Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) 2 ] 2

doi:https://doi.org/10.1021/acs.inorgchem.6b03097

Title: Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) ₂ ] ₂

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Abstract

Diamond anvil cell techniques, synchrotron-based infrared and Raman spectroscopies, and lattice dynamics calculations are combined with prior magnetic property work to reveal the pressure–temperature phase diagram of Co[N(CN)2]2. The second-order structural boundaries converge on key areas of activity involving the spin state exposing how the pressure-induced local lattice distortions trigger the ferromagnetic → antiferromagnetic transition in this quantum material.

Authors:

^[1]; O’Neal, K. R. ^[1]; Brinzari, T. V. ^[1]; Chen, P. ^[1]; Schlueter, J. A. ^[2]; Manson, J. L. ^[3]; Litvinchuk, A. P. ^[4]; Liu, Z. ^[5]

Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996, United States
Division of Materials Research, National Science Foundation, Arlington, Virginia 22230, United States
Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, Washington 99004, United States
Texas Center for Superconductivity and Department of Physics, University of Houston, Houston, Texas 77204, United States
Geophysical Laboratory, Carnegie Institution of Washington, Washington, D.C. 20015, United States

Publication Date:: 2017-04-07

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1409589

Report Number(s):: BNL-114641-2017-JA¿¿¿
Journal ID: ISSN 0020-1669

DOE Contract Number:: SC0012704

Resource Type:: Journal Article

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Volume: 56; Journal Issue: 9; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Musfeldt, J. L., O’Neal, K. R., Brinzari, T. V., Chen, P., Schlueter, J. A., Manson, J. L., Litvinchuk, A. P., and Liu, Z. Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) 2 ] 2.  United States: N. p., 2017. 
        Web.  doi:10.1021/acs.inorgchem.6b03097.

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                    Musfeldt, J. L., O’Neal, K. R., Brinzari, T. V., Chen, P., Schlueter, J. A., Manson, J. L., Litvinchuk, A. P., & Liu, Z. Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) 2 ] 2.  United States.  https://doi.org/10.1021/acs.inorgchem.6b03097

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                    Musfeldt, J. L., O’Neal, K. R., Brinzari, T. V., Chen, P., Schlueter, J. A., Manson, J. L., Litvinchuk, A. P., and Liu, Z. Fri .  
        "Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) 2 ] 2".  United States.  https://doi.org/10.1021/acs.inorgchem.6b03097.

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@article{osti_1409589,

  title        = {Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) 2 ] 2},

  author       = {Musfeldt, J. L. and O’Neal, K. R. and Brinzari, T. V. and Chen, P. and Schlueter, J. A. and Manson, J. L. and Litvinchuk, A. P. and Liu, Z.},

  abstractNote = {Diamond anvil cell techniques, synchrotron-based infrared and Raman spectroscopies, and lattice dynamics calculations are combined with prior magnetic property work to reveal the pressure–temperature phase diagram of Co[N(CN)2]2. The second-order structural boundaries converge on key areas of activity involving the spin state exposing how the pressure-induced local lattice distortions trigger the ferromagnetic → antiferromagnetic transition in this quantum material.},

  doi          = {10.1021/acs.inorgchem.6b03097},

  url          = {https://www.osti.gov/biblio/1409589},
  journal      = {Inorganic Chemistry},

  issn         = {0020-1669},

  number       = 9,

  volume       = 56,

  place        = {United States},

  year         = {2017},

  month        = {4}

}

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Title: Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) 2 ] 2

Abstract

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Title: Pressure–Temperature Phase Diagram Reveals Spin–Lattice Interactions in Co[N(CN) ₂ ] ₂