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Title: A spin transition mechanism for cooperative adsorption in metal–organic frameworks

Journal Article · · Nature (London)
DOI:https://doi.org/10.1038/nature23674· OSTI ID:1410682

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001015; AC02-06CH11357
OSTI ID:
1410682
Journal Information:
Nature (London), Vol. 550, Issue 10, 2017; ISSN 0028-0836
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
ENGLISH

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Reversible CO Scavenging via Adsorbate-Dependent Spin State Transitions in an Iron(II)–Triazolate Metal–Organic Framework journal April 2016
An Explanation for the Very Large Breathing Effect of a Metal–Organic Framework during CO2 Adsorption journal September 2007
Flexible metal–organic frameworks journal January 2014
Carbon Dioxide Capture in Metal–Organic Frameworks journal September 2011
Reversible CO Binding Enables Tunable CO/H 2 and CO/N 2 Separations in Metal–Organic Frameworks with Exposed Divalent Metal Cations journal July 2014
Hydrocarbon Separations in Metal–Organic Frameworks journal September 2013
Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks journal January 2008
CO Ligation Intermediates and the Mechanism of Hemoglobin Cooperativity journal January 1999
Cooperative Spin Crossover Behavior in Cyanide-Bridged Fe(II)−M(II) Bimetallic 3D Hofmann-like Networks (M = Ni, Pd, and Pt) journal July 2001
Introduction to Metal–Organic Frameworks journal September 2011
High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites journal July 2016
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks journal March 2015
Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework Material journal November 2002
Selective gas adsorption and separation in metal–organic frameworks journal January 2009
Organometallic Ferrocenyl Polymers Displaying Tunable Cooperative Interactions between Transition Metal Centers journal December 1993
The Chemistry and Applications of Metal-Organic Frameworks journal August 2013
Reactivity of coordinatively unsaturated iron complexes towards carbon monoxide: to bind or not to bind? journal January 2011
Indexing of powder diffraction patterns by iterative use of singular value decomposition journal January 2003
A supported Cu(I)@MIL-100(Fe) adsorbent with high CO adsorption capacity and CO/N2 selectivity journal June 2015
Spin-Transition Polymers: From Molecular Materials Toward Memory Devices journal January 1998
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871 https://doi.org/10.1021/ja8036096
journal August 2008
Monodentate hydroxide as a super strong yet reversible active site for CO 2 capture from high-humidity flue gas journal January 2015
Selective, Tunable O 2 Binding in Cobalt(II)–Triazolate/Pyrazolate Metal–Organic Frameworks journal May 2016
Self-Accelerating CO Sorption in a Soft Nanoporous Crystal journal December 2013
Industrial Gas Handbook book February 2007

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