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Title: Facile and template-free method toward chemical synthesis of polyaniline film/nanotube structures

Abstract

Here, a facile and template-free method is reported to synthesize a new thin film structure: polyaniline (PANI) film/nanotubes (F/N) structure. The PANI F/N is a 100-nm thick PANI film embedded with PANI nanotubes. This well-controlled method requires no surfactant or organic acid as well as relatively low concentration of reagents. Synthesis condition studies reveal that aniline oligomers with certain structures are responsible for guiding the growth of the nanotubes. Electrical characterization also indicates that the PANI F/N possesses similar field-effect transistor characteristics to bare PANI film. With its 20% increased surface-area-to-volume (S/V) ratio contributed by surface embedded nanotubes and the excellent p-type semiconducting characteristic, PANI F/N shows clear superiority compared with bare PANI film. Such advantages guarantee the PANI F/N a promising future toward the development of ultra-high sensitivity and low-cost biosensors.

Authors:
 [1];  [2];  [1];  [3];  [1]
  1. Univ. of Pittsburgh, Pittsburgh, PA (United States)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Chonbuk National Univ., Jeonju (Korea)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Science Foundation (NSF); USDOE
OSTI Identifier:
1409083
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Polymer Science. Part A, Polymer Chemistry
Additional Journal Information:
Journal Volume: 55; Journal Issue: 24; Journal ID: ISSN 0887-624X
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; biomaterials; chemical synthesis; conjugated polymers; field-effect transistors; film/nanotubes; nanotube; polyaniline; sensors

Citation Formats

Liu, Pei, Zhu, Yisi, Torres, Jorge, Lee, Seung Hee, and Yun, Minhee. Facile and template-free method toward chemical synthesis of polyaniline film/nanotube structures. United States: N. p., 2017. Web. doi:10.1002/pola.28749.
Liu, Pei, Zhu, Yisi, Torres, Jorge, Lee, Seung Hee, & Yun, Minhee. Facile and template-free method toward chemical synthesis of polyaniline film/nanotube structures. United States. doi:10.1002/pola.28749.
Liu, Pei, Zhu, Yisi, Torres, Jorge, Lee, Seung Hee, and Yun, Minhee. Tue . "Facile and template-free method toward chemical synthesis of polyaniline film/nanotube structures". United States. doi:10.1002/pola.28749. https://www.osti.gov/servlets/purl/1409083.
@article{osti_1409083,
title = {Facile and template-free method toward chemical synthesis of polyaniline film/nanotube structures},
author = {Liu, Pei and Zhu, Yisi and Torres, Jorge and Lee, Seung Hee and Yun, Minhee},
abstractNote = {Here, a facile and template-free method is reported to synthesize a new thin film structure: polyaniline (PANI) film/nanotubes (F/N) structure. The PANI F/N is a 100-nm thick PANI film embedded with PANI nanotubes. This well-controlled method requires no surfactant or organic acid as well as relatively low concentration of reagents. Synthesis condition studies reveal that aniline oligomers with certain structures are responsible for guiding the growth of the nanotubes. Electrical characterization also indicates that the PANI F/N possesses similar field-effect transistor characteristics to bare PANI film. With its 20% increased surface-area-to-volume (S/V) ratio contributed by surface embedded nanotubes and the excellent p-type semiconducting characteristic, PANI F/N shows clear superiority compared with bare PANI film. Such advantages guarantee the PANI F/N a promising future toward the development of ultra-high sensitivity and low-cost biosensors.},
doi = {10.1002/pola.28749},
journal = {Journal of Polymer Science. Part A, Polymer Chemistry},
number = 24,
volume = 55,
place = {United States},
year = {Tue Sep 05 00:00:00 EDT 2017},
month = {Tue Sep 05 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
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