On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks

Rosnes, Mali H.; Sheptyakov, Denis; Franz, Alexandra; Frontzek, Matthias; Dietzel, Pascal D.  C.; Georgiev, Peter A.

doi:10.1039/C7CP05119K

Title: On the elusive nature of oxygen binding at coordinatively unsaturated 3d transition metal centers in metal–organic frameworks

Journal Article · Mon Sep 18 00:00:00 EDT 2017 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/C7CP05119K· OSTI ID:1410908

^[1]; Sheptyakov, Denis ^[2]; Franz, Alexandra ^[3];

^[4];

^[1];

^[5]

Univ. of Bergen (Norway). Dept. of Chemistry
Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Neutron Scattering
Helmholtz-Zentrum Berlin fur Materialien und Energie GmbH, Berlin (Germany)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
Univ. of Milan (Italy). Dept. of Chemistry

Low and ambient temperature binding of oxygen, O₂, in MOF-74, CPO-27-M (M = Mn, Co, Ni, Cu, Zn) framework materials remains in the physisorption regime, with energetics very similar to that of nitrogen, N₂, sorption.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; European Union (EU)

Grant/Contract Number:: AC05-00OR22725; 283883; 221596; 209339; 290605

OSTI ID:: 1410908

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 19, Issue 38; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 13 works

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