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Title: Nanoporous metal-carbon composite

Abstract

Described here is a metal-carbon composite, comprising (a) a porous three-dimensional scaffold comprising one or more of carbon nanotubes, graphene and graphene oxide, and (b) metal nanoparticles disposed on said porous scaffold, wherein the metal-carbon composite has a density of 1 g/cm.sup.3 or less, and wherein the metal nanoparticles account for 1 wt. % or more of the metal-carbon composite. Also described are methods for making the metal-carbon composite.

Inventors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1414417
Patent Number(s):
9,844,762
Application Number:
14/485,474
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA) LLNL
DOE Contract Number:  
AC52-07NA27344
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Sep 12
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Worsley, Marcus A., Satcher, Joe, Kucheyev, Sergei, Charnvanichborikarn, Supakit, Colvin, Jeffrey, Felter, Thomas, Kim, Sangil, Merrill, Matthew, and Orme, Christine. Nanoporous metal-carbon composite. United States: N. p., 2017. Web.
Worsley, Marcus A., Satcher, Joe, Kucheyev, Sergei, Charnvanichborikarn, Supakit, Colvin, Jeffrey, Felter, Thomas, Kim, Sangil, Merrill, Matthew, & Orme, Christine. Nanoporous metal-carbon composite. United States.
Worsley, Marcus A., Satcher, Joe, Kucheyev, Sergei, Charnvanichborikarn, Supakit, Colvin, Jeffrey, Felter, Thomas, Kim, Sangil, Merrill, Matthew, and Orme, Christine. Tue . "Nanoporous metal-carbon composite". United States. doi:. https://www.osti.gov/servlets/purl/1414417.
@article{osti_1414417,
title = {Nanoporous metal-carbon composite},
author = {Worsley, Marcus A. and Satcher, Joe and Kucheyev, Sergei and Charnvanichborikarn, Supakit and Colvin, Jeffrey and Felter, Thomas and Kim, Sangil and Merrill, Matthew and Orme, Christine},
abstractNote = {Described here is a metal-carbon composite, comprising (a) a porous three-dimensional scaffold comprising one or more of carbon nanotubes, graphene and graphene oxide, and (b) metal nanoparticles disposed on said porous scaffold, wherein the metal-carbon composite has a density of 1 g/cm.sup.3 or less, and wherein the metal nanoparticles account for 1 wt. % or more of the metal-carbon composite. Also described are methods for making the metal-carbon composite.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 19 00:00:00 EST 2017},
month = {Tue Dec 19 00:00:00 EST 2017}
}

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Works referenced in this record:

Graphene Aerogels
patent-application, February 2012


Capillarity-induced filling of carbon nanotubes
journal, January 1993

  • Ajayan, P. M.; lijima, Sumio
  • Nature, Vol. 361, Issue 6410, p. 333-334
  • DOI: 10.1038/361333a0

Metal oxide hydrogen, oxygen, and carbon monoxide sensors for hydrogen setups and cells
journal, June 2007


Superior Thermal Conductivity of Single-Layer Graphene
journal, March 2008

  • Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong
  • Nano Letters, Vol. 8, Issue 3, p. 902-907
  • DOI: 10.1021/nl0731872

Synthesis and Characterization of Copper-Doped Carbon Aerogels
journal, September 2002

  • Baumann, Theodore F.; Fox, Glenn A.; Satcher, Joe H.
  • Langmuir, Vol. 18, Issue 18, p. 7073-7076
  • DOI: 10.1021/la0259003

Electromigration—A brief survey and some recent results
journal, April 1969


Electromigration in thin aluminum films on titanium nitride
journal, April 1976

  • Blech, I. A.
  • Journal of Applied Physics, Vol. 47, Issue 4, p. 1203-1208
  • DOI: 10.1063/1.322842

A miniaturized catalytic gas sensor for hydrogen detection based on stabilized nanoparticles as catalytic layer
journal, October 2013

  • Brauns, E.; Morsbach, E.; Schnurpfeil, G.
  • Sensors and Actuators B: Chemical, Vol. 187, p. 420-425
  • DOI: 10.1016/j.snb.2013.01.037

Glucose sensors made of novel carbon nanotube-gold nanoparticle composites
journal, January 2007


Nanoporous Cu–C composites based on carbon-nanotube aerogels
journal, January 2014

  • Charnvanichborikarn, S.; Shin, S. J.; Worsley, M. A.
  • Journal of Materials Chemistry A, Vol. 2, Issue 4, p. 962-967
  • DOI: 10.1039/C3TA14303A

Synthesis of Cu Nanoparticles and Microsized Fibers by Using Carbon Nanotubes as a Template
journal, June 1999

  • Chen, P.; Wu, X.; Lin, J.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 22, p. 4559-4561
  • DOI: 10.1021/jp983983j

Copper Nanoparticle/Polymer Composites with Antifungal and Bacteriostatic Properties
journal, October 2005

  • Cioffi, Nicola; Torsi, Luisa; Ditaranto, Nicoletta
  • Chemistry of Materials, Vol. 17, Issue 21, p. 5255-5262
  • DOI: 10.1021/cm0505244

Explosion-proof monitoring of hydrocarbons by mechanically stabilised, integrable calorimetric microsensors
journal, October 2003


Antibacterial activity of copper monodispersed nanoparticles into sepiolite
journal, August 2006

  • Esteban-Cubillo, Antonio; Pecharromán, Carlos; Aguilar, Eduardo
  • Journal of Materials Science, Vol. 41, Issue 16, p. 5208-5212
  • DOI: 10.1007/s10853-006-0432-x

Formation of Graphitic Structures in Cobalt- and Nickel-Doped Carbon Aerogels
journal, March 2005

  • Fu, Ruowen; Baumann, Theodore F.; Cronin, Steve
  • Langmuir, Vol. 21, Issue 7, p. 2647-2651
  • DOI: 10.1021/la047344d

The Si planar pellistor: a low-power pellistor sensor in Si thin-film technology
journal, June 1991


Characterization and Mechanical Behavior of Nanoporous Gold
journal, September 2006

  • Hodge, A. M.; Hayes, J. R.; Caro, J. A.
  • Advanced Engineering Materials, Vol. 8, Issue 9, p. 853-857
  • DOI: 10.1002/adem.200600079

Thermopile sensor-devices for the catalytic detection of hydrogen gas
journal, March 2008

  • Houlet, Lionel Fabrice; Shin, Woosuck; Tajima, Kazuki
  • Sensors and Actuators B: Chemical, Vol. 130, Issue 1, p. 200-206
  • DOI: 10.1016/j.snb.2007.07.119

Hydrogen sensors – A review
journal, October 2011

  • Hübert, T.; Boon-Brett, L.; Black, G.
  • Sensors and Actuators B: Chemical, Vol. 157, Issue 2, p. 329-352
  • DOI: 10.1016/j.snb.2011.04.070

Potential of silver nanoparticle-coated polyurethane foam as an antibacterial water filter
journal, January 2005

  • Jain, Prashant; Pradeep, T.
  • Biotechnology and Bioengineering, Vol. 90, Issue 1, p. 59-63
  • DOI: 10.1002/bit.20368

A study on the hydrogen storage capacity of Ni-plated porous carbon nanofibers
journal, August 2008

  • Kim, Byung-Joo; Lee, Young-Seak; Park, Soo-Jin
  • International Journal of Hydrogen Energy, Vol. 33, Issue 15, p. 4112-4115
  • DOI: 10.1016/j.ijhydene.2008.05.077

The thermal decomposition of platinum(II) and (IV) complexes
journal, September 1974


Functionalized Carbon Nanotubes for Molecular Hydrogen Sensors
journal, September 2001


Review of Electrochemical Hydrogen Sensors
journal, March 2009

  • Korotcenkov, Ghenadii; Han, Sang Do; Stetter, Joseph R.
  • Chemical Reviews, Vol. 109, Issue 3, p. 1402-1433
  • DOI: 10.1021/cr800339k

Carbon nanofibre/hydrous RuO2 nanocomposite electrodes for supercapacitors
journal, June 2007


Low-power micro gas sensor
journal, July 1996

  • Lee, Duk-Dong; Chung, Wan-Young; Choi, Man-Sik
  • Sensors and Actuators B: Chemical, Vol. 33, Issue 1-3, p. 147-150
  • DOI: 10.1016/0925-4005(96)01822-9

Micromachined catalytic combustible hydrogen gas sensor
journal, April 2011

  • Lee, Eui-Bok; Hwang, In-Sung; Cha, Jung-Ho
  • Sensors and Actuators B: Chemical, Vol. 153, Issue 2, p. 392-397
  • DOI: 10.1016/j.snb.2010.11.004

Cu2O@reduced graphene oxide composite for removal of contaminants from water and supercapacitors
journal, January 2011

  • Li, Baojun; Cao, Huaqiang; Yin, Gui
  • Journal of Materials Chemistry, Vol. 21, Issue 29, p. 10645-10648
  • DOI: 10.1039/c1jm12135a

Electrostatic-Force-Directed Assembly of Ag Nanocrystals onto Vertically Aligned Carbon Nanotubes
journal, December 2007

  • Lu, Ganhua; Zhu, Liying; Wang, Pengxiang
  • The Journal of Physical Chemistry C, Vol. 111, Issue 48, p. 17919-17922
  • DOI: 10.1021/jp071523x

A sandwich structure of graphene and nickel oxide with excellent supercapacitive performance
journal, January 2011

  • Lv, Wei; Sun, Feng; Tang, Dai-Ming
  • Journal of Materials Chemistry, Vol. 21, Issue 25, p. 9014-9019
  • DOI: 10.1039/c1jm10400d

Low-power, fast, selective nanoparticle-based hydrogen sulfide gas sensor
journal, April 2012

  • Mickelson, William; Sussman, Allen; Zettl, Alex
  • Applied Physics Letters, Vol. 100, Issue 17, Article No. 173110
  • DOI: 10.1063/1.3703761

Gold–silica nanocomposites for the detection of human ovarian cancer cells a preliminary study
journal, July 2007


The thermal stability of graphene in air investigated by Raman spectroscopy
journal, April 2013

  • Nan, Hai Yan; Ni, Zhen Hua; Wang, Jun
  • Journal of Raman Spectroscopy, Vol. 44, Issue 7, p. 1018-1021
  • DOI: 10.1002/jrs.4312

Preparation of MnO2/graphene composite as electrode material for supercapacitors
journal, January 2011

  • Qian, Yong; Lu, Shunbao; Gao, Fenglei
  • Journal of Materials Science, Vol. 46, Issue 10, p. 3517-3522
  • DOI: 10.1007/s10853-011-5260-y

Synthesis of Highly Crystalline sp2-Bonded Boron Nitride Aerogels
journal, September 2013

  • Rousseas, Michael; Goldstein, Anna P.; Mickelson, William
  • ACS Nano, Vol. 7, Issue 10, p. 8540-8546
  • DOI: 10.1021/nn402452p

Planar catalytic combustor film for thermoelectric hydrogen sensor
journal, July 2005

  • Shin, Woosuck; Tajima, Kazuki; Choi, Yeongsoo
  • Sensors and Actuators B: Chemical, Vol. 108, Issue 1-2, p. 455-460
  • DOI: 10.1016/j.snb.2004.12.077

Thermal and gas-sensing properties of a micromachined thermal conductivity sensor for the detection of hydrogen in automotive applications
journal, April 2002


Antimicrobial cellulose acetate nanofibers containing silver nanoparticles
journal, September 2006


Amperometric Gas Sensors - A Review
journal, February 2008

  • Stetter, Joseph R.; Li, Jing
  • Chemical Reviews, Vol. 108, Issue 2, p. 352-366
  • DOI: 10.1021/cr0681039

Carbon nanotube-supported gold nanoparticles as efficient catalysts for selective oxidation of cellobiose into gluconic acid in aqueous medium
journal, January 2009

  • Tan, Xuesong; Deng, Weiping; Liu, Mi
  • Chemical Communications, Vol. 0, Issue 46, p. 7179-7181
  • DOI: 10.1039/b917224f

Tailored cutting of carbon nanotubes and controlled dispersion of metal nanoparticles inside their channels
journal, January 2008

  • Wang, Chuanfu; Guo, Shujing; Pan, Xiulian
  • Journal of Materials Chemistry, Vol. 18, Issue 47, p. 5782-5786
  • DOI: 10.1039/b811560e

Hydrogen Storage Properties of Carbons Doped with Ruthenium, Platinum, and Nickel Nanoparticles
journal, July 2008

  • Wang, Lifeng; Yang, Ralph T.
  • The Journal of Physical Chemistry C, Vol. 112, Issue 32, p. 12486-12494
  • DOI: 10.1021/jp803093w

Nanoporous Gold: From an Ancient Technology to a High-Tech Material
book, January 2012

  • Wittstock, Arne; Biener, Jürgen; Erlebacher, Jonah
  • RSC Nanoscience & Nanotechnology, 264 p.
  • DOI: 10.1039/9781849735285

Synthesis of Graphene Aerogel with High Electrical Conductivity
journal, October 2010

  • Worsley, Marcus A.; Pauzauskie, Peter J.; Olson, Tammy Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14067-14069
  • DOI: 10.1021/ja1072299

Mechanically robust 3D graphene macroassembly with high surface area
journal, January 2012

  • Worsley, Marcus A.; Kucheyev, Sergei O.; Mason, Harris E.
  • Chemical Communications, Vol. 48, Issue 67, p. 8428-8430
  • DOI: 10.1039/c2cc33979j

Graphene Anchored with Co3O4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance
journal, June 2010

  • Wu, Zhong-Shuai; Ren, Wencai; Wen, Lei
  • ACS Nano, Vol. 4, Issue 6, p. 3187-3194
  • DOI: 10.1021/nn100740x

Rapid microwave-assisted synthesis of graphene nanosheet/Co3O4 composite for supercapacitors
journal, September 2010


Fabrication of Palladium Nanotubes and Their Application in Hydrogen Sensing
journal, June 2005

  • Yu, Shufang; Welp, Ulrich; Hua, Leonard Z.
  • Chemistry of Materials, Vol. 17, Issue 13, p. 3445-3450
  • DOI: 10.1021/cm048191i