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Subnanometer to nanometer transition metal CO oxidation catalysts

Patent ·
OSTI ID:1414917
The present invention provides a catalyst defined in part by a conductive substrate; a film overlaying a surface of the substrate; and a plurality of metal clusters supported by the layer, wherein each cluster comprises between 8 and 11 atoms. Further provided is a catalyst defined in part by a conductive substrate; a layer overlaying a surface of the substrate; and a plurality of metal clusters supported by the layer, wherein each cluster comprises at least two metals.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357;
Assignee:
UCHICAGO ARGONNE, LLC (Chicago, IL)
Patent Number(s):
9,849,445
Application Number:
15/276,374
OSTI ID:
1414917
Country of Publication:
United States
Language:
English

References (6)

Size-Dependent Oxygen Activation Efficiency over Pdn/TiO2(110) for the CO Oxidation Reaction
  • Kaden, William E.; Kunkel, William A.; Kane, Matt D.
  • Journal of the American Chemical Society, Vol. 132, Issue 38, p. 13097-13099 https://doi.org/10.1021/ja103347v
journal September 2010
Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters journal February 2012
Pd nanoparticle enhanced re-oxidation of non-stoichiometric TiO2: STM imaging of spillover and a new form of SMSI journal January 1999
Size-dependent catalytic activity and geometries of size-selected Pt clusters on TiO2(110) surfaces journal January 2011
Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument journal May 2014
Generation of intense and cold beam of Pt-Ag bi-element cluster ions having single-composition journal March 2011