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Title: Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet

Abstract

A new octacyanotungstate( v ) singe chain magnet with an effective energy barrier of 39.7(3) cm −1 is achieved by enforcing Ising-like magnetic anisotropy via introduction of trigonal distortion with a fac -tridentate capping ligand.

Authors:
 [1]; ORCiD logo [2];  [3];  [2]; ORCiD logo [2];  [2]; ORCiD logo [2]
  1. Department of Chemistry, Texas A & M University, College Station, USA, Department of Chemistry
  2. Department of Chemistry, Texas A & M University, College Station, USA
  3. Department of Chemistry, Southern University of Science and Technology, Shenzhen, P. R. China
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1410835
Grant/Contract Number:
FG02-02ER45999
Resource Type:
Journal Article: Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 1; Related Information: CHORUS Timestamp: 2017-12-20 07:15:49; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zhang, Yuan-Zhu, Dolinar, Brian S., Liu, Shihao, Brown, Andrew J., Zhang, Xuan, Wang, Zhao-Xi, and Dunbar, Kim R.. Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet. United Kingdom: N. p., 2018. Web. doi:10.1039/C7SC02925J.
Zhang, Yuan-Zhu, Dolinar, Brian S., Liu, Shihao, Brown, Andrew J., Zhang, Xuan, Wang, Zhao-Xi, & Dunbar, Kim R.. Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet. United Kingdom. doi:10.1039/C7SC02925J.
Zhang, Yuan-Zhu, Dolinar, Brian S., Liu, Shihao, Brown, Andrew J., Zhang, Xuan, Wang, Zhao-Xi, and Dunbar, Kim R.. Mon . "Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet". United Kingdom. doi:10.1039/C7SC02925J.
@article{osti_1410835,
title = {Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W( v )–Co( ii ) cyanide single-chain magnet},
author = {Zhang, Yuan-Zhu and Dolinar, Brian S. and Liu, Shihao and Brown, Andrew J. and Zhang, Xuan and Wang, Zhao-Xi and Dunbar, Kim R.},
abstractNote = {A new octacyanotungstate( v ) singe chain magnet with an effective energy barrier of 39.7(3) cm −1 is achieved by enforcing Ising-like magnetic anisotropy via introduction of trigonal distortion with a fac -tridentate capping ligand.},
doi = {10.1039/C7SC02925J},
journal = {Chemical Science},
number = 1,
volume = 9,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1039/C7SC02925J

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