Electric field effect on chemical and phase equilibria in nano-TiB2–TiO2–TiBO3 system at <650 °C: an in situ time-resolved energy dispersive x-ray diffraction study with an ultrahigh energy synchrotron probe

Özdemir, Tevfik E.; Akdoğan, Enver Koray; Şavklıyıldız, İlyas; Biçer, Hülya; Örnek, Metin; Zhong, Zhong; Tsakalakos, Thomas

doi:10.1557/jmr.2016.466

Title: Electric field effect on chemical and phase equilibria in nano-TiB₂–TiO₂–TiBO₃ system at <650 °C: an in situ time-resolved energy dispersive x-ray diffraction study with an ultrahigh energy synchrotron probe

Journal Article · Mon Dec 19 00:00:00 EST 2016 · Journal of Materials Research

DOI:https://doi.org/10.1557/jmr.2016.466· OSTI ID:1413927

Özdemir, Tevfik E. ^[1]; Akdoğan, Enver Koray ^[1]; Şavklıyıldız, İlyas ^[2]; Biçer, Hülya ^[3]; Örnek, Metin ^[1]; Zhong, Zhong ^[4]; Tsakalakos, Thomas ^[1]

Rutgers Univ., Piscataway, NJ (United States). Dept. of Materials Science and Engineering
Selcuk Univ., Konya (Turkey). Metallurgical and Materials Engineering Dept.
DulumpÄ±nar Univ., Kutahya (Turkey). Dept. of Materials Science and Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source

Nano-TiB₂ powder of 58 nm size with TiO₂ and TiBO₃ as secondary phases was heated with 20 °C to <650 °C in argon while applying an electric field. The powder became conductive at 520 and 305 °C (T_onset) for 16 and 40 V/cm, respectively, at which point current bursts of 4.5 and 10.0 A (peak value) were observed. Current bursts were accompanied by >1% TiB₂ unit cell expansion, exceeding zero field thermally induced expansion. The current bursts also induced nonisothermal reaction between TiB₂ and TiO₂, yielding TiBO₃ that is absent with no field. Increase from 16 to 40 V/cm shifts the TiB₂ → TiBO₃ reaction forward, decreases T_onset but increases reaction rate. Analysis using Van’t Hoff relation, including electrochemical effects, precluded possibility of appreciable Joule heating, which was supported with adiabatic internal temperature calculations. In conclusion, the observed low temperature oxidation of TiB₂ to TiBO₃ that is electrochemically driven and is mediated by the TiO₂ solid electrolyte.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1413927

Report Number(s):: BNL-114453-2017-JA; applab; TRN: US1800588

Journal Information:: Journal of Materials Research, Vol. 32, Issue 02; ISSN 0884-2914

Publisher:: Materials Research SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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Title: Electric field effect on chemical and phase equilibria in nano-TiB2–TiO2–TiBO3 system at <650 °C: an in situ time-resolved energy dispersive x-ray diffraction study with an ultrahigh energy synchrotron probe

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Title: Electric field effect on chemical and phase equilibria in nano-TiB₂–TiO₂–TiBO₃ system at <650 °C: an in situ time-resolved energy dispersive x-ray diffraction study with an ultrahigh energy synchrotron probe