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Stabilization of battery electrodes using polymer coatings

Patent ·
OSTI ID:1414934
;
An electrochemical device (e.g., a battery (cell)) including: an aqueous electrolyte and one or two electrodes (e.g., an anode and/or a cathode), one or both of which is a Prussian Blue analogue material of the general chemical formula A.sub.xP[R(CN).sub.6-jL.sub.j].sub.z.nH.sub.2O, where: A is a cation; P is a metal cation; R is a transition metal cation; L is a ligand that may be substituted in the place of a CN.sup.- ligand; 0.ltoreq.x.ltoreq.2; 0.ltoreq.z.ltoreq.1; and 0.ltoreq.n.ltoreq.5, the electrode including a polymer coating to reduce capacity loss.
Research Organization:
Natron Energy, Inc., Santa Clara, CA (United States)
Sponsoring Organization:
USDOE
Assignee:
Natron Energy, Inc. (Santa Clara, CA)
Patent Number(s):
9,853,318
Application Number:
13/892,982
OSTI ID:
1414934
Country of Publication:
United States
Language:
English

References (38)

The thermodynamics of the insertion electrochemistry of solid metal hexacyanometallates journal March 2002
Anomalous Non-Prussian Blue Structures and Magnetic Ordering of K2MnII[MnII(CN)6] and Rb2MnII[MnII(CN)6] journal February 2010
Prussian Blue Containing Nafion Composite Film as Rechargeable Battery journal January 1987
Formation of copper(II), zinc(II), silver(I) and lead(II) ferrocyanides journal November 1970
Electrochemical Analysis of Conductive Polymer-Coated LiFePO4 Nanocrystalline Cathodes with Controlled Morphology journal July 2011
Solubilities of some chloride and perchlorate salts in sulfolane journal February 1972
High Affinity of Thallium Ions to Copper Hexacyanoferrate Films journal January 2001
Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues journal June 1986
One-step synthesis and self-organization of polypyrrole ultrathin films inlayed with Prussian blue nanoparticles induced by a drop of toluene solution on water surface journal January 2012
Highly Sensitive Molecularly Imprinted Electrochemical Sensor Based on the Double Amplification by an Inorganic Prussian Blue Catalytic Polymer and the Enzymatic Effect of Glucose Oxidase journal January 2012
Electrochemical behavior of iron-hexacyanoruthenate(II) thin films in aqueous electrolytes: potential analytical and catalytic applications journal June 2001
Über Hexacyanomanganate(I) und Hexacyanorhenat(I) journal December 1958
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
Beiträge zur Komplexchemie des Technetiums. II. Darstellung und Eigenschaften von Kalium-cyanotechnetat(I) journal December 1962
A simple and an efficient strategy to synthesize multi-component nanocomposites for biosensor applications journal January 2012
Photogalvanic behaviour of K3Mn(CN)6 in CN− aqueous solutions journal February 1990
Fabrication of a Cyanide-Bridged Coordination Polymer Electrode for Enhanced Electrochemical Ion Storage Ability journal April 2012
Charge–discharge characteristics of a solid-state Prussian blue secondary cell journal April 2000
Tunable Reaction Potentials in Open Framework Nanoparticle Battery Electrodes for Grid-Scale Energy Storage journal January 2012
Some Performance Characteristics of a Prussian Blue Battery journal January 1985
Core-Multishell Magnetic Coordination Nanoparticles: Toward Multifunctionality on the Nanoscale journal November 2008
The Formal Potentials of Solid Metal Hexacyanometalates journal January 1996
The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2O journal November 1977
Fast disproportionation of hexacyanomanganate(III) in acidic solution. Formation of hexacyanomanganate(IV) and kinetics of its decomposition journal December 1986
Electrochemical studies of the factors influencing the cycle stability of Prussian Blue films journal April 1992
Cyanide complexes of the early transition metals (groups IVa-VIIa) journal November 1975
Fabrication of all-solid-state thin-film secondary cells using hexacyanometallate-based electrode materials journal May 2004
Sulfone-Based Electrolyte Solutions for Rechargeable Magnesium Batteries Using 2,5-Dimethoxy-1,4-benzoquinone Positive Electrode journal January 2014
Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries journal December 2011
A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage journal January 2012
Electrochemical properties and lithium ion solvation behavior of sulfone–ester mixed electrolytes for high-voltage rechargeable lithium cells journal May 2008
The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes journal January 2012
Performance characteristics of zinc hexacyanoferrate/Prussian blue and copper hexacyanoferrate/Prussian blue solid state secondary cells journal December 2000
A secondary cell based on thin layers of zeolite-like nickel hexacyanometallates journal August 1989
Copper hexacyanoferrate battery electrodes with long cycle life and high power journal November 2011
The Color and Electronic Configurations of Prussian Blue journal May 1962
In Situ Investigation of the Electrochemical Reduction of Carbonate Electrolyte Solutions at Graphite Electrodes journal January 1998
Hexacyanoferrate layers as electrodes for secondary cells journal May 1987

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