Redox flow batteries based on supporting solutions containing chloride

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Nie, Zimin; Chen, Baowei; Zhang, Jianlu; Xia, Guanguang

Title: Redox flow batteries based on supporting solutions containing chloride

Patent · Tue Nov 14 00:00:00 EST 2017

OSTI ID:1408903

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Nie, Zimin; Chen, Baowei; Zhang, Jianlu; Xia, Guanguang

Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

View Patent

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

Assignee:: Battelle Memorial Institute (Richland, VA)

Patent Number(s):: 9,819,039

Application Number:: 14/815,037

OSTI ID:: 1408903

Resource Relation:: Patent File Date: 2015 Jul 31

Country of Publication:: United States

Language:: English

References (36)

Redox Fuel Cell Boeke, Jan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3540933 US Patent Document 3,540,933	patent	November 1970
Electrically rechargeable REDOX flow cell Thaller, Lawrence H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3996064 US Patent Document 3,996,064	patent	December 1976
Redox battery including a bromine positive electrode and a chromium ion negative electrode, and method Giner, Jose D.; Stark, Herbert https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4469760 US Patent Document 4,469,760	patent	September 1984
All-vanadium redox battery Skyllas-Kazacos, Maria; Rychick, Miron; Robins, Robert R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4786567 US Patent Document 4,786,567	patent	November 1988
Electrolytes for redox flow batteries Nagashima, Ikuo; Fukui, Jun; Gotoh, Hidenori https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4814241 US Patent Document 4,814,241	patent	March 1989
Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries Kazacos, Maria Skyllas; Kazacos, Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6562514 US Patent Document 6,562,514	patent	May 2003
Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method Tanaka, Yasuyuki; Mita, Muneo; Horikawa, Ken https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6872376 US Patent Document 6,872,376	patent	March 2005
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions Kazacos, Michael; Kazacos, Maria Skyllas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7078123 US Patent Document 7,078,123	patent	July 2006
Vanadium/polyhalide redox flow battery Skyllas-Kazacos, Maria https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7320844 US Patent Document 7,320,844	patent	January 2008
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8628880 US Patent Document 8,628,880	patent	January 2014
Fe-V redox flow batteries Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8771856 US Patent Document 8,771,856	patent	July 2014
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9077011 US Patent Document 9,077,011	patent	July 2015
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9123931 US Patent Document 9,123,931	patent	September 2015
Fully flexible financial instrument pricing system with intelligent user interfaces Lim, Cheong Kee Jeffrey https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030014345 US Patent Document 10/182462; 20030014345	patent-application	January 2003
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions Kazacos, Michael; Kazacos, Maria Skyllas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030143456 US Patent Document 10/226751; 20030143456	patent-application	July 2003
Metal halide redox flow battery Skyllas-Kazacos, Maria; Kazacos, Michael; Mousa, Asem https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050244707 US Patent Document 10/512417; 20050244707	patent-application	November 2005
Novel vanadium halide redox flow battery Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholasl https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060183016 US Patent Document 10/548555; 20060183016	patent-application	August 2006
Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries Kazacos, George Christopher; Kazacos, Nicholas Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080292964 US Patent Document 11/917989; 20080292964	patent-application	November 2008
High Energy Battery Materials Adamson, George W.; Ortiz, Jr., Luis A. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100230632 US Patent Document 11/992378; 20100230632	patent-application	September 2010
Novel Vanadium Halide Redox Flow Battery Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100291420 US Patent Document 12/843521; 20100291420	patent-application	November 2010
Redox Flow Battery System for Distributed Energy Storage Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110045332 US Patent Document 12/883511; 20110045332	patent-application	February 2011
Redox Flow Cell Rebalancing Keshavarz, Majid; Karuppaiah, Chockkalingam; Zu, Ge https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110086247 US Patent Document 12/790573; 20110086247	patent-application	April 2011
System Dongle Parakulam, Gopalakrishnan R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120040216 US Patent Document 12/855059; 20120040216	patent-application	February 2012
Fe-V Redox Flow Batteries Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120077067 US Patent Document 12/892698; 20120077067	patent-application	March 2012
Redox Flow Batteries Based on Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120077079 US Patent Document 12/892693; 20120077079	patent-application	March 2012
Redox Flow Batteries Based On Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140199607 US Patent Application 14/105823; 20140199607	patent-application	July 2014
Redox Flow Batteries Based on Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140234753 US Patent Document 14/261262; 20140234753	patent-application	August 2014
High Energy Density Redox Flow Device Chiang, Yet-Ming; Carter, W. Craig; Duduta, Mihai https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140248521 US Patent Document 14/276723; 20140248521	patent-application	September 2014
All-Vanadium Sulfate Acid Redox Flow Battery System Nie, Zimin; Wang, Wei; Wei, Xiaoliang https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160099480 US Patent Document 14/875565; 20160099480	patent-application	April 2016
Effects of additives on the stability of electrolytes for all-vanadium redox flow batteries Zhang, Jianlu; Li, Liyu; Nie, Zimin Journal of Applied Electrochemistry, Vol. 41, Issue 10, p. 1215-1221 https://doi.org/10.1007/s10800-011-0312-1	journal	June 2011
A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-Scale Energy Storage Li, Liyu; Kim, Soowhan; Wang, Wei Advanced Energy Materials, Vol. 1, Issue 3, p. 394-400 https://doi.org/10.1002/aenm.201100008	journal	March 2011
Use of polyelectrolyte for incorporation of ion-exchange groups in composite membranes for vanadium redox flow battery applications Mohammadi, T.; Skyllas-Kazacos, M. Journal of Power Sources, Vol. 56, Issue 1, p. 91-96 https://doi.org/10.1016/0378-7753(95)80014-8	journal	July 1995
Progress in Flow Battery Research and Development Skyllas-Kazacos, M.; Chakrabarti, M. H.; Hajimolana, S. A. Journal of The Electrochemical Society, Vol. 158, Issue 8, p. R55-R79 https://doi.org/10.1149/1.3599565	journal	June 2011
Novel vanadium chloride/polyhalide redox flow battery Skyllas-Kazacos, Maria Journal of Power Sources, Vol. 124, Issue 1, p. 299-302 https://doi.org/10.1016/S0378-7753(03)00621-9	journal	October 2003
Investigation of the V(V)/V(IV) system for use in the positive half-cell of a redox battery Sum, E.; Rychcik, M.; Skyllas-kazacos, M. Journal of Power Sources, Vol. 16, Issue 2, p. 85-95 https://doi.org/10.1016/0378-7753(85)80082-3	journal	October 1985
A study of the V(II)/V(III) redox couple for redox flow cell applications Sum, E.; Skyllas-Kazacos, M. Journal of Power Sources, Vol. 15, Issue 2-3, p. 179-190 https://doi.org/10.1016/0378-7753(85)80071-9	journal	June 1985

Similar Records

Redox flow batteries based on supporting solutions containing chloride

Patent · Tue Jul 07 00:00:00 EDT 2015 · OSTI ID:1408903

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; +5 more

Redox flow batteries based on supporting solutions containing chloride

Patent · Tue Sep 01 00:00:00 EDT 2015 · OSTI ID:1408903

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; +5 more

Redox flow batteries based on supporting solutions containing chloride

Patent · Tue Jan 14 00:00:00 EST 2014 · OSTI ID:1408903

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; +5 more

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
25 ENERGY STORAGE

Title: Redox flow batteries based on supporting solutions containing chloride

Citation Formats

References (36)

Similar Records

Related Subjects