Oxygen content tailored magnetic and electronic properties in cobaltite double perovskite thin films

Harrell, Zach John; Enriquez, Erik M.; Chen, Aiping; Dowden, Paul Charles; Mace, Brennan; Lu, Xujie; Jia, Quanxi; Chen, Chonglin

doi:10.1063/1.4977026

Title: Oxygen content tailored magnetic and electronic properties in cobaltite double perovskite thin films

Journal Article · Mon Feb 27 00:00:00 EST 2017 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4977026· OSTI ID:1414131

^[1];

^[2];

^[2]; Dowden, Paul Charles ^[2]; Mace, Brennan ^[3];

^[2];

^[4]; Chen, Chonglin ^[3]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Texas at San Antonio, San Antonio, TX (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Texas at San Antonio, San Antonio, TX (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. at Buffalo - The State Univ. of New York, Buffalo, NY (United States)

Oxygen content in transition metal oxides is one of the most important parameters to control for the desired physical properties. Recently, we have systematically studied the oxygen content and property relationship of the double perovskite PrBaCo₂O_5.5+δ (PBCO) thin films deposited on the LaAlO₃ substrates. The oxygen content in the films was varied by in-situ annealing in a nitrogen, oxygen, or ozone environment. Associated with the oxygen content, the out-of-plane lattice parameter progressively decreases with increasing oxygen content in the films. The saturated magnetization shows a drastic increase and resistivity is significantly reduced in the ozone annealed samples, indicating the strong coupling between physical properties and oxygen content. Furthermore, these results demonstrate that the magnetic properties of PBCO films are highly dependent on the oxygen contents, or the film with higher oxygen uptake has the largest magnetization.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1414131

Alternate ID(s):: OSTI ID: 1348270

Report Number(s):: LA-UR-16-27359; APPLAB; TRN: US1800656

Journal Information:: Applied Physics Letters, Vol. 110, Issue 9; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 20 works

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thin films
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Title: Oxygen content tailored magnetic and electronic properties in cobaltite double perovskite thin films

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