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Title: A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase

Abstract

A self-assembled ternary blend bulk heterojunction increases the optimal blend thickness, making it suitable for practical roll-to-roll organic solar cell fabrication.

Authors:
 [1];  [1];  [1];  [1];  [2];  [1];  [1]; ORCiD logo [3];  [1]
  1. Department of Materials Science and Engineering; Stony Brook University; Stony Brook; USA
  2. Center for Neutron Research; National Institute of Standards and Technology; Gaithersburg; USA
  3. Center for Functional Nanomaterials; Brookhaven National Laboratory; Upton; USA
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1409518
Report Number(s):
BNL-114570-2017-JA¿¿¿
Journal ID: ISSN 2040-3364; NANOHL
DOE Contract Number:  
SC0012704
Resource Type:
Journal Article
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 9; Journal Issue: 32; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Li, Hongfei, Yang, Zhenhua, Pan, Cheng, Jiang, Naisheng, Satija, Sushil K., Xu, Di, Gersappe, Dilip, Nam, Chang-Yong, and Rafailovich, Miriam H. A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase. United States: N. p., 2017. Web. doi:10.1039/C7NR03789A.
Li, Hongfei, Yang, Zhenhua, Pan, Cheng, Jiang, Naisheng, Satija, Sushil K., Xu, Di, Gersappe, Dilip, Nam, Chang-Yong, & Rafailovich, Miriam H. A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase. United States. doi:10.1039/C7NR03789A.
Li, Hongfei, Yang, Zhenhua, Pan, Cheng, Jiang, Naisheng, Satija, Sushil K., Xu, Di, Gersappe, Dilip, Nam, Chang-Yong, and Rafailovich, Miriam H. Sun . "A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase". United States. doi:10.1039/C7NR03789A.
@article{osti_1409518,
title = {A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase},
author = {Li, Hongfei and Yang, Zhenhua and Pan, Cheng and Jiang, Naisheng and Satija, Sushil K. and Xu, Di and Gersappe, Dilip and Nam, Chang-Yong and Rafailovich, Miriam H.},
abstractNote = {A self-assembled ternary blend bulk heterojunction increases the optimal blend thickness, making it suitable for practical roll-to-roll organic solar cell fabrication.},
doi = {10.1039/C7NR03789A},
journal = {Nanoscale},
issn = {2040-3364},
number = 32,
volume = 9,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

A Study on the Correlation Between Structure and Hole Transport in Semi-Crystalline Regioregular P3HT
journal, September 2012

  • Shen, Xiaobo; Duzhko, Volodimyr V.; Russell, Thomas P.
  • Advanced Energy Materials, Vol. 3, Issue 2
  • DOI: 10.1002/aenm.201200509

Enhancing the efficiency of low bandgap conducting polymer bulk heterojunction solar cells using P3HT as a morphology control agent
journal, January 2013

  • Chang, Sheng-Yung; Liao, Hsueh-Chung; Shao, Yu-Tsun
  • Journal of Materials Chemistry A, Vol. 1, Issue 7
  • DOI: 10.1039/c2ta00990k

Depletion of PCBM at the Cathode Interface in P3HT/PCBM Thin Films as Quantified via Neutron Reflectivity Measurements
journal, June 2010

  • Parnell, Andrew J.; Dunbar, Alan D. F.; Pearson, Andrew J.
  • Advanced Materials, Vol. 22, Issue 22
  • DOI: 10.1002/adma.200903971

Crystallization-Induced 10-nm Structure Formation in P3HT/PCBM Blends
journal, April 2013

  • Kohn, Peter; Rong, Zhuxia; Scherer, Kai H.
  • Macromolecules, Vol. 46, Issue 10
  • DOI: 10.1021/ma400403c

Ternary blend polymer solar cells with enhanced power conversion efficiency
journal, August 2014


Miscibility, Crystallinity, and Phase Development in P3HT/PCBM Solar Cells: Toward an Enlightened Understanding of Device Morphology and Stability
journal, November 2011

  • Collins, Brian A.; Tumbleston, John R.; Ade, Harald
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 24
  • DOI: 10.1021/jz2014902

Two-dimensional charge transport in self-organized, high-mobility conjugated polymers
journal, October 1999

  • Sirringhaus, H.; Brown, P. J.; Friend, R. H.
  • Nature, Vol. 401, Issue 6754, p. 685-688
  • DOI: 10.1038/44359

Materials for the Active Layer of Organic Photovoltaics: Ternary Solar Cell Approach
journal, January 2013


Real-Time Investigation of Crystallization and Phase-Segregation Dynamics in P3HT:PCBM Solar Cells During Thermal Annealing
journal, March 2011

  • Agostinelli, Tiziano; Lilliu, Samuele; Labram, John G.
  • Advanced Functional Materials, Vol. 21, Issue 9
  • DOI: 10.1002/adfm.201002076

Surface Studies of Solids by Total Reflection of X-Rays
journal, July 1954


P3HT/PCBM Bulk Heterojunction Solar Cells: Impact of Blend Composition and 3D Morphology on Device Performance
journal, April 2010

  • van Bavel, Svetlana S.; Bärenklau, Maik; de With, Gijsbertus
  • Advanced Functional Materials, Vol. 20, Issue 9
  • DOI: 10.1002/adfm.200902247

Recombination and loss analysis in polythiophene based bulk heterojunction photodetectors
journal, November 2002

  • Schilinsky, Pavel; Waldauf, Christoph; Brabec, Christoph J.
  • Applied Physics Letters, Vol. 81, Issue 20
  • DOI: 10.1063/1.1521244

Investigation of annealing effects and film thickness dependence of polymer solar cells based on poly(3-hexylthiophene)
journal, August 2005

  • Li, Gang; Shrotriya, Vishal; Yao, Yan
  • Journal of Applied Physics, Vol. 98, Issue 4
  • DOI: 10.1063/1.2008386

Improved Power Conversion Efficiency in Bulk Heterojunction Organic Solar Cells with Radial Electron Contacts
journal, September 2011

  • Allen, Jonathan E.; Black, Charles T.
  • ACS Nano, Vol. 5, Issue 10
  • DOI: 10.1021/nn2031963

The Scope and Limitations of Ternary Blend Organic Photovoltaics
journal, September 2014

  • Savoie, Brett M.; Dunaisky, Scott; Marks, Tobin J.
  • Advanced Energy Materials, Vol. 5, Issue 3
  • DOI: 10.1002/aenm.201400891

Modeling optical effects and thickness dependent current in polymer bulk-heterojunction solar cells
journal, January 2006

  • Sievers, Douglas W.; Shrotriya, Vishal; Yang, Yang
  • Journal of Applied Physics, Vol. 100, Issue 11
  • DOI: 10.1063/1.2388854

High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends
journal, October 2005

  • Li, Gang; Shrotriya, Vishal; Huang, Jinsong
  • Nature Materials, Vol. 4, Issue 11, p. 864-868
  • DOI: 10.1038/nmat1500

Control of the nanoscale crystallinity and phase separation in polymer solar cells
journal, March 2008

  • Chu, Chih-Wei; Yang, Hoichang; Hou, Wei-Jen
  • Applied Physics Letters, Vol. 92, Issue 10
  • DOI: 10.1063/1.2891884

Enhancing the Efficiency of Bulk Heterojunction Solar Cells via Templated Self-Assembly
journal, February 2013

  • Pan, Cheng; Li, Hongfei; Akgun, Bulent
  • Macromolecules, Vol. 46, Issue 5
  • DOI: 10.1021/ma302458d

Fabrication and processing of polymer solar cells: A review of printing and coating techniques
journal, April 2009


Roll-to-Roll Printed Large-Area All-Polymer Solar Cells with 5% Efficiency Based on a Low Crystallinity Conjugated Polymer Blend
journal, March 2017


Optimization of thickness and morphology of active layer for high performance of bulk-heterojunction organic solar cells
journal, June 2010


High-performance multiple-donor bulk heterojunction solar cells
journal, February 2015


P3HT/PCBM Bulk Heterojunction Organic Photovoltaics: Correlating Efficiency and Morphology
journal, February 2011

  • Chen, Dian; Nakahara, Atsuhiro; Wei, Dongguang
  • Nano Letters, Vol. 11, Issue 2, p. 561-567
  • DOI: 10.1021/nl103482n

Enhanced Hole Mobility in Regioregular Polythiophene Infiltrated in Straight Nanopores
journal, December 2005

  • Coakley, K. M.; Srinivasan, B. S.; Ziebarth, J. M.
  • Advanced Functional Materials, Vol. 15, Issue 12
  • DOI: 10.1002/adfm.200500364

Submicron-scale manipulation of phase separation in organic solar cells
journal, January 2008

  • Chen, Fang-Chung; Lin, Yi-Kai; Ko, Chu-Jung
  • Applied Physics Letters, Vol. 92, Issue 2
  • DOI: 10.1063/1.2835047

Enhanced charge collection in confined bulk heterojunction organic solar cells
journal, October 2011

  • Allen, Jonathan E.; Yager, Kevin G.; Hlaing, Htay
  • Applied Physics Letters, Vol. 99, Issue 16
  • DOI: 10.1063/1.3651509

Enhanced Power Conversion Efficiency of Low Band-Gap Polymer Solar Cells by Insertion of Optimized Binary Processing Additives
journal, October 2013

  • Wang, Dong Hwan; Kyaw, Aung Ko Ko; Pouliot, Jean-Rémi
  • Advanced Energy Materials, Vol. 4, Issue 4
  • DOI: 10.1002/aenm.201300835

Panchromatic polymer–polymer ternary solar cells enhanced by Förster resonance energy transfer and solvent vapor annealing
journal, January 2015

  • Goh, Tenghooi; Huang, Jing-Shun; Bartolome, Benjamin
  • Journal of Materials Chemistry A, Vol. 3, Issue 36
  • DOI: 10.1039/C5TA04905A

Charge-Transport Anisotropy Due to Grain Boundaries in Directionally Crystallized Thin Films of Regioregular Poly(3-hexylthiophene)
journal, April 2009

  • Jimison, Leslie H.; Toney, Michael F.; McCulloch, Iain
  • Advanced Materials, Vol. 21, Issue 16
  • DOI: 10.1002/adma.200802722

Dynamics of entangled linear polymer melts:  A molecular‐dynamics simulation
journal, April 1990

  • Kremer, Kurt; Grest, Gary S.
  • The Journal of Chemical Physics, Vol. 92, Issue 8
  • DOI: 10.1063/1.458541

In situ measurement of power conversion efficiency and molecular ordering during thermal annealing in P3HT:PCBM bulk heterojunction solar cells
journal, January 2011

  • Treat, Neil D.; Shuttle, Chris G.; Toney, Michael F.
  • Journal of Materials Chemistry, Vol. 21, Issue 39
  • DOI: 10.1039/c1jm12677f

Self‐assembly of a homopolymer mixture via phase separation
journal, May 1994

  • Krausch, Georg; Kramer, Edward J.; Rafailovich, Miriam H.
  • Applied Physics Letters, Vol. 64, Issue 20
  • DOI: 10.1063/1.111482

Phase Diagram of P3HT/PCBM Blends and Its Implication for the Stability of Morphology
journal, February 2009

  • Zhao, Jun; Swinnen, Ann; Van Assche, Guy
  • The Journal of Physical Chemistry B, Vol. 113, Issue 6, p. 1587-1591
  • DOI: 10.1021/jp804151a

Nanoparticle concentration profile in polymer-based solar cells
journal, January 2010

  • Kiel, Jonathan W.; Kirby, Brian J.; Majkrzak, Charles F.
  • Soft Matter, Vol. 6, Issue 3, p. 641-646
  • DOI: 10.1039/B920979D

Polymer bulk heterojunction solar cells employing Förster resonance energy transfer
journal, May 2013


Polymer-Fullerene Bulk-Heterojunction Solar Cells
journal, April 2009

  • Dennler, Gilles; Scharber, Markus C.; Brabec, Christoph J.
  • Advanced Materials, Vol. 21, Issue 13, p. 1323-1338
  • DOI: 10.1002/adma.200801283

Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology
journal, October 2005

  • Ma, W.; Yang, C.; Gong, X.
  • Advanced Functional Materials, Vol. 15, Issue 10, p. 1617-1622
  • DOI: 10.1002/adfm.200500211

25th Anniversary Article: Bulk Heterojunction Solar Cells: Understanding the Mechanism of Operation
journal, December 2013


Solution-processed small-molecule solar cells: breaking the 10% power conversion efficiency
journal, November 2013

  • Liu, Yongsheng; Chen, Chun-Chao; Hong, Ziruo
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep03356

Pathways for the degradation of organic photovoltaic P3HT:PCBM based devices
journal, July 2008

  • Reese, Matthew O.; Morfa, Anthony J.; White, Matthew S.
  • Solar Energy Materials and Solar Cells, Vol. 92, Issue 7
  • DOI: 10.1016/j.solmat.2008.01.020

Simultaneous Use of Small‐ and Wide‐Angle X‐ray Techniques to Analyze Nanometerscale Phase Separation in Polymer Heterojunction Solar Cells
journal, July 2008

  • Chiu, Mao‐Yuan; Jeng, U‐Ser; Su, Chiu‐Hun
  • Advanced Materials, Vol. 20, Issue 13
  • DOI: 10.1002/adma.200703097

Effect of electron-transport polymer addition to polymer/fullerene blend solar cells
journal, September 2005


Bulk heterojunction solar cells with internal quantum efficiency approaching 100%
journal, April 2009

  • Park, Sung Heum; Roy, Anshuman; Beaupré, Serge
  • Nature Photonics, Vol. 3, Issue 5, p. 297-302
  • DOI: 10.1038/nphoton.2009.69

Dependence of Regioregular Poly(3-hexylthiophene) Film Morphology and Field-Effect Mobility on Molecular Weight
journal, April 2005

  • Kline, R. Joseph; McGehee, Michael D.; Kadnikova, Ekaterina N.
  • Macromolecules, Vol. 38, Issue 8, p. 3312-3319
  • DOI: 10.1021/ma047415f

Record High Hole Mobility in Polymer Semiconductors via Side-Chain Engineering
journal, September 2013

  • Kang, Il; Yun, Hui-Jun; Chung, Dae Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 40
  • DOI: 10.1021/ja405112s

Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions
journal, December 1995


Effects of Thermal Annealing Upon the Morphology of Polymer-Fullerene Blends
journal, August 2010

  • Verploegen, Eric; Mondal, Rajib; Bettinger, Christopher J.
  • Advanced Functional Materials, Vol. 20, Issue 20
  • DOI: 10.1002/adfm.201000975

Low bandgap polymers for photon harvesting in bulk heterojunction solar cells
journal, January 2004

  • Winder, Christoph; Sariciftci, Niyazi Serdar
  • Journal of Materials Chemistry, Vol. 14, Issue 7
  • DOI: 10.1039/b306630d

Interdiffusion of PCBM and P3HT Reveals Miscibility in a Photovoltaically Active Blend
journal, November 2010

  • Treat, Neil D.; Brady, Michael A.; Smith, Gordon
  • Advanced Energy Materials, Vol. 1, Issue 1, p. 82-89
  • DOI: 10.1002/aenm.201000023

Ultra Fast and Parsimonious Materials Screening for Polymer Solar Cells Using Differentially Pumped Slot-Die Coating
journal, September 2010

  • Alstrup, Jan; Jørgensen, Mikkel; Medford, Andrew J.
  • ACS Applied Materials & Interfaces, Vol. 2, Issue 10
  • DOI: 10.1021/am100505e

Formation of Nanopatterned Polymer Blends in Photovoltaic Devices
journal, April 2010

  • He, Ximin; Gao, Feng; Tu, Guoli
  • Nano Letters, Vol. 10, Issue 4
  • DOI: 10.1021/nl904098m

High-performance ternary blend polymer solar cells involving both energy transfer and hole relay processes
journal, June 2015

  • Lu, Luyao; Chen, Wei; Xu, Tao
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8327

For the Bright Future-Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4%
journal, May 2010

  • Liang, Yongye; Xu, Zheng; Xia, Jiangbin
  • Advanced Materials, Vol. 22, Issue 20, p. E135-E138
  • DOI: 10.1002/adma.200903528

Nanostructured electrodes for organic bulk heterojunction solar cells: Model study using carbon nanotube dispersed polythiophene-fullerene blend devices
journal, September 2011

  • Nam, Chang-Yong; Wu, Qin; Su, Dong
  • Journal of Applied Physics, Vol. 110, Issue 6
  • DOI: 10.1063/1.3633236

High-Molecular-Weight Insulating Polymers Can Improve the Performance of Molecular Solar Cells
journal, April 2014

  • Huang, Ye; Wen, Wen; Mukherjee, Subhrangsu
  • Advanced Materials, Vol. 26, Issue 24
  • DOI: 10.1002/adma.201400497

Charge Transport and Photocurrent Generation in Poly(3-hexylthiophene): Methanofullerene Bulk-Heterojunction Solar Cells
journal, March 2006

  • Mihailetchi, V. D.; Xie, H. X.; de Boer, B.
  • Advanced Functional Materials, Vol. 16, Issue 5
  • DOI: 10.1002/adfm.200500420

Poly(3-hexylthiophene) Nanorods with Aligned Chain Orientation for Organic Photovoltaics
journal, February 2010

  • Kim, Jong Soo; Park, Yunmin; Lee, Dong Yun
  • Advanced Functional Materials, Vol. 20, Issue 4
  • DOI: 10.1002/adfm.200901760

Molecular-Scale and Nanoscale Morphology of P3HT:PCBM Bulk Heterojunctions: Energy-Filtered TEM and Low-Dose HREM
journal, February 2011

  • Drummy, Lawrence F.; Davis, Robert J.; Moore, Diana L.
  • Chemistry of Materials, Vol. 23, Issue 3
  • DOI: 10.1021/cm102463t

High-Performance Air-Processed Polymer–Fullerene Bulk Heterojunction Solar Cells
journal, November 2009

  • Nam, Chang-Yong; Su, Dong; Black, Charles T.
  • Advanced Functional Materials, Vol. 19, Issue 22
  • DOI: 10.1002/adfm.200900311

Parallel-like Bulk Heterojunction Polymer Solar Cells
journal, March 2012

  • Yang, Liqiang; Zhou, Huaxing; Price, Samuel C.
  • Journal of the American Chemical Society, Vol. 134, Issue 12
  • DOI: 10.1021/ja211597w

Tandem polymer solar cells featuring a spectrally matched low-bandgap polymer
journal, February 2012


10.2% Power Conversion Efficiency Polymer Tandem Solar Cells Consisting of Two Identical Sub-Cells
journal, May 2013


Nanoscale Phase Separation and High Photovoltaic Efficiency in Solution-Processed, Small-Molecule Bulk Heterojunction Solar Cells
journal, October 2009

  • Walker, Bright; Tamayo, Arnold B.; Dang, Xuan-Dung
  • Advanced Functional Materials, Vol. 19, Issue 19, p. 3063-3069
  • DOI: 10.1002/adfm.200900832

Transport in polycrystalline polymer thin-film transistors
journal, April 2005