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Title: Honeycomb-Ordered Na 3Ni 1.5M 0.5BiO 6 (M = Ni, Cu, Mg, Zn) as High-Voltage Layered Cathodes for Sodium-Ion Batteries

Abstract

Developing high-voltage layered cathodes for sodium-ion batteries (SIBs) has always been a severe challenge. Herein, a new family of honeycomb-layered Na 3Ni 1.5M 0.5BiO 6 (M = Ni, Cu, Mg, Zn) with a monoclinic superstructure has been shown to combine good Na + (de)intercalation activity with a competitive 3.3 V high voltage. By coupling the electrochemical process with ex situ X-ray absorption spectroscopy as well as in situ X-ray diffraction, the charge compensation mechanism and structural evolution of these new cathodes are clearly investigated. Interestingly, both Ni 2+/Ni 3+ and Cu 2+/Cu 3+ participate in the redox reaction upon cycling, and the succession of single-phase, two-phase, or three-phase regions upon Na+ extraction/insertion were identified with rather good accuracy. Furthermore, this research strategy could provide insights into the structure–function–property relationships on a new series of honeycomb-ordered materials with the general formula Na 3Ni 1.5M 0.5BiO 6 and also serve as a bridge to guide future design of high-performance cathodes for SIBs.

Authors:
ORCiD logo [1];  [1];  [1]; ORCiD logo [1];  [2];  [2];  [3];  [3];  [4]; ORCiD logo [5]; ORCiD logo [1]
  1. Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Qingdao Univ., Qingdao (China)
  4. Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Science, Beijing (China)
  5. Chinese Academy of Sciences (CAS), Beijing (China)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1409508
Report Number(s):
BNL-114520-2017-JA
Journal ID: ISSN 2380-8195; R&D Project: MA453MAEA; VT1201000
Grant/Contract Number:  
SC0012704
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ACS Energy Letters
Additional Journal Information:
Journal Volume: 2; Journal ID: ISSN 2380-8195
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; National Synchrotron Light Source

Citation Formats

Wang, Peng -Fei, Guo, Yu -Jie, Duan, Hui, Zuo, Tong -Tong, Hu, Enyuan, Attenkofer, Klaus, Li, Hongliang, Zhao, Xiu Song, Yin, Ya -Xia, Yu, Xiqian, and Guo, Yu -Guo. Honeycomb-Ordered Na3Ni1.5M0.5BiO6 (M = Ni, Cu, Mg, Zn) as High-Voltage Layered Cathodes for Sodium-Ion Batteries. United States: N. p., 2017. Web. doi:10.1021/acsenergylett.7b00930.
Wang, Peng -Fei, Guo, Yu -Jie, Duan, Hui, Zuo, Tong -Tong, Hu, Enyuan, Attenkofer, Klaus, Li, Hongliang, Zhao, Xiu Song, Yin, Ya -Xia, Yu, Xiqian, & Guo, Yu -Guo. Honeycomb-Ordered Na3Ni1.5M0.5BiO6 (M = Ni, Cu, Mg, Zn) as High-Voltage Layered Cathodes for Sodium-Ion Batteries. United States. doi:10.1021/acsenergylett.7b00930.
Wang, Peng -Fei, Guo, Yu -Jie, Duan, Hui, Zuo, Tong -Tong, Hu, Enyuan, Attenkofer, Klaus, Li, Hongliang, Zhao, Xiu Song, Yin, Ya -Xia, Yu, Xiqian, and Guo, Yu -Guo. Wed . "Honeycomb-Ordered Na3Ni1.5M0.5BiO6 (M = Ni, Cu, Mg, Zn) as High-Voltage Layered Cathodes for Sodium-Ion Batteries". United States. doi:10.1021/acsenergylett.7b00930.
@article{osti_1409508,
title = {Honeycomb-Ordered Na3Ni1.5M0.5BiO6 (M = Ni, Cu, Mg, Zn) as High-Voltage Layered Cathodes for Sodium-Ion Batteries},
author = {Wang, Peng -Fei and Guo, Yu -Jie and Duan, Hui and Zuo, Tong -Tong and Hu, Enyuan and Attenkofer, Klaus and Li, Hongliang and Zhao, Xiu Song and Yin, Ya -Xia and Yu, Xiqian and Guo, Yu -Guo},
abstractNote = {Developing high-voltage layered cathodes for sodium-ion batteries (SIBs) has always been a severe challenge. Herein, a new family of honeycomb-layered Na3Ni1.5M0.5BiO6 (M = Ni, Cu, Mg, Zn) with a monoclinic superstructure has been shown to combine good Na+ (de)intercalation activity with a competitive 3.3 V high voltage. By coupling the electrochemical process with ex situ X-ray absorption spectroscopy as well as in situ X-ray diffraction, the charge compensation mechanism and structural evolution of these new cathodes are clearly investigated. Interestingly, both Ni2+/Ni3+ and Cu2+/Cu3+ participate in the redox reaction upon cycling, and the succession of single-phase, two-phase, or three-phase regions upon Na+ extraction/insertion were identified with rather good accuracy. Furthermore, this research strategy could provide insights into the structure–function–property relationships on a new series of honeycomb-ordered materials with the general formula Na3Ni1.5M0.5BiO6 and also serve as a bridge to guide future design of high-performance cathodes for SIBs.},
doi = {10.1021/acsenergylett.7b00930},
journal = {ACS Energy Letters},
number = ,
volume = 2,
place = {United States},
year = {Wed Nov 01 00:00:00 EDT 2017},
month = {Wed Nov 01 00:00:00 EDT 2017}
}

Journal Article:
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