Phase Changes of Monosulfoaluminate in NaCl Aqueous Solution

Yoon, Seyoon; Ha, Juyoung; Chae, Sejung Rosie; Kilcoyne, David A.; Jun, Yubin; Oh, Jae Eun; Monteiro, Paulo J. M.

doi:10.3390/ma9050401

Title: Phase Changes of Monosulfoaluminate in NaCl Aqueous Solution

Journal Article · Sat May 21 00:00:00 EDT 2016 · Materials

DOI:https://doi.org/10.3390/ma9050401· OSTI ID:1414742

Yoon, Seyoon ^[1]; Ha, Juyoung ^[2]; Chae, Sejung Rosie ^[3]; Kilcoyne, David A. ^[4]; Jun, Yubin ^[5]; Oh, Jae Eun ^[5]; Monteiro, Paulo J. M. ^[3]

Kyonggi Univ., Suwon (Korea, Republic of). Dept. of Civil Engineering; Ulsan National Inst. of Science and Technology (UNIST), Ulsan (Korea, Republic of). School of Urban and Environmental Engineering
Kean Univ., Union, NJ (United States). School of Environmental and Life Sciences
Univ. of California, Berkeley, CA (United States). Dept. of Civil and Environmental Engineering
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Ulsan National Inst. of Science and Technology (UNIST), Ulsan (Korea, Republic of). School of Urban and Environmental Engineering

Monosulfoaluminate (Ca₄Al₂(SO₄)(OH)₁₂∙6H₂O) plays an important role in anion binding in Portland cement by exchanging its original interlayer ions (SO₄^2- and OH^-) with chloride ions. In this study, scanning transmission X-ray microscope (STXM), X-ray absorption near edge structure (XANES) spectroscopy, and X-ray diffraction (XRD) were used to investigate the phase change of monosulfoaluminate due to its interaction with chloride ions. Pure monosulfoaluminate was synthesized and its powder samples were suspended in 0, 0.1, 1, 3, and 5 M NaCl solutions for seven days. At low chloride concentrations, a partial dissolution of monosulfoaluminate formed ettringite, while, with increasing chloride content, the dissolution process was suppressed. As the NaCl concentration increased, the dominant mechanism of the phase change became ion exchange, resulting in direct phase transformation from monosulfoaluminate to Kuzel’s salt or Friedel’s salt. The phase assemblages of the NaCl-reacted samples were explored using thermodynamic calculations and least-square linear combination (LC) fitting of measured XANES spectra. A comprehensive description of the phase change and its dominant mechanism are discussed.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC); National Research Foundation of Korea (NRF); Ministry of Science, ICT & Future Planning (MISP) (Korea, Republic of)

Grant/Contract Number:: AC02-05CH11231; 2015K000130; NRF-2014R1A1A3052424

OSTI ID:: 1414742

Journal Information:: Materials, Vol. 9, Issue 5; ISSN 1996-1944

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 34 works

Citation information provided by
Web of Science

References (33)

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
The density of cement phases Balonis, M.; Glasser, F. P. Cement and Concrete Research, Vol. 39, Issue 9 https://doi.org/10.1016/j.cemconres.2009.06.005	journal	September 2009
The influence of sulphates on chloride binding and pore solution chemistry Xu, Y. Cement and Concrete Research, Vol. 27, Issue 12 https://doi.org/10.1016/S0008-8846(97)00196-8	journal	December 1997
Chloride binding of cement-based materials subjected to external chloride environment – A review Yuan, Qiang; Shi, Caijun; De Schutter, Geert Construction and Building Materials, Vol. 23, Issue 1 https://doi.org/10.1016/j.conbuildmat.2008.02.004	journal	January 2009
Structural transition of Friedel's salt 3CaO·Al2O3·CaCl2·10H2O studied by synchrotron powder diffraction Rapin, J. -P.; Renaudin, G.; Elkaim, E. Cement and Concrete Research, Vol. 32, Issue 4 https://doi.org/10.1016/S0008-8846(01)00716-5	journal	April 2002
Studies using 27Al MAS NMR of AFm and AFt phases and the formation of Friedel's salt Jones, M. R.; Macphee, D. E.; Chudek, J. A. Cement and Concrete Research, Vol. 33, Issue 2 https://doi.org/10.1016/S0008-8846(02)00901-8	journal	February 2003
The system CaO-Al2O3-CaCl2-H2O at 23±2 °C and the mechanisms of chloride binding in concrete Brown, Paul; Bothe, James Cement and Concrete Research, Vol. 34, Issue 9 https://doi.org/10.1016/j.cemconres.2004.03.011	journal	September 2004
Chloride binding capacity of various hydrated cement paste systems Delagrave, Anik; Marchand, Jacques; Ollivier, Jean-Pierre Advanced Cement Based Materials, Vol. 6, Issue 1 https://doi.org/10.1016/S1065-7355(97)90003-1	journal	June 1997
Micro-spectroscopic investigation of Al and S speciation in hardened cement paste Wieland, E.; Dähn, R.; Vespa, M. Cement and Concrete Research, Vol. 40, Issue 6 https://doi.org/10.1016/j.cemconres.2010.02.001	journal	June 2010
Stability and solubility relationships in AFm phases Glasser, F. P.; Kindness, A.; Stronach, S. A. Cement and Concrete Research, Vol. 29, Issue 6 https://doi.org/10.1016/S0008-8846(99)00055-1	journal	June 1999
Chloride binding capacity and binding isotherms of OPC pastes and mortars Luping, Tang; Nilsson, Lars-Olof Cement and Concrete Research, Vol. 23, Issue 2 https://doi.org/10.1016/0008-8846(93)90089-R	journal	March 1993
Impact of chloride on the mineralogy of hydrated Portland cement systems Balonis, Magdalena; Lothenbach, Barbara; Le Saout, Gwenn Cement and Concrete Research, Vol. 40, Issue 7 https://doi.org/10.1016/j.cemconres.2010.03.002	journal	July 2010
Uptake of chloride and carbonate ions by calcium monosulfoaluminate hydrate Mesbah, Adel; Cau-dit-Coumes, Céline; Renaudin, Guillaume Cement and Concrete Research, Vol. 42, Issue 8 https://doi.org/10.1016/j.cemconres.2012.05.012	journal	August 2012
Chloride binding into hydrated blended cements: The influence of limestone and alkalinity Ipavec, Andrej; Vuk, Tomaž; Gabrovšek, Roman Cement and Concrete Research, Vol. 48 https://doi.org/10.1016/j.cemconres.2013.02.010	journal	June 2013
Chloride Binding of Cement Estimated by Binding Isotherms of Hydrates Hirao, Hiroshi; Yamada, Kazuo; Takahashi, Haruka Journal of Advanced Concrete Technology, Vol. 3, Issue 1 https://doi.org/10.3151/jact.3.77	journal	January 2005
Chloride ion binding capacity of aluminoferrites Csizmadia, Jolán; Balázs, György; Tamás, Ferenc D. Cement and Concrete Research, Vol. 31, Issue 4 https://doi.org/10.1016/S0008-8846(01)00458-6	journal	April 2001
Friedel’s salt, Ca2Al(OH)6(Cl,OH)·2H2O: its solid solutions and their role in chloride binding Birnin-Yauri, U. A.; Glasser, F. P. Cement and Concrete Research, Vol. 28, Issue 12 https://doi.org/10.1016/S0008-8846(98)00162-8	journal	December 1998
The AFm phase in Portland cement Matschei, T.; Lothenbach, B.; Glasser, F. P. Cement and Concrete Research, Vol. 37, Issue 2 https://doi.org/10.1016/j.cemconres.2006.10.010	journal	February 2007
Mechanism of Friedel's salt formation in cements rich in tri-calcium aluminate Suryavanshi, A. K.; Scantlebury, J. D.; Lyon, S. B. Cement and Concrete Research, Vol. 26, Issue 5 https://doi.org/10.1016/S0008-8846(96)85009-5	journal	May 1996
Study on the expansion of concrete under attack of sulfate and sulfate–chloride ions Zhang, Minghua; Chen, Jiankang; Lv, Yunfeng Construction and Building Materials, Vol. 39 https://doi.org/10.1016/j.conbuildmat.2012.05.003	journal	February 2013
Characterization of the α−β Phase Transition in Friedels Salt (Ca ₂ Al(OH) ₆ Cl·2H ₂ O) by Variable-Temperature ²⁷ Al MAS NMR Spectroscopy Andersen, Morten Daugaard; Jakobsen, Hans J.; Skibsted, Jørgen The Journal of Physical Chemistry A, Vol. 106, Issue 28 https://doi.org/10.1021/jp014573p	journal	July 2002
Solubility of ettringite (Ca6[Al(OH)6]2(SO4)3 · 26H2O) at 5–75°C Perkins, Robert B.; Palmer, Carl D. Geochimica et Cosmochimica Acta, Vol. 63, Issue 13-14 https://doi.org/10.1016/S0016-7037(99)00078-2	journal	July 1999
Impact of chloride-rich environments on cement paste mineralogy Galan, Isabel; Perron, Lucie; Glasser, Fredrik P. Cement and Concrete Research, Vol. 68 https://doi.org/10.1016/j.cemconres.2014.10.017	journal	February 2015
PhreeqC modeling of Friedel's salt equilibria at 23±1 °C Bothe, James V.; Brown, Paul W. Cement and Concrete Research, Vol. 34, Issue 6 https://doi.org/10.1016/j.cemconres.2003.11.016	journal	June 2004
Effect of polymers on the nanostructure and on the carbonation of calcium silicate hydrates: a scanning transmission X-ray microscopy study Ha, J.; Chae, S.; Chou, K. W. Journal of Materials Science, Vol. 47, Issue 2 https://doi.org/10.1007/s10853-011-5877-x	journal	September 2011
Chloride binding in cement II. The influence of the hydroxide concentration in the pore solution of hardened cement paste on chloride binding Tritthart, Josef Cement and Concrete Research, Vol. 19, Issue 5 https://doi.org/10.1016/0008-8846(89)90039-2	journal	September 1989
Mechanism of the CaCl2 attack on portland cement concrete Chatterji, S. Cement and Concrete Research, Vol. 8, Issue 4 https://doi.org/10.1016/0008-8846(78)90026-1	journal	July 1978
Impact of the associated cation on chloride binding of Portland cement paste De Weerdt, K.; Colombo, A.; Coppola, L. Cement and Concrete Research, Vol. 68 https://doi.org/10.1016/j.cemconres.2014.01.027	journal	February 2015
The binding of chloride ions by sulphate resistant portland cement Suryavanshi, A. K.; Scantlebury, J. D.; Lyon, S. B. Cement and Concrete Research, Vol. 25, Issue 3 https://doi.org/10.1016/0008-8846(95)00047-g	journal	April 1995
Delayed ettringite formation Taylor, H. F. W.; Famy, C.; Scrivener, K. L. Cement and Concrete Research, Vol. 31, Issue 5 https://doi.org/10.1016/s0008-8846(01)00466-5	journal	May 2001
Structural phase transition and high temperature phase structure of Friedels salt, 3CaO · Al2O3 · CaCl2 · 10H2O Renaudin, G.; Kubel, F.; Rivera, J. -P. Cement and Concrete Research, Vol. 29, Issue 12 https://doi.org/10.1016/s0008-8846(99)00199-4	journal	December 1999
IFEFFIT : interactive XAFS analysis and FEFF fitting Newville, Matthew Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/s0909049500016964	journal	March 2001
Calcium L -edge XANES study of some calcium compounds Naftel, S. J.; Sham, T. K.; Yiu, Y. M. Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/s0909049500019555	journal	March 2001

Cited By (5)

Effect of TIPA on Chloride Immobilization in Cement-Fly Ash Paste Ma, Baoguo; Zhang, Ting; Tan, Hongbo Advances in Materials Science and Engineering, Vol. 2018 https://doi.org/10.1155/2018/4179421	journal	July 2018
Chloride-Binding Capacity of Portland Cement Paste Blended with Synthesized CA ₂ (CaO·2Al ₂ O ₃ ) Lee, Yunsu; Kim, Mingyun; Chen, Zhengxin Advances in Materials Science and Engineering, Vol. 2018 https://doi.org/10.1155/2018/5418930	journal	January 2018
A Comparison Study for Chloride-Binding Capacity between Alkali-Activated Fly Ash and Slag in the Use of Seawater Jun, Yubin; Yoon, Seyoon; Oh, Jae Applied Sciences, Vol. 7, Issue 10 https://doi.org/10.3390/app7100971	journal	September 2017
Recycling of Reverse Osmosis (RO) Reject Water as a Mixing Water of Calcium Sulfoaluminate (CSA) Cement for Brick Production Lee, Hwan; Jeon, Dongho; Song, Haemin Applied Sciences, Vol. 9, Issue 23 https://doi.org/10.3390/app9235044	journal	November 2019
Chloride Resistance of Portland Cement-Based Mortar Incorporating High Aluminate Cement and Calcium Carbonate Lee, Yunsu; Lim, Seungmin; Lee, Hanseung Materials, Vol. 13, Issue 2 https://doi.org/10.3390/ma13020359	journal	January 2020

Similar Records

Uptake of chloride and carbonate ions by calcium monosulfoaluminate hydrate

Journal Article · Wed Aug 15 00:00:00 EDT 2012 · Cement and Concrete Research · OSTI ID:1414742

Mesbah, Adel; Cau-dit-Coumes, Celine; Renaudin, Guillaume; +2 more

Impact of chloride on the mineralogy of hydrated Portland cement systems

Journal Article · Thu Jul 15 00:00:00 EDT 2010 · Cement and Concrete Research · OSTI ID:1414742

Balonis, Magdalena; Lothenbach, Barbara; Le Saout, Gwenn; +1 more

The hydrothermal decomposition of calcium monosulfoaluminate 14-hydrate to katoite hydrogarnet and beta-anhydrite: An in-situ synchrotron X-ray diffraction study

Journal Article · Thu Oct 15 00:00:00 EDT 2009 · Journal of Solid State Chemistry · OSTI ID:1414742

Meller, Nicola; Kyritsis, Konstantinos; Hall, Christopher

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
cement chemistry
STXM
XANES
chloride
Kuzel's salt
Friedel's salt
monosulfate

Title: Phase Changes of Monosulfoaluminate in NaCl Aqueous Solution

Citation Formats

References (33)

Cited By (5)

Similar Records

Related Subjects