Escape of anions from geminate recombination in THF due to charge delocalization

Chen, Hung -Cheng; Cook, Andrew R.; Asaoka, Sadayuki; Boschen, Jeffery S.; Windus, Theresa L.; Miller, John R.

doi:10.1039/C7CP05880B

Title: Escape of anions from geminate recombination in THF due to charge delocalization

Journal Article · Fri Nov 24 00:00:00 EST 2017 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/C7CP05880B· OSTI ID:1412781

Chen, Hung -Cheng ^[1];

^[1]; Asaoka, Sadayuki ^[2]; Boschen, Jeffery S. ^[3]; Windus, Theresa L. ^[4];

^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Kyoto Institute of Technology, Kyoto (Japan)
Department of Chemistry and Ames Laboratory (USDOE); Iowa State University; Ames; USA
Iowa State Univ., Ames, IA (United States)

Geminate recombination of 24 radical anions (M˙^-) with solvated protons (RH₂⁺) was studied in tetrahydrofuran (THF) with pulse radiolysis.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States); Ames Lab., Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; AC02-98CH10886; AC02-07CH11358

OSTI ID:: 1412781

Alternate ID(s):: OSTI ID: 1413138

Report Number(s):: BNL-114803-2017-JA; IS-J-9488; PPCPFQ; R&D Project: CO037; KC0304030; TRN: US1800361

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 19, Issue 48; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 2 works

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References (80)

Electron and organic radical anion solvation. Pulse radiolysis of tetrahydrofuran and its solutions of N-methylacetamide or pyrrolidone Tran-Thi, T. H.; Koulkes-Pujo, A. M. The Journal of Physical Chemistry, Vol. 87, Issue 7 https://doi.org/10.1021/j100230a014	journal	March 1983
Dynamics of proton transfer involving delocalized negative ions in the gas phase Farneth, William E.; Brauman, John I. Journal of the American Chemical Society, Vol. 98, Issue 25 https://doi.org/10.1021/ja00441a001	journal	December 1976
Mechanisms of the ultrafast production and recombination of solvated electrons in weakly polar fluids: Comparison of multiphoton ionization and detachment via the charge-transfer-to-solvent transition of Na− in THF Martini, Ignacio B.; Barthel, Erik R.; Schwartz, Benjamin J. The Journal of Chemical Physics, Vol. 113, Issue 24 https://doi.org/10.1063/1.1328071	journal	December 2000
The LEAF picosecond pulse radiolysis facility at Brookhaven National Laboratory Wishart, James F.; Cook, Andrew R.; Miller, John R. Review of Scientific Instruments, Vol. 75, Issue 11 https://doi.org/10.1063/1.1807004	journal	November 2004
Comparison of the chain length dependence of the singlet- and triplet-excited states of oligofluorenes Wasserberg, Dorothee; Dudek, Stephen P.; Meskers, Stefan C. J. Chemical Physics Letters, Vol. 411, Issue 1-3 https://doi.org/10.1016/j.cplett.2005.06.039	journal	August 2005
Picosecond pulse radiolysis studies on geminate ion recombination in saturated hydrocarbon Tagawa, S.; Washio, M.; Kobayashi, H. Radiation Physics and Chemistry (1977), Vol. 21, Issue 1-2 https://doi.org/10.1016/0146-5724(83)90128-0	journal	January 1983
Electric field assisted dissociation of charge transfer states as a mechanism of photocarrier production Braun, Charles L. The Journal of Chemical Physics, Vol. 80, Issue 9 https://doi.org/10.1063/1.447243	journal	May 1984
Analysis of photogeneration in a doped polymer system in terms of a kinetic model for electric‐field‐assisted dissociation of charge‐transfer states Goliber, T. E.; Perlstein, J. H. The Journal of Chemical Physics, Vol. 80, Issue 9 https://doi.org/10.1063/1.447244	journal	May 1984
Solute radical cation yields in the pulse radiolysis of solutions of aromatic amines in chlorinated hydrocarbons Burrows, H. D.; Greatorex, D.; Kemp, T. J. The Journal of Physical Chemistry, Vol. 76, Issue 1 https://doi.org/10.1021/j100645a004	journal	January 1972
Intrinsic and Dynamical Reaction Pathways of an Excited State Proton Transfer Raucci, Umberto; Savarese, Marika; Adamo, Carlo The Journal of Physical Chemistry B, Vol. 119, Issue 6 https://doi.org/10.1021/jp508947f	journal	August 2014
Geminate ion recombination in irradiated liquid CCl4 van den Ende, Cornelis A. M.; Luthjens, Lee H.; Warman, John M. Radiation Physics and Chemistry (1977), Vol. 19, Issue 6 https://doi.org/10.1016/0146-5724(82)90137-6	journal	January 1982
Dependence of the hydrogen kinetic isotope effect on the reaction free energy German, Ernst D.; Kuznetsov, Alexander M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 77, Issue 2 https://doi.org/10.1039/f19817700397	journal	January 1981
Proton transfer in solution: Molecular dynamics with quantum transitions Hammes‐Schiffer, Sharon; Tully, John C. The Journal of Chemical Physics, Vol. 101, Issue 6 https://doi.org/10.1063/1.467455	journal	September 1994
Length and Time-Dependent Rates in Diffusion-Controlled Reactions with Conjugated Polymers Sreearunothai, Paiboon; Asaoka, Sadayuki; Cook, Andrew R. The Journal of Physical Chemistry A, Vol. 113, Issue 12 https://doi.org/10.1021/jp809413x	journal	March 2009
New methods for the accurate determination of extinction and diffusion coefficients of aromatic and heteroaromatic radical anions in N,N-dimethylformamide Pedersen, Steen U.; Bo Christensen, Torben; Thomasen, Tove Journal of Electroanalytical Chemistry, Vol. 454, Issue 1-2 https://doi.org/10.1016/S0022-0728(98)00195-8	journal	August 1998
A dynamical theory of nonadiabatic proton and hydrogen atom transfer reaction rates in solution Borgis, Daniel C.; Lee, Sangyoub; Hynes, James T. Chemical Physics Letters, Vol. 162, Issue 1-2 https://doi.org/10.1016/0009-2614(89)85059-6	journal	October 1989
Proton-transfer reactions. 3. Differences in the protonation of localized and delocalized carbanion intermediates Koch, Heinz F.; Koch, Judith G.; Koch, Nanci H. Journal of the American Chemical Society, Vol. 105, Issue 8 https://doi.org/10.1021/ja00346a047	journal	April 1983
Effects of electronic delocalization on intramolecular proton transfer Tarkka, Richard M.; Jenekhe, Samson A. Chemical Physics Letters, Vol. 260, Issue 5-6 https://doi.org/10.1016/0009-2614(96)00910-4	journal	October 1996
Curve Crossing Formulation for Proton Transfer Reactions in Solution Borgis, Daniel; Hynes, James T. The Journal of Physical Chemistry, Vol. 100, Issue 4 https://doi.org/10.1021/jp9522324	journal	January 1996
The Empirical Treatment of Solvent-Solute Interactions: 15 Years of .pi.* Laurence, Christian; Nicolet, Pierre; Dalati, M. Tawfik The Journal of Physical Chemistry, Vol. 98, Issue 23 https://doi.org/10.1021/j100074a003	journal	June 1994
Pulse radiolysis of solutions of amines of low ionization potential Kemp, T. J.; Roberts, J. P.; Salmon, G. A. The Journal of Physical Chemistry, Vol. 72, Issue 5 https://doi.org/10.1021/j100851a012	journal	May 1968
Charge Photogeneration in Organic Solar Cells Clarke, Tracey M.; Durrant, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6736-6767 https://doi.org/10.1021/cr900271s	journal	November 2010
Ion Pairs from Photoexcited, “Random” Electron Donors and Acceptors: Alkylbenzenes and Tetracyanoethylene Zhou, Jinwei; Findley, Bret R.; Teslja, Alexey The Journal of Physical Chemistry A, Vol. 104, Issue 49 https://doi.org/10.1021/jp003005r	journal	December 2000
Theory of Coupled Electron and Proton Transfer Reactions Hammes-Schiffer, Sharon; Stuchebrukhov, Alexei A. Chemical Reviews, Vol. 110, Issue 12 https://doi.org/10.1021/cr1001436	journal	December 2010
Dynamics of Interconversion of Contact and Solvent-Separated Radical-Ion Pairs Arnold, Bradley R.; Noukakis, Dimitri; Farid, Samir Journal of the American Chemical Society, Vol. 117, Issue 15 https://doi.org/10.1021/ja00120a023	journal	April 1995
Pulse radiolysis studies. XXI. Optical absorption spectrum of the solvated electron in ethers and in binary solutions of these ethers Jou, F. Y.; Dorfman, Leon M. The Journal of Chemical Physics, Vol. 58, Issue 11 https://doi.org/10.1063/1.1679050	journal	June 1973
Solvent-Separated Ion Pairs of Carbanions Hogen-Esch, T. E.; Smid, J. Journal of the American Chemical Society, Vol. 87, Issue 3 https://doi.org/10.1021/ja01081a059	journal	February 1965
Direct Measurements of the Charge-Recombination Dynamics of Geminate Ion Pairs Formed upon Electron-Transfer Quenching at High Donor Concentration Vauthey, Eric The Journal of Physical Chemistry A, Vol. 105, Issue 2 https://doi.org/10.1021/jp0023260	journal	January 2001
Nonlinear Free Energy Relations for Adiabatic Proton Transfer Reactions in a Polar Environment. I. Fixed Proton Donor−Acceptor Separation Kiefer, Philip M.; Hynes, James T. The Journal of Physical Chemistry A, Vol. 106, Issue 9 https://doi.org/10.1021/jp0134244	journal	March 2002
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update Hunter, Edward P. L.; Lias, Sharon G. Journal of Physical and Chemical Reference Data, Vol. 27, Issue 3 https://doi.org/10.1063/1.556018	journal	May 1998
Contact and solvent-separated geminate radical ion pairs in electron-transfer photochemistry Gould, Ian R.; Young, Ralph H.; Moody, Roger E. The Journal of Physical Chemistry, Vol. 95, Issue 5 https://doi.org/10.1021/j100158a031	journal	March 1991
Analytical solution of the Debye-Smoluchowski equation for geminate and homogeneous recombination and for flourescence quenching Flannery, M. R. Physical Review A, Vol. 25, Issue 6 https://doi.org/10.1103/PhysRevA.25.3403	journal	June 1982
Picosecond geminate charge recombination: the dependence of reaction kinetics on initial pair separation Scott, T. W.; Braun, C. L. Chemical Physics Letters, Vol. 127, Issue 5 https://doi.org/10.1016/0009-2614(86)80597-8	journal	June 1986
Driving Force Dependence of Rates for Nonadiabatic Proton and Proton-Coupled Electron Transfer: Conditions for Inverted Region Behavior Edwards, Sarah J.; Soudackov, Alexander V.; Hammes-Schiffer, Sharon The Journal of Physical Chemistry B, Vol. 113, Issue 44 https://doi.org/10.1021/jp907808t	journal	November 2009
Observation of initial ion-pairs in pulse-irradiated weakly polar liquids Shaede, Eric A.; Kurihara, Hirondo; Dorfman, Leon M. International Journal for Radiation Physics and Chemistry, Vol. 6, Issue 1 https://doi.org/10.1016/0020-7055(74)90034-5	journal	February 1974
Investigation of the Electrochemical Reduction of Benzophenone in Aprotic Solvents Using the Method of Cyclic Voltammetry Tsierkezos, Nikos G. Journal of Solution Chemistry, Vol. 36, Issue 10 https://doi.org/10.1007/s10953-007-9188-4	journal	August 2007
Studies of Contact and Solvent-Separated Ion Pairs of Carbanions. II. Conductivities and Thermodynamics of Dissociation of Fluorenyllithium, -sodium, and -cesium Hogen-Esch, T. E.; Smid, J. Journal of the American Chemical Society, Vol. 88, Issue 2 https://doi.org/10.1021/ja00954a025	journal	January 1966
Kinetics of proton transfer reactions involving carbon Wirz, J. Pure and Applied Chemistry, Vol. 70, Issue 11 https://doi.org/10.1351/pac199870112221	journal	November 1998
Theory of the kinetic isotope effect in proton transfer reactions in a polar medium German, Ernst D.; Kuznetsov, Alexander M.; Dogonadze, Revaz R. Journal of the Chemical Society, Faraday Transactions 2, Vol. 76 https://doi.org/10.1039/f29807601128	journal	January 1980
Electronic Population Analysis on LCAO–MO Molecular Wave Functions. I Mulliken, R. S. The Journal of Chemical Physics, Vol. 23, Issue 10 https://doi.org/10.1063/1.1740588	journal	October 1955
Solution of the time‐dependent Onsager problem Hong, K. M.; Noolandi, J. The Journal of Chemical Physics, Vol. 69, Issue 11 https://doi.org/10.1063/1.436493	journal	December 1978
Studies of Contact and Solvent-Separated Ion Pairs of Carbanions. I. Effect of Temperature, Counterion, and Solvent Esch, T. E. Hogen-; Smid, J. Journal of the American Chemical Society, Vol. 88, Issue 2 https://doi.org/10.1021/ja00954a024	journal	January 1966
Electron and Hole Transport To Trap Groups at the Ends of Conjugated Polyfluorenes Asaoka, Sadayuki; Takeda, Norihiko; Iyoda, Tomokazu Journal of the American Chemical Society, Vol. 130, Issue 36 https://doi.org/10.1021/ja800426z	journal	September 2008
Geminate recombination measurements of solvated electron in THF using laser-synchronized picosecond electron pulse Waele, Vincent De; Sorgues, Sébastien; Pernot, Pascal Chemical Physics Letters, Vol. 423, Issue 1-3 https://doi.org/10.1016/j.cplett.2006.03.008	journal	May 2006
Studies of Ions and Ion Pairs in Tetrahydrofuran Solution. Alkali Metal Salts of Tetraphenylboride Bhattacharyya, D. N.; Lee, C. L.; Smid, J. The Journal of Physical Chemistry, Vol. 69, Issue 2 https://doi.org/10.1021/j100886a042	journal	February 1965
Solution of the Smoluchowski equation with a Coulomb potential. I. General results Hong, K. M.; Noolandi, J. The Journal of Chemical Physics, Vol. 68, Issue 11 https://doi.org/10.1063/1.435636	journal	June 1978
Partially diffusion‐controlled recombination Sano, Hisatake; Tachiya, M. The Journal of Chemical Physics, Vol. 71, Issue 3 https://doi.org/10.1063/1.438427	journal	August 1979
Evidence for Inverted Region Behavior in Proton Transfer to Carbanions Andrieux, Claude P.; Gamby, Jean; Hapiot, Philippe Journal of the American Chemical Society, Vol. 125, Issue 33 https://doi.org/10.1021/ja035268f	journal	August 2003
Dissociative Equilibria in the Systems Aromatic Hydrocarbon ^[UNK] ,Na ⁺ ⇄ Radical Anion ^[UNK] + Na ⁺ Slates, R. V.; Szwarc, M. The Journal of Physical Chemistry, Vol. 69, Issue 12 https://doi.org/10.1021/j100782a012	journal	December 1965
Static and dynamic solution properties of monodisperse oligofluorenes Somma, E.; Loppinet, B.; Chi, C. Physical Chemistry Chemical Physics, Vol. 8, Issue 23 https://doi.org/10.1039/b601531j	journal	January 2006
Thermodynamics of the Electron and the Proton Bartmess, John E. The Journal of Physical Chemistry, Vol. 98, Issue 25 https://doi.org/10.1021/j100076a029	journal	June 1994
Absolute Energies of Interconverting Contact and Solvent-Separated Radical−Ion Pairs Arnold, Bradley R.; Farid, Samir; Goodman, Joshua L. Journal of the American Chemical Society, Vol. 118, Issue 23 https://doi.org/10.1021/ja9604020	journal	January 1996
Nonadiabatic Proton/Deuteron Transfer within the Benzophenone−Triethylamine Triplet Contact Radical Ion Pair: Exploration of the Influence of Structure upon Reaction ^† Heeb, Libby R.; Peters, Kevin S. The Journal of Physical Chemistry B, Vol. 112, Issue 2 https://doi.org/10.1021/jp073340g	journal	January 2008
Mixed Quantum/Classical Dynamics of Hydrogen Transfer Reactions Hammes-Schiffer, Sharon The Journal of Physical Chemistry A, Vol. 102, Issue 51 https://doi.org/10.1021/jp983246n	journal	December 1998
Mobilities of Radical Cations and Anions, Dimer Radical Anions, and Relative Electron Affinities by Times of Flight in n-Hexane Lim, S. K.; Burba, M. E.; Albrecht, A. C. The Journal of Physical Chemistry, Vol. 98, Issue 38 https://doi.org/10.1021/j100089a048	journal	September 1994
Efficiencies of photoinduced electron-transfer reactions: role of the Marcus inverted region in return electron transfer within geminate radical-ion pairs Gould, Ian R.; Ege, Deniz; Moser, Jacques E. Journal of the American Chemical Society, Vol. 112, Issue 11 https://doi.org/10.1021/ja00167a027	journal	May 1990
Kinetic Isotope Effects for Nonadiabatic Proton Transfer Reactions in a Polar Environment. 1. Interpretation of Tunneling Kinetic Isotopic Effects Kiefer, Philip M.; Hynes, James T. The Journal of Physical Chemistry A, Vol. 108, Issue 52 https://doi.org/10.1021/jp040497p	journal	December 2004
Contact and solvent-separated ion pairs of carbanions. VI. Conductivities and thermodynamics of dissociation of fluorenyl alkali salts in tetrahydrofuran and dimethoxyethane Ellingsen, T.; Smid, J. The Journal of Physical Chemistry, Vol. 73, Issue 8 https://doi.org/10.1021/j100842a044	journal	August 1969
Ionic photodissociation of electron donor-acceptor systems in solution Masuhara, Hiroshi; Mataga, Noboru Accounts of Chemical Research, Vol. 14, Issue 10 https://doi.org/10.1021/ar00070a004	journal	October 1981
Long Distance Photoinduced Electron Transfer in Solutions: A Mechanism for Producing Large Yields of Free Ions by Electron Transfer Quenching Zhou, Jinwei; Shah, Roshan P.; Findley, Bret R. The Journal of Physical Chemistry A, Vol. 106, Issue 1 https://doi.org/10.1021/jp012808r	journal	January 2002
Behavior of radical ion pairs produced by photoinduced electron transfer in polar solutions Mataga, Noboru; Okada, Tadashi; Kanda, Yu Tetrahedron, Vol. 42, Issue 22 https://doi.org/10.1016/S0040-4020(01)88074-1	journal	January 1986
Deviations from Ohm's Law in Weak Electrolytes Onsager, Lars The Journal of Chemical Physics, Vol. 2, Issue 9 https://doi.org/10.1063/1.1749541	journal	September 1934
Contact and solvent-separated ion pairs of carbanions. V. The role of solvent structure in alkali ion solvation Chan, L. L.; Smid, J. Journal of the American Chemical Society, Vol. 90, Issue 17 https://doi.org/10.1021/ja01019a025	journal	August 1968
Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model Barone, Vincenzo; Cossi, Maurizio The Journal of Physical Chemistry A, Vol. 102, Issue 11 https://doi.org/10.1021/jp9716997	journal	March 1998
Transients formed during reduction of polynuclear aromatics: a pulse radiolysis study Das, Tomi Nath; Priyadarsini, K. Indira Journal of the Chemical Society, Perkin Transactions 2, Issue 4 https://doi.org/10.1039/p29930000733	journal	January 1993
A solution of the Debye–Smoluchowski equation for the rate of reaction of ions in dilute solution Rice, Stephen A.; Butler, P. Robin; Pilling, Michael J. The Journal of Chemical Physics, Vol. 70, Issue 9 https://doi.org/10.1063/1.438020	journal	May 1979
Picosecond measurements of time-resolved geminate charge recombination Braun, C. L.; Scott, T. W. The Journal of Physical Chemistry, Vol. 87, Issue 24 https://doi.org/10.1021/j150642a002	journal	November 1983
What makes proton transfer fast Kresge, Alexander J. Accounts of Chemical Research, Vol. 8, Issue 10 https://doi.org/10.1021/ar50094a006	journal	October 1975
Hot exciton dissociation in polymer solar cells Grancini, G.; Maiuri, M.; Fazzi, D. Nature Materials, Vol. 12, Issue 1 https://doi.org/10.1038/nmat3502	journal	December 2012
Accuracies of the empirical theories of the escape probability based on Eigen model and Braun model compared with the exact extension of Onsager theory Wojcik, Mariusz; Tachiya, M. The Journal of Chemical Physics, Vol. 130, Issue 10 https://doi.org/10.1063/1.3082005	journal	March 2009
Further Evidence of an Inverted Region in Proton Transfer within the Benzophenone/Substituted Aniline Contact Radical Ion Pairs; Importance of Vibrational Reorganization Energy Heeb, Libby R.; Peters, Kevin S. The Journal of Physical Chemistry A, Vol. 110, Issue 20 https://doi.org/10.1021/jp056188w	journal	May 2006
Dynamical theory of proton tunneling transfer rates in solution: general formulation Borgis, Daniel; Hynes, James T. Chemical Physics, Vol. 170, Issue 3 https://doi.org/10.1016/0301-0104(93)85117-Q	journal	March 1993
Studies of Solvation Phenomena of Ions and Ion Pairs in Dimethoxyethane and Tetrahydrofuran Carvajal, C.; Tölle, K. J.; Smid, J. Journal of the American Chemical Society, Vol. 87, Issue 24 https://doi.org/10.1021/ja00952a005	journal	December 1965
Theory of time-dependent geminate recombination Noolandi, J. Journal of Electrostatics, Vol. 12 https://doi.org/10.1016/0304-3886(82)90061-4	journal	April 1982
Solvent-Separated Radical Ion Pairs and Free Ion Yields. 1. Effect of Temperature on Free Ion Formation in Solution Zhong, Cheng; Zhou, Jinwei; Braun, Charles L. The Journal of Physical Chemistry A, Vol. 108, Issue 33 https://doi.org/10.1021/jp049486m	journal	August 2004
Pulse radiolysis studies of ion association Beaumond, D.; Rodgers, M. A. J. Transactions of the Faraday Society, Vol. 65 https://doi.org/10.1039/tf9696502973	journal	January 1969
Polarons, Bipolarons, and Side-By-Side Polarons in Reduction of Oligofluorenes Zaikowski, Lori; Kaur, Parmeet; Gelfond, Claudia Journal of the American Chemical Society, Vol. 134, Issue 26 https://doi.org/10.1021/ja301494n	journal	June 2012
DFT and Proton Transfer Reactions: A Benchmark Study on Structure and Kinetics Mangiatordi, Giuseppe Felice; Brémond, Eric; Adamo, Carlo Journal of Chemical Theory and Computation, Vol. 8, Issue 9 https://doi.org/10.1021/ct300338y	journal	August 2012
Development of a Potential Surface for Simulation of Proton and Hydride Transfer Reactions in Solution: Application to NADH Hydride Transfer Hurley, M. M.; Hammes-Schiffer, Sharon The Journal of Physical Chemistry A, Vol. 101, Issue 21 https://doi.org/10.1021/jp970269d	journal	May 1997
Energies, structures, and electronic properties of molecules in solution with the C-PCM solvation model Cossi, Maurizio; Rega, Nadia; Scalmani, Giovanni Journal of Computational Chemistry, Vol. 24, Issue 6 https://doi.org/10.1002/jcc.10189	journal	April 2003

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Title: Escape of anions from geminate recombination in THF due to charge delocalization

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