis by Ni-AIM guided by theoretical prediction. Given the generality of the AIM methodology, this emerging class of materials should prove ripe for the discovery of new catalysts for the transformation of volatile substrates.« less
  • Platinum is a key catalyst that is invaluable in many important industrial processes such as CO oxidation in catalytic converters, oxidation and reduction reactions in fuel cells, nitric acid production, and petroleum cracking.[1] Many of these applications utilize Pt nanoparticles supported on oxides or porous carbon.[2] However, in practical applications that involve high temperatures (typically higher than 3008C), the Pt nanoparticles tend to lose their specific surface area and thus catalytic activity during operation because of sintering. Recent studies have shown that a porous oxide shell can act as a physical barrier to prevent sintering of unsupported metal nanoparticles and,more » at the same time, provide channels for chemical species to reach the surface of the nanoparticles, thus allowing the catalytic reaction to occur. This concept has been demonstrated in several systems, including Pt@SiO2,[3] Pt@CoO,[4] Pt/CeO2@SiO2,[5] Pd@SiO2,[6] Au@SiO2,[7] Au@SnO2 [8] and Au@ZrO2 [9] core– shell nanostructures. Despite these results, a sinter-resistant system has not been realized in supported Pt nanoparticle catalysts.« less