REE Incorporation into Calcite Individual Crystals as One Time Spike Addition

Gabitov, Rinat; Sadekov, Aleksey; Migdisov, Artas

doi:10.3390/min7110204

Title: REE Incorporation into Calcite Individual Crystals as One Time Spike Addition

Journal Article · Thu Oct 26 00:00:00 EDT 2017 · Minerals

DOI:https://doi.org/10.3390/min7110204· OSTI ID:1409791

Gabitov, Rinat ^[1]; Sadekov, Aleksey ^[2];

^[3]

Mississippi State Univ., Mississippi State, MS (United States). Department of Geosciences
The University of Western Australia, Crawley, WA (Australia). ARC Centre of Excellence for Coral Reef Studies
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Experiments on the incorporation of trace elements into calcite were performed, and rare earth elements (REE) were used to mark the growth zones of individual crystals. Experiments were conducted at different pH (7.7 to 8.8) and temperatures (2 °C to 24.6 °C) in NH₄Cl + CaCl₂ solutions, where REE were rapidly consumed by growing calcite. LA-ICP-MS line-scans yielded the distribution of (REE/Ca)_calcite within individual crystals in a manner consistent with the addition of REE into fluid. A sharp decrease of (REE/Ca)_calcite toward the crystal edge suggests the fast depletion of (REE/Ca)_fluid due to strong REE consumption by growing calcite. An attempt was made to estimate the lower limit of the partition coefficients between calcite and fluid using selected REE/Ca data within individual calcite crystals and the amount of REE added into fluid.

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Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1409791

Report Number(s):: LA-UR-17-28574

Journal Information:: Minerals, Vol. 7, Issue 11; ISSN 2075-163X

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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References (36)

The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of ocean waters Elderfield, H.; Upstill-Goddard, R.; Sholkovitz, E. R. Geochimica et Cosmochimica Acta, Vol. 54, Issue 4 https://doi.org/10.1016/0016-7037(90)90432-K	journal	April 1990
Incorporation of Eu(III) into Calcite under Recrystallization conditions Hellebrandt, S. E.; Hofmann, S.; Jordan, N. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep33137	journal	September 2016
Experimental study of europium (III) coprecipitation with calcite Lakshtanov, L. Z.; Stipp, S. L. S. Geochimica et Cosmochimica Acta, Vol. 68, Issue 4 https://doi.org/10.1016/j.gca.2003.07.010	journal	February 2004
Incorporation of Np(V) and U(VI) in carbonate and sulfate minerals crystallized from aqueous solution Balboni, Enrica; Morrison, Jessica M.; Wang, Zheming Geochimica et Cosmochimica Acta, Vol. 151 https://doi.org/10.1016/j.gca.2014.10.027	journal	February 2015
REE diffusion in calcite Cherniak, D. J. Earth and Planetary Science Letters, Vol. 160, Issue 3-4 https://doi.org/10.1016/S0012-821X(98)00087-9	journal	August 1998
Study of the radiotoxicity of actinides recycling in boiling water reactors fuel François, J. L.; Guzmán, J. R.; Martín-del-Campo, C. Nuclear Engineering and Design, Vol. 239, Issue 10 https://doi.org/10.1016/j.nucengdes.2009.05.012	journal	October 2009
The coprecipitation of rare-earth elements with calcite and aragonite Terakado, Yasutaka; Masuda, Akimasa Chemical Geology, Vol. 69, Issue 1-2 https://doi.org/10.1016/0009-2541(88)90162-3	journal	June 1988
Partitioning of rare earth elements (REEs) between calcite and seawater solutions at 25°C and 1 atm, and high dissolved REE concentrations Zhong, Shaojun; Mucci, Alfonso Geochimica et Cosmochimica Acta, Vol. 59, Issue 3 https://doi.org/10.1016/0016-7037(94)00381-U	journal	February 1995
Experimental study of rare earth element partitioning between calcite and sodium chloride solution at room temperature and pressure Toyama, Kotaro; Terakado, Yasutaka GEOCHEMICAL JOURNAL, Vol. 48, Issue 5 https://doi.org/10.2343/geochemj.2.0322	journal	January 2014
The experimental determination of REE partition coefficients in the water-calcite system Voigt, Martin; Mavromatis, Vasileios; Oelkers, Eric H. Chemical Geology, Vol. 462 https://doi.org/10.1016/j.chemgeo.2017.04.024	journal	June 2017
Charge Compensation in Solid Solutions Schmidt, Moritz; Stumpf, Thorsten; Marques Fernandes, Maria Angewandte Chemie International Edition, Vol. 47, Issue 31 https://doi.org/10.1002/anie.200705827	journal	July 2008
Incorporation of trivalent actinides into calcite: A time resolved laser fluorescence spectroscopy (TRLFS) study Fernandes, M. Marques; Stumpf, T.; Rabung, T. Geochimica et Cosmochimica Acta, Vol. 72, Issue 2 https://doi.org/10.1016/j.gca.2007.10.015	journal	January 2008
Relationship between surface structure, growth mechanism, and trace element incorporation in calcite Paquette, Jeanne; Reeder, Richard J. Geochimica et Cosmochimica Acta, Vol. 59, Issue 4 https://doi.org/10.1016/0016-7037(95)00004-J	journal	February 1995
Oxygen isotope fractionation between calcite and fluid as a function of growth rate and temperature: An in situ study Gabitov, Rinat I.; Watson, E. Bruce; Sadekov, Aleksey Chemical Geology, Vol. 306-307 https://doi.org/10.1016/j.chemgeo.2012.02.021	journal	May 2012
An intensity ratio calibration method for the accurate determination of Mg/Ca and Sr/Ca of marine carbonates by ICP-AES: MARINE CARBONATE ANALYSIS de Villiers, Stephanie; Greaves, Mervyn; Elderfield, Henry Geochemistry, Geophysics, Geosystems, Vol. 3, Issue 1 https://doi.org/10.1029/2001GC000169	journal	January 2002
Coulometric total carbon dioxide analysis for marine studies: maximizing the performance of an automated gas extraction system and coulometric detector Johnson, K. M.; Wills, K. D.; Butler, D. B. Marine Chemistry, Vol. 44, Issue 2-4 https://doi.org/10.1016/0304-4203(93)90201-X	journal	December 1993
Comparative hydrolysis behavior of the rare earths and yttrium: the influence of temperature and ionic strength Klungness, Greta D.; Byrne, Robert H. Polyhedron, Vol. 19, Issue 1 https://doi.org/10.1016/S0277-5387(99)00332-0	journal	January 2000
Comparative carbonate complexation of yttrium and gadolinium at 25 °C and 0.7 mol dm−3 ionic strength Liu, Xuewu; Byrne, Robert H. Marine Chemistry, Vol. 51, Issue 3 https://doi.org/10.1016/0304-4203(95)00067-4	journal	December 1995
Carbonate complexation of yttrium and the rare earth elements in natural waters Luo, Yu-Ran; Byrne, Robert H. Geochimica et Cosmochimica Acta, Vol. 68, Issue 4 https://doi.org/10.1016/S0016-7037(03)00495-2	journal	February 2004
Growth-step-selective incorporation of boron on the calcite surface Hemming, N. Gary; Reeder, Richard J.; Hart, Stanley R. Geochimica et Cosmochimica Acta, Vol. 62, Issue 17 https://doi.org/10.1016/S0016-7037(98)00214-2	journal	September 1998
Nanoscale effects of strontium on calcite growth: An in situ AFM study in the absence of vital effects Wasylenki, Laura E.; Dove, Patricia M.; Wilson, Darren S. Geochimica et Cosmochimica Acta, Vol. 69, Issue 12 https://doi.org/10.1016/j.gca.2004.12.019	journal	June 2005
Surface enrichment and trace-element uptake during crystal growth Watson, E. Bruce Geochimica et Cosmochimica Acta, Vol. 60, Issue 24 https://doi.org/10.1016/S0016-7037(96)00299-2	journal	December 1996
A conceptual model for near-surface kinetic controls on the trace-element and stable isotope composition of abiogenic calcite crystals 1 1Associate editor: R.H. Byrne Watson, E. Bruce Geochimica et Cosmochimica Acta, Vol. 68, Issue 7 https://doi.org/10.1016/j.gca.2003.10.003	journal	April 2004
A simple model for sector zoning in slowly grown crystals; implications for growth rate and lattice diffusion, with emphasis on accessory minerals in crustal rocks Watson, E. Bruce; Liang, Yan American Mineralogist, Vol. 80, Issue 11-12 https://doi.org/10.2138/am-1995-11-1209	journal	December 1995
Surface speciation of calcite observed in situ by high-resolution X-ray reflectivity Fenter, P.; Geissbühler, P.; DiMasi, E. Geochimica et Cosmochimica Acta, Vol. 64, Issue 7 https://doi.org/10.1016/S0016-7037(99)00403-2	journal	April 2000
Near-surface controls on the composition of growing crystals: Car–Parrinello molecular dynamics (CPMD) simulations of Ti energetics and diffusion in alpha quartz Lanzillo, N. A.; Watson, E. B.; Thomas, J. B. Geochimica et Cosmochimica Acta, Vol. 131 https://doi.org/10.1016/j.gca.2014.01.015	journal	April 2014
Experimental determination of growth rate effect on U6+ and Mg2+ partitioning between aragonite and fluid at elevated U6+ concentration Gabitov, R. I.; Gaetani, G. A.; Watson, E. B. Geochimica et Cosmochimica Acta, Vol. 72, Issue 16 https://doi.org/10.1016/j.gca.2008.05.047	journal	August 2008
Crystal growth rate effect on Mg/Ca and Sr/Ca partitioning between calcite and fluid: An in situ approach Gabitov, R. I.; Sadekov, A.; Leinweber, A. Chemical Geology, Vol. 367 https://doi.org/10.1016/j.chemgeo.2013.12.019	journal	February 2014
Relative precipitation rates of aragonite and Mg calcite from seawater: Temperature or carbonate ion control? Burton, Elizabeth A.; Walter, Lynn M. Geology, Vol. 15, Issue 2 https://doi.org/10.1130/0091-7613(1987)15<111:RPROAA>2.0.CO;2	journal	January 1987
In situ study of boron partitioning between calcite and fluid at different crystal growth rates Gabitov, Rinat I.; Rollion-Bard, Claire; Tripati, Aradhna Geochimica et Cosmochimica Acta, Vol. 137 https://doi.org/10.1016/j.gca.2014.04.014	journal	July 2014
Non-equilibrium isotopic and elemental fractionation during diffusion-controlled crystal growth under static and dynamic conditions Watson, E. Bruce; Müller, Thomas Chemical Geology, Vol. 267, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2008.10.036	journal	September 2009
Diffusion of ions in sea water and in deep-sea sediments Yuan-Hui, Li; Gregory, Sandra Geochimica et Cosmochimica Acta, Vol. 38, Issue 5 https://doi.org/10.1016/0016-7037(74)90145-8	journal	May 1974
An experimental study of hydroxylbastnasite solubility in aqueous solutions at 25 °C Voigt, Martin; Rodriguez-Blanco, Juan Diego; Vallina, Beatriz Chemical Geology, Vol. 430 https://doi.org/10.1016/j.chemgeo.2016.03.012	journal	July 2016
Preparation of Artificial Seawater1 Kester, Dana R.; Duedall, Iver W.; Connors, Donald N. Limnology and Oceanography, Vol. 12, Issue 1 https://doi.org/10.4319/lo.1967.12.1.0176	journal	April 1967
Effect of mineralogy, salinity, and temperature on Li/Ca and Li isotope composition of calcium carbonate Marriott, Caedmon S.; Henderson, Gideon M.; Crompton, Rebecca Chemical Geology, Vol. 212, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2004.08.002	journal	November 2004
Uptake of sodium and potassium by calcite Ishikawa, M.; Ichikuni, M. Chemical Geology, Vol. 42, Issue 1-4 https://doi.org/10.1016/0009-2541(84)90010-X	journal	January 1984

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