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Title: Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides

Abstract

A permanently porous, three-dimensional metal–organic material formed from zero-valent metal nodes is presented. Combination of ditopic m-terphenyl diisocyanide, [CNAr Mes2] 2, and the d 10 Ni(0) precursor Ni(COD) 2, produces a porous metal–organic material featuring tetrahedral [Ni(CNAr Mes2) 4] n structural sites. X-ray absorption spectroscopy provides firm evidence for the presence of Ni(0) centers, whereas gas-sorption and thermogravimetric analysis reveal the characteristics of a robust network with a microdomain N 2-adsorption profile.

Authors:
 [1];  [2];  [1];  [1];  [1];  [2];  [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Univ. of California, San Diego, CA (United States). Dept. of Chemistry and Biochemistry
  2. Cornell Univ., Ithaca, NY (United States). Baker Lab., Dept. of Chemistry and Chemical Biology
Publication Date:
Research Org.:
Univ. of California, San Diego, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF); USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)
OSTI Identifier:
1409488
Alternate Identifier(s):
OSTI ID: 1413210
Grant/Contract Number:
SC0008058; AC02-76SF00515
Resource Type:
Journal Article: Published Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 139; Journal Issue: 48; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Agnew, Douglas W., DiMucci, Ida M., Arroyave, Alejandra, Gembicky, Milan, Moore, Curtis E., MacMillan, Samantha N., Rheingold, Arnold L., Lancaster, Kyle M., and Figueroa, Joshua S. Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. United States: N. p., 2017. Web. doi:10.1021/jacs.7b09569.
Agnew, Douglas W., DiMucci, Ida M., Arroyave, Alejandra, Gembicky, Milan, Moore, Curtis E., MacMillan, Samantha N., Rheingold, Arnold L., Lancaster, Kyle M., & Figueroa, Joshua S. Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. United States. doi:10.1021/jacs.7b09569.
Agnew, Douglas W., DiMucci, Ida M., Arroyave, Alejandra, Gembicky, Milan, Moore, Curtis E., MacMillan, Samantha N., Rheingold, Arnold L., Lancaster, Kyle M., and Figueroa, Joshua S. Mon . "Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides". United States. doi:10.1021/jacs.7b09569.
@article{osti_1409488,
title = {Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides},
author = {Agnew, Douglas W. and DiMucci, Ida M. and Arroyave, Alejandra and Gembicky, Milan and Moore, Curtis E. and MacMillan, Samantha N. and Rheingold, Arnold L. and Lancaster, Kyle M. and Figueroa, Joshua S.},
abstractNote = {A permanently porous, three-dimensional metal–organic material formed from zero-valent metal nodes is presented. Combination of ditopic m-terphenyl diisocyanide, [CNArMes2]2, and the d10 Ni(0) precursor Ni(COD)2, produces a porous metal–organic material featuring tetrahedral [Ni(CNArMes2)4]n structural sites. X-ray absorption spectroscopy provides firm evidence for the presence of Ni(0) centers, whereas gas-sorption and thermogravimetric analysis reveal the characteristics of a robust network with a microdomain N2-adsorption profile.},
doi = {10.1021/jacs.7b09569},
journal = {Journal of the American Chemical Society},
number = 48,
volume = 139,
place = {United States},
year = {Mon Nov 13 00:00:00 EST 2017},
month = {Mon Nov 13 00:00:00 EST 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1021/jacs.7b09569

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