Electrocatalytic Metal–Organic Frameworks for Energy Applications

Downes, Courtney A.; Marinescu, Smaranda C.

doi:10.1002/cssc.201701420

Title: Electrocatalytic Metal–Organic Frameworks for Energy Applications

Journal Article · Mon Nov 13 00:00:00 EST 2017 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201701420· OSTI ID:1408540

Downes, Courtney A. ^[1];

^[1]

Department of Chemistry University of Southern California 840 Downey Way Los Angeles CA 90089 USA

Abstract With the global energy demand expected to increase drastically over the next several decades, the development of a sustainable energy system to meet this increase is paramount. Renewable energy sources can be coupled with electrochemical conversion processes to store energy in chemical bonds. To promote these difficult transformations, electrocatalysts that operate at high conversion rates and efficiency are required. Metal–organic frameworks (MOFs) have emerged as a promising class of materials; however, the insulating nature of MOFs has limited their application as electrocatalysts. The recent development of conductive MOFs has led to several electrocatalytic MOFs that display activity comparable to that of the best‐performing heterogeneous catalysts. Although many electrocatalytic MOFs exhibit low activity and stability, the few successful examples highlight the possibility of MOF electrocatalysts as replacements for noble‐metal‐based catalysts in commercial energy‐converting devices. We review herein the use of pristine MOFs as electrocatalysts to facilitate important energy‐related reactions.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-17ER16362

OSTI ID:: 1408540

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Vol. 10 Journal Issue: 22; ISSN 1864-5631

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

Citation Metrics:

Cited by: 155 works

Citation information provided by
Web of Science

References (140)

One dimensional metal dithiolene (M = Ni, Fe, Zn) coordination polymers for the hydrogen evolution reaction Downes, Courtney A.; Marinescu, Smaranda C. Dalton Transactions, Vol. 45, Issue 48 https://doi.org/10.1039/C6DT03257E	journal	January 2016
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting Roger, Isolda; Shipman, Michael A.; Symes, Mark D. Nature Reviews Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/s41570-016-0003	journal	January 2017
Fe-Porphyrin-Based Metal–Organic Framework Films as High-Surface Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO ₂ Hod, Idan; Sampson, Matthew D.; Deria, Pravas ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01767	journal	September 2015
Homogeneous water oxidation catalysts containing a single metal site Wasylenko, Derek J.; Palmer, Ryan D.; Berlinguette, Curtis P. Chem. Commun., Vol. 49, Issue 3 https://doi.org/10.1039/C2CC35632E	journal	January 2013
Experimental and Theoretical Insight into Electrocatalytic Hydrogen Evolution with Nickel Bis(aryldithiolene) Complexes as Catalysts Zarkadoulas, Athanasios; Field, Martin J.; Papatriantafyllopoulou, Constantina Inorganic Chemistry, Vol. 55, Issue 2 https://doi.org/10.1021/acs.inorgchem.5b02000	journal	November 2015
Ultrathin metal-organic framework array for efficient electrocatalytic water splitting Duan, Jingjing; Chen, Sheng; Zhao, Chuan Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15341	journal	June 2017
Electrocatalysis of CO2 reduction at surface modified metallic and semiconducting electrodes Cabrera, Carlos R.; Abruña, Héctor D. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 209, Issue 1 https://doi.org/10.1016/0022-0728(86)80189-9	journal	September 1986
Postsynthetic modification of metal–organic frameworks—a progress report Tanabe, Kristine K.; Cohen, Seth M. Chem. Soc. Rev., Vol. 40, Issue 2 https://doi.org/10.1039/C0CS00031K	journal	January 2011
Künstliche Photosynthese für die Produktion von nachhaltigen Kraftstoffen und chemischen Produkten Kim, Dohyung; Sakimoto, Kelsey K.; Hong, Dachao Angewandte Chemie, Vol. 127, Issue 11 https://doi.org/10.1002/ange.201409116	journal	January 2015
Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications Faber, Matthew S.; Jin, Song Energy Environ. Sci., Vol. 7, Issue 11 https://doi.org/10.1039/C4EE01760A	journal	January 2014
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide Zhu, Dong Dong; Liu, Jin Long; Qiao, Shi Zhang Advanced Materials, Vol. 28, Issue 18 https://doi.org/10.1002/adma.201504766	journal	March 2016
Highly selective electrochemical reduction of carbon dioxide using Cu based metal organic framework as an electrocatalyst Senthil Kumar, R.; Senthil Kumar, S.; Anbu Kulandainathan, M. Electrochemistry Communications, Vol. 25 https://doi.org/10.1016/j.elecom.2012.09.018	journal	November 2012
High Electrical Conductivity in Ni ₃ (2,3,6,7,10,11-hexaiminotriphenylene) ₂ , a Semiconducting Metal–Organic Graphene Analogue Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A. Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja502765n	journal	April 2014
Re(bipy-tBu)(CO) ₃ Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies Smieja, Jonathan M.; Kubiak, Clifford P. Inorganic Chemistry, Vol. 49, Issue 20 https://doi.org/10.1021/ic1008363	journal	October 2010
A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells Sui, Sheng; Wang, Xiaoying; Zhou, Xintong Journal of Materials Chemistry A, Vol. 5, Issue 5 https://doi.org/10.1039/C6TA08580F	journal	January 2017
From Hydrogenases to Noble Metal-Free Catalytic Nanomaterials for H2 Production and Uptake Le Goff, A.; Artero, V.; Jousselme, B. Science, Vol. 326, Issue 5958 https://doi.org/10.1126/science.1179773	journal	December 2009
A Smorgasbord of Carbon: Electrochemical Analysis of Cobalt–Bis(benzenedithiolate) Complex Adsorption and Electrocatalytic Activity on Diverse Graphitic Supports Eady, Shawn C.; MacInnes, Molly M.; Lehnert, Nicolai ACS Applied Materials & Interfaces, Vol. 8, Issue 36 https://doi.org/10.1021/acsami.6b05159	journal	August 2016
Study of Electrocatalytic Properties of Metal–Organic Framework PCN-223 for the Oxygen Reduction Reaction Usov, Pavel M.; Huffman, Brittany; Epley, Charity C. ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b01547	journal	April 2017
Electrocatalytic four-electron reduction of oxygen with Copper (II)-based metal-organic frameworks Mao, Junjie; Yang, Lifen; Yu, Ping Electrochemistry Communications, Vol. 19 https://doi.org/10.1016/j.elecom.2012.02.025	journal	June 2012
Hydrogen Evolution Catalyzed by Cobaloximes Dempsey, Jillian L.; Brunschwig, Bruce S.; Winkler, Jay R. Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar900253e	journal	December 2009
Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF ₃ -Terminated Self-Assembled Monolayers on Au(111) Hermes, Stephan; Schröder, Felicitas; Chelmowski, Rolf Journal of the American Chemical Society, Vol. 127, Issue 40 https://doi.org/10.1021/ja053523l	journal	October 2005
Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO) ₃ Cl (bipy = 2,2′-bipyridine) Hawecker, Jeannot; Lehn, Jean-Marie; Ziessel, Raymond J. Chem. Soc., Chem. Commun., Issue 6 https://doi.org/10.1039/C39840000328	journal	January 1984
Electrocatalytic water oxidation by a molecular catalyst incorporated into a metal–organic framework thin film Johnson, Ben A.; Bhunia, Asamanjoy; Ott, Sascha Dalton Transactions, Vol. 46, Issue 5 https://doi.org/10.1039/C6DT03718F	journal	January 2017
An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors Stassen, Ivo; Burtch, Nicholas; Talin, Alec Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00122C	journal	January 2017
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO ₂ reduction in water Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao Science, Vol. 349, Issue 6253 https://doi.org/10.1126/science.aac8343	journal	August 2015
Metal-Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials Meek, Scott T.; Greathouse, Jeffery A.; Allendorf, Mark D. Advanced Materials, Vol. 23, Issue 2 https://doi.org/10.1002/adma.201002854	journal	October 2010
Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions Thoi, V. Sara; Sun, Yujie; Long, Jeffrey R. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35272A	journal	January 2013
Metal-Organic Frameworks for Energy Applications Wang, Hailong; Zhu, Qi-Long; Zou, Ruqiang Chem, Vol. 2, Issue 1 https://doi.org/10.1016/j.chempr.2016.12.002	journal	January 2017
Electrochemical Reduction of Carbon Dioxide Using a Copper Rubeanate Metal Organic Framework Hinogami, R.; Yotsuhashi, S.; Deguchi, M. ECS Electrochemistry Letters, Vol. 1, Issue 4 https://doi.org/10.1149/2.001204eel	journal	January 2012
Efficient Electrochemical and Photoelectrochemical H ₂ Production from Water by a Cobalt Dithiolene One-Dimensional Metal–Organic Surface Downes, Courtney A.; Marinescu, Smaranda C. Journal of the American Chemical Society, Vol. 137, Issue 43 https://doi.org/10.1021/jacs.5b07020	journal	October 2015
Molecular cathode and photocathode materials for hydrogen evolution in photoelectrochemical devices Queyriaux, Nicolas; Kaeffer, Nicolas; Morozan, Adina Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Vol. 25 https://doi.org/10.1016/j.jphotochemrev.2015.08.001	journal	December 2015
Unraveling the Optoelectronic and Photochemical Behavior of Zn ₄ O-Based Metal Organic Frameworks Khajavi, Hossein; Gascon, Jorge; Schins, Juleon M. The Journal of Physical Chemistry C, Vol. 115, Issue 25 https://doi.org/10.1021/jp201760s	journal	June 2011
Mechanism of the Electrocatalytic Reduction of Protons with Diaryldithiolene Cobalt Complexes Letko, Christopher S.; Panetier, Julien A.; Head-Gordon, Martin Journal of the American Chemical Society, Vol. 136, Issue 26 https://doi.org/10.1021/ja5019755	journal	June 2014
Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework Clough, Andrew J.; Skelton, Jonathan M.; Downes, Courtney A. Journal of the American Chemical Society, Vol. 139, Issue 31 https://doi.org/10.1021/jacs.7b05742	journal	July 2017
Sustainable Hydrogen Production Turner, J. A. Science, Vol. 305, Issue 5686 https://doi.org/10.1126/science.1103197	journal	August 2004
Recent advances of doped carbon as non-precious catalysts for oxygen reduction reaction Shi, Hao; Shen, Yanfei; He, Fei J. Mater. Chem. A, Vol. 2, Issue 38 https://doi.org/10.1039/C4TA02790F	journal	January 2014
Highly oriented MOF thin film-based electrocatalytic device for the reduction of CO ₂ to CO exhibiting high faradaic efficiency Ye, Lu; Liu, Jinxuan; Gao, Yan Journal of Materials Chemistry A, Vol. 4, Issue 40 https://doi.org/10.1039/C6TA04801C	journal	January 2016
Heterogenised Molecular Catalysts for the Reduction of CO ₂ to Fuels Windle, Christopher D.; Reisner, Erwin CHIMIA International Journal for Chemistry, Vol. 69, Issue 7 https://doi.org/10.2533/chimia.2015.435	journal	August 2015
Crystal engineering, structure–function relationships, and the future of metal–organic frameworks Allendorf, Mark D.; Stavila, Vitalie CrystEngComm, Vol. 17, Issue 2 https://doi.org/10.1039/C4CE01693A	journal	January 2015
Photogeneration of hydrogen from water using CdSe nanocrystals demonstrating the importance of surface exchange Das, A.; Han, Z.; Haghighi, M. G. Proceedings of the National Academy of Sciences, Vol. 110, Issue 42 https://doi.org/10.1073/pnas.1316755110	journal	September 2013
Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution Zhao, Shenlong; Wang, Yun; Dong, Juncai Nature Energy, Vol. 1, Issue 12 https://doi.org/10.1038/nenergy.2016.184	journal	November 2016
Oxygen reduction in the nanocage of metal–organic frameworks with an electron transfer mediator Jiang, Min; Li, Liangjun; Zhu, Dandan J. Mater. Chem. A, Vol. 2, Issue 15 https://doi.org/10.1039/C3TA15319C	journal	January 2014
Polyoxometalate-Based Metal Organic Frameworks (POMOFs): Structural Trends, Energetics, and High Electrocatalytic Efficiency for Hydrogen Evolution Reaction Nohra, Brigitte; El Moll, Hani; Rodriguez Albelo, L. Marleny Journal of the American Chemical Society, Vol. 133, Issue 34 https://doi.org/10.1021/ja201165c	journal	August 2011
Perspectives on metal–organic frameworks with intrinsic electrocatalytic activity Solomon, Marcello B.; Church, Tamara L.; D'Alessandro, Deanna M. CrystEngComm, Vol. 19, Issue 29 https://doi.org/10.1039/C7CE00215G	journal	January 2017
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Postsynthetic modification of metal–organic frameworks Wang, Zhenqiang; Cohen, Seth M. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802258p	journal	January 2009
Noncovalent Modification of Carbon Nanotubes with Pyrene-Functionalized Nickel Complexes: Carbon Monoxide Tolerant Catalysts for Hydrogen Evolution and Uptake Tran, Phong D.; Le Goff, Alan; Heidkamp, Jonathan Angewandte Chemie International Edition, Vol. 50, Issue 6 https://doi.org/10.1002/anie.201005427	journal	January 2011
Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions McNamara, W. R.; Han, Z.; Yin, C. -J. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1120757109	journal	June 2012
The recent progress and future of oxygen reduction reaction catalysis: A review Stacy, John; Regmi, Yagya N.; Leonard, Brian Renewable and Sustainable Energy Reviews, Vol. 69 https://doi.org/10.1016/j.rser.2016.09.135	journal	March 2017
Electrodeposition from Acidic Solutions of Nickel Bis(benzenedithiolate) Produces a Hydrogen-Evolving Ni–S Film on Glassy Carbon Fang, Ming; Engelhard, Mark H.; Zhu, Zihua ACS Catalysis, Vol. 4, Issue 1 https://doi.org/10.1021/cs400675u	journal	December 2013
Fe/Ni Metal–Organic Frameworks and Their Binder-Free Thin Films for Efficient Oxygen Evolution with Low Overpotential Wang, Lu; Wu, Yizhen; Cao, Rui ACS Applied Materials & Interfaces, Vol. 8, Issue 26 https://doi.org/10.1021/acsami.6b05375	journal	June 2016
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix Energy & Environmental Science, Vol. 3, Issue 9 https://doi.org/10.1039/c0ee00071j	journal	January 2010
Proton-Reduction Reaction Catalyzed by Homoleptic Nickel-bis-1,2-dithiolate Complexes: Experimental and Theoretical Mechanistic Investigations Zarkadoulas, Athanasios; Field, Martin J.; Artero, Vincent ChemCatChem, Vol. 9, Issue 12 https://doi.org/10.1002/cctc.201601399	journal	April 2017
Electrocatalytic Oxygen Evolution Reaction in Acidic Environments - Reaction Mechanisms and Catalysts Reier, Tobias; Nong, Hong Nhan; Teschner, Detre Advanced Energy Materials, Vol. 7, Issue 1 https://doi.org/10.1002/aenm.201601275	journal	October 2016
The Interaction of Water with MOF-5 Simulated by Molecular Dynamics Greathouse, Jeffery A.; Allendorf, Mark D. Journal of the American Chemical Society, Vol. 128, Issue 33 https://doi.org/10.1021/ja063506b	journal	August 2006
Recent advances in porous polyoxometalate-based metal–organic framework materials Du, Dong-Ying; Qin, Jun-Sheng; Li, Shun-Li Chem. Soc. Rev., Vol. 43, Issue 13 https://doi.org/10.1039/C3CS60404G	journal	January 2014
Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2 Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10942	journal	March 2016
Factors Determining the Rate and Selectivity of 4e ^– /4H ⁺ Electrocatalytic Reduction of Dioxygen by Iron Porphyrin Complexes Chatterjee, Sudipta; Sengupta, Kushal; Mondal, Biswajit Accounts of Chemical Research, Vol. 50, Issue 7 https://doi.org/10.1021/acs.accounts.7b00192	journal	July 2017
Signature of Metallic Behavior in the Metal–Organic Frameworks M ₃ (hexaiminobenzene) ₂ (M = Ni, Cu) Dou, Jin-Hu; Sun, Lei; Ge, Yicong Journal of the American Chemical Society, Vol. 139, Issue 39 https://doi.org/10.1021/jacs.7b07234	journal	September 2017
Photo-Induced Generation of Dihydrogen and Reduction of Carbon Dioxide Using Transition Metal Complexes Sutin, Norman; Creutz, Carol; Fujita, Etsuko Comments on Inorganic Chemistry, Vol. 19, Issue 2 https://doi.org/10.1080/02603599708032729	journal	January 1997
Understanding trends in electrochemical carbon dioxide reduction rates Liu, Xinyan; Xiao, Jianping; Peng, Hongjie Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15438	journal	May 2017
Copper-Based Metal-Organic Porous Materials for CO ₂ Electrocatalytic Reduction to Alcohols Albo, Jonathan; Vallejo, Daniel; Beobide, Garikoitz ChemSusChem, Vol. 10, Issue 6 https://doi.org/10.1002/cssc.201600693	journal	August 2016
Molecular Catalysts for Water Oxidation Blakemore, James D.; Crabtree, Robert H.; Brudvig, Gary W. Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00122	journal	July 2015
Metal–organic framework composites Zhu, Qi-Long; Xu, Qiang Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C3CS60472A	journal	January 2014
Noncovalent Modification of Carbon Nanotubes with Pyrene-Functionalized Nickel Complexes: Carbon Monoxide Tolerant Catalysts for Hydrogen Evolution and Uptake Tran, Phong D.; Le Goff, Alan; Heidkamp, Jonathan Angewandte Chemie, Vol. 123, Issue 6 https://doi.org/10.1002/ange.201005427	journal	January 2011
Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator Kambe, Tetsuya; Sakamoto, Ryota; Kusamoto, Tetsuro Journal of the American Chemical Society, Vol. 136, Issue 41 https://doi.org/10.1021/ja507619d	journal	October 2014
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide Kornienko, Nikolay; Zhao, Yingbo; Kley, Christopher S. Journal of the American Chemical Society, Vol. 137, Issue 44 https://doi.org/10.1021/jacs.5b08212	journal	October 2015
Design Principles for Covalent Organic Frameworks as Efficient Electrocatalysts in Clean Energy Conversion and Green Oxidizer Production Lin, Chun-Yu; Zhang, Lipeng; Zhao, Zhenghang Advanced Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adma.201606635	journal	February 2017
Energy-Related Small Molecule Activation Reactions: Oxygen Reduction and Hydrogen and Oxygen Evolution Reactions Catalyzed by Porphyrin- and Corrole-Based Systems Zhang, Wei; Lai, Wenzhen; Cao, Rui Chemical Reviews, Vol. 117, Issue 4 https://doi.org/10.1021/acs.chemrev.6b00299	journal	November 2016
Electrocatalytic reduction of CO2 at a chemically modified electrode O'Toole, Terrence R.; Margerum, Lawrence D.; Westmoreland, T. David Journal of the Chemical Society, Chemical Communications, Issue 20 https://doi.org/10.1039/c39850001416	journal	January 1985
Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide by a Polymerized Film of an Alkynyl-Substituted Rhenium(I) Complex Portenkirchner, Engelbert; Gasiorowski, Jacek; Oppelt, Kerstin ChemCatChem, Vol. 5, Issue 7 https://doi.org/10.1002/cctc.201200904	journal	April 2013
A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution Hod, Idan; Deria, Pravas; Bury, Wojciech Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9304	journal	September 2015
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Molecular engineering of a cobalt-based electrocatalytic nanomaterial for H2 evolution under fully aqueous conditions Andreiadis, Eugen S.; Jacques, Pierre-André; Tran, Phong D. Nature Chemistry, Vol. 5, Issue 1 https://doi.org/10.1038/nchem.1481	journal	October 2012
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation Gorlin, Yelena; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614 https://doi.org/10.1021/ja104587v	journal	October 2010
A lead–porphyrin metal–organic framework: gas adsorption properties and electrocatalytic activity for water oxidation Dai, Fangna; Fan, Weidong; Bi, Jiahui Dalton Transactions, Vol. 45, Issue 1 https://doi.org/10.1039/C5DT04025F	journal	January 2016
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives Suen, Nian-Tzu; Hung, Sung-Fu; Quan, Quan Chemical Society Reviews, Vol. 46, Issue 2 https://doi.org/10.1039/C6CS00328A	journal	January 2017
Post-synthetic metalation of metal–organic frameworks Evans, Jack D.; Sumby, Christopher J.; Doonan, Christian J. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00076E	journal	January 2014
Metal–Organic Framework Thin Films as Platforms for Atomic Layer Deposition of Cobalt Ions To Enable Electrocatalytic Water Oxidation Kung, Chung-Wei; Mondloch, Joseph E.; Wang, Timothy C. ACS Applied Materials & Interfaces, Vol. 7, Issue 51 https://doi.org/10.1021/acsami.5b06901	journal	December 2015
Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion Shinagawa, Tatsuya; Garcia-Esparza, Angel T.; Takanabe, Kazuhiro Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep13801	journal	September 2015
Facile heterogenization of a cobalt catalyst via graphene adsorption: robust and versatile dihydrogen production systems Eady, Shawn C.; Peczonczyk, Sabrina L.; Maldonado, Stephen Chem. Commun., Vol. 50, Issue 59 https://doi.org/10.1039/C4CC02920H	journal	January 2014
Electrocatalytic Reduction of Carbon Dioxide with Mono(bipyridine)carbonylruthenium Complexes in Solution or as Polymeric Thin Films Collomb-Dunand-Sauthier, Marie-Noelle; Deronzier, Alain; Ziessel, Raymond Inorganic Chemistry, Vol. 33, Issue 13 https://doi.org/10.1021/ic00091a040	journal	June 1994
Molecular Catalysis of O ₂ Reduction by Iron Porphyrins in Water: Heterogeneous versus Homogeneous Pathways Costentin, Cyrille; Dridi, Hachem; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 137, Issue 42 https://doi.org/10.1021/jacs.5b06834	journal	October 2015
Bioinspired Metal Selenolate Polymers with Tunable Mechanistic Pathways for Efficient H ₂ Evolution Downes, Courtney A.; Marinescu, Smaranda C. ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b03161	journal	December 2016
Graphite-Conjugated Rhenium Catalysts for Carbon Dioxide Reduction Oh, Seokjoon; Gallagher, James R.; Miller, Jeffrey T. Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b13080	journal	February 2016
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
A Cobalt–Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons McNamara, William R.; Han, Zhiji; Alperin, Paul J. Journal of the American Chemical Society, Vol. 133, Issue 39 https://doi.org/10.1021/ja207842r	journal	October 2011
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
Stability and Hydrolyzation of Metal Organic Frameworks with Paddle-Wheel SBUs upon Hydration Tan, Kui; Nijem, Nour; Canepa, Pieremanuele Chemistry of Materials, Vol. 24, Issue 16 https://doi.org/10.1021/cm301427w	journal	August 2012
Photoelectrochemical Generation of Hydrogen from Water Using a CdSe Quantum Dot-Sensitized Photocathode Ruberu, T. Purnima A.; Dong, Yuming; Das, Amit ACS Catalysis, Vol. 5, Issue 4 https://doi.org/10.1021/cs5021035	journal	March 2015
Earth-abundant hydrogen evolution electrocatalysts McKone, James R.; Marinescu, Smaranda C.; Brunschwig, Bruce S. Chem. Sci., Vol. 5, Issue 3 https://doi.org/10.1039/C3SC51711J	journal	January 2014
Zeolitic imidazolate framework materials: recent progress in synthesis and applications Chen, Binling; Yang, Zhuxian; Zhu, Yanqiu Journal of Materials Chemistry A, Vol. 2, Issue 40, p. 16811-16831 https://doi.org/10.1039/C4TA02984D	journal	January 2014
Homonuclear Mixed-Valent Cobalt Imidazolate Framework for Oxygen-Evolution Electrocatalysis Flügel, Erik A.; Lau, Vincent W-h.; Schlomberg, Hendrik Chemistry - A European Journal, Vol. 22, Issue 11 https://doi.org/10.1002/chem.201504151	journal	January 2016
A molecular catalyst for water oxidation that binds to metal oxide surfaces Sheehan, Stafford W.; Thomsen, Julianne M.; Hintermair, Ulrich Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7469	journal	March 2015
π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312380b	journal	February 2013
Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei Angewandte Chemie, Vol. 127, Issue 41 https://doi.org/10.1002/ange.201506048	journal	August 2015
Light-Driven Hydrogen Production from Aqueous Protons using Molybdenum Catalysts Eckenhoff, William T.; Brennessel, William W.; Eisenberg, Richard Inorganic Chemistry, Vol. 53, Issue 18 https://doi.org/10.1021/ic501440a	journal	August 2014
Catalytic Light-Driven Generation of Hydrogen from Water by Iron Dithiolene Complexes Lv, Hongjin; Ruberu, T. Purnima A.; Fleischauer, Valerie E. Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b05040	journal	September 2016
Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions Matsuoka, Ryota; Sakamoto, Ryota; Kambe, Tetsuya Chem. Commun., Vol. 50, Issue 60 https://doi.org/10.1039/C4CC02022G	journal	January 2014
Electrocatalytic reduction of CO2 by a complex of rhenium in thin polymeric films O'Toole, Terrence R.; Sullivan, B. Patrick; Bruce, Mitchell R. -M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 259, Issue 1-2 https://doi.org/10.1016/0022-0728(89)80049-X	journal	February 1989
Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film Usov, P. M.; Ahrenholtz, S. R.; Maza, W. A. Journal of Materials Chemistry A, Vol. 4, Issue 43 https://doi.org/10.1039/C6TA05877A	journal	January 2016
Immobilizing Molecular Metal Dithiolene-Diamine Complexes on 2D Metal-Organic Frameworks for Electrocatalytic H ₂ Production Dong, Renhao; Zheng, Zhikun; Tranca, Diana C. Chemistry - A European Journal, Vol. 23, Issue 10 https://doi.org/10.1002/chem.201605337	journal	December 2016
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol Chemical Reviews, Vol. 116, Issue 6 https://doi.org/10.1021/acs.chemrev.5b00462	journal	February 2016
A review of the aqueous electrochemical reduction of CO₂ to hydrocarbons at copper Gattrell, M.; Gupta, N.; Co, A. Journal of Electroanalytical Chemistry, Vol. 594, Issue 1, p. 1-19 https://doi.org/10.1016/j.jelechem.2006.05.013	journal	August 2006
Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges Du, Pingwu; Eisenberg, Richard Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee03250c	journal	January 2012
Towards the electrochemical conversion of carbon dioxide into methanol Albo, J.; Alvarez-Guerra, M.; Castaño, P. Green Chemistry, Vol. 17, Issue 4 https://doi.org/10.1039/C4GC02453B	journal	January 2015
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects Savéant, Jean-Michel Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378 https://doi.org/10.1021/cr068079z	journal	July 2008
Recent Progress on MOF-Derived Nanomaterials as Advanced Electrocatalysts in Fuel Cells Song, Zhongxin; Cheng, Niancai; Lushington, Andrew Catalysts, Vol. 6, Issue 8 https://doi.org/10.3390/catal6080116	journal	August 2016
Thin films of metal–organic frameworks Zacher, Denise; Shekhah, Osama; Wöll, Christof Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b805038b	journal	January 2009
Noncovalent Immobilization of a Molecular Iron-Based Electrocatalyst on Carbon Electrodes for Selective, Efficient CO ₂ -to-CO Conversion in Water Maurin, Antoine; Robert, Marc Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b12652	journal	February 2016
Modular and Stepwise Synthesis of a Hybrid Metal–Organic Framework for Efficient Electrocatalytic Oxygen Evolution Shen, Jian-Qiang; Liao, Pei-Qin; Zhou, Dong-Dong Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b12353	journal	January 2017
Molecular polypyridine-based metal complexes as catalysts for the reduction of CO ₂ Elgrishi, Noémie; Chambers, Matthew B.; Wang, Xia Chemical Society Reviews, Vol. 46, Issue 3 https://doi.org/10.1039/C5CS00391A	journal	January 2017
Metal poly(benzodithiolenes) Dirk, C. W.; Bousseau, M.; Barrett, P. H. Macromolecules, Vol. 19, Issue 2 https://doi.org/10.1021/ma00156a003	journal	March 1986
Efficient and selective molecular catalyst for the CO ₂ -to-CO electrochemical conversion in water Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Proceedings of the National Academy of Sciences, Vol. 112, Issue 22 https://doi.org/10.1073/pnas.1507063112	journal	May 2015
Surface Immobilization of Molecular Electrocatalysts for Energy Conversion Bullock, R. Morris; Das, Atanu K.; Appel, Aaron M. Chemistry - A European Journal, Vol. 23, Issue 32 https://doi.org/10.1002/chem.201605066	journal	March 2017
Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei Angewandte Chemie International Edition, Vol. 54, Issue 41 https://doi.org/10.1002/anie.201506048	journal	August 2015
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Making Oxygen with Ruthenium Complexes Concepcion, Javier J.; Jurss, Jonah W.; Brennaman, M. Kyle Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9001526	journal	December 2009
An Alkaline-Stable, Metal Hydroxide Mimicking Metal–Organic Framework for Efficient Electrocatalytic Oxygen Evolution Lu, Xue-Feng; Liao, Pei-Qin; Wang, Jia-Wei Journal of the American Chemical Society, Vol. 138, Issue 27 https://doi.org/10.1021/jacs.6b03125	journal	June 2016
Elektrisch leitfähige poröse Metall-organische Gerüstverbindungen Sun, Lei; Campbell, Michael G.; Dincă, Mircea Angewandte Chemie, Vol. 128, Issue 11 https://doi.org/10.1002/ange.201506219	journal	January 2016
Metal-Organic Framework-Based Nanomaterials for Electrocatalysis Mahmood, Asif; Guo, Wenhan; Tabassum, Hassina Advanced Energy Materials, Vol. 6, Issue 17 https://doi.org/10.1002/aenm.201600423	journal	May 2016
Electrochemical Water Oxidation by a Catalyst-Modified Metal-Organic Framework Thin Film Lin, Shaoyang; Pineda-Galvan, Yuliana; Maza, William A. ChemSusChem, Vol. 10, Issue 3 https://doi.org/10.1002/cssc.201601181	journal	December 2016
Highly efficient electrochemical reduction of CO ₂ to CH ₄ in an ionic liquid using a metal–organic framework cathode Kang, Xinchen; Zhu, Qinggong; Sun, Xiaofu Chemical Science, Vol. 7, Issue 1 https://doi.org/10.1039/C5SC03291A	journal	January 2016
Surface-supported metal–organic framework thin films: fabrication methods, applications, and challenges Liu, Jinxuan; Wöll, Christof Chemical Society Reviews, Vol. 46, Issue 19 https://doi.org/10.1039/C7CS00315C	journal	January 2017
Translation of Ligand-Centered Hydrogen Evolution Reaction Activity and Mechanism of a Rhenium-Thiolate from Solution to Modified Electrodes: A Combined Experimental and Density Functional Theory Study Zhang, Wuyu; Haddad, Andrew Z.; Garabato, Brady D. Inorganic Chemistry, Vol. 56, Issue 4 https://doi.org/10.1021/acs.inorgchem.6b02829	journal	February 2017
Artificial Photosynthesis for Sustainable Fuel and Chemical Production Kim, Dohyung; Sakimoto, Kelsey K.; Hong, Dachao Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201409116	journal	January 2015
Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water Clough, Andrew J.; Yoo, Joseph W.; Mecklenburg, Matthew H. Journal of the American Chemical Society, Vol. 137, Issue 1 https://doi.org/10.1021/ja5116937	journal	December 2014
Efficiency of Splitting Water with Semiconducting Photoelectrodes Weber, Michael F. Journal of The Electrochemical Society, Vol. 131, Issue 6 https://doi.org/10.1149/1.2115797	journal	January 1984
Electrocatalytic and homogeneous approaches to conversion of CO ₂ to liquid fuels Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B804323J	journal	January 2009
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Combining theory and experiment in electrocatalysis: Insights into materials design Seh, Zhi Wei; Kibsgaard, Jakob; Dickens, Colin F. Science, Vol. 355, Issue 6321 https://doi.org/10.1126/science.aad4998	journal	January 2017
A Case for Electrofuels Tatin, Arnaud; Bonin, Julien; Robert, Marc ACS Energy Letters, Vol. 1, Issue 5 https://doi.org/10.1021/acsenergylett.6b00510	journal	October 2016
Water oxidation electrocatalysis by a zeolitic imidazolate framework Wang, Sibo; Hou, Yidong; Lin, Sen Nanoscale, Vol. 6, Issue 17 https://doi.org/10.1039/C4NR02399D	journal	January 2014
Ultrastable Polymolybdate-Based Metal–Organic Frameworks as Highly Active Electrocatalysts for Hydrogen Generation from Water Qin, Jun-Sheng; Du, Dong-Ying; Guan, Wei Journal of the American Chemical Society, Vol. 137, Issue 22 https://doi.org/10.1021/jacs.5b02688	journal	May 2015
Electrically Conductive Porous Metal-Organic Frameworks Sun, Lei; Campbell, Michael G.; Dincă, Mircea Angewandte Chemie International Edition, Vol. 55, Issue 11 https://doi.org/10.1002/anie.201506219	journal	January 2016
Metal organic frameworks for electrochemical applications Morozan, Adina; Jaouen, Frédéric Energy & Environmental Science, Vol. 5, Issue 11 https://doi.org/10.1039/c2ee22989g	journal	January 2012
Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO ₂ Reduction Takeda, Hiroyuki; Cometto, Claudio; Ishitani, Osamu ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02181	journal	November 2016

Similar Records

Electrocatalytic water oxidation performance in an extended porous organic framework with a covalent alliance of distinct Ru sites

Journal Article · Thu May 05 00:00:00 EDT 2022 · Nanoscale · OSTI ID:1408540

Boro, Bishal; Adak, Mrinal K.; Biswas, Sohag; +6 more

Redox-Mediator-Assisted Electrocatalytic Hydrogen Evolution from Water by a Molybdenum Sulfide-Functionalized Metal–Organic Framework

Journal Article · Wed Sep 12 00:00:00 EDT 2018 · ACS Catalysis · OSTI ID:1408540

Noh, Hyunho; Kung, Chung-Wei; Otake, Ken-ichi; +6 more

Boosting Hydrogen Evolution in Neutral Medium by Accelerating Water Dissociation with Ru Clusters Loaded on Mo ₂ CTx MXene

Journal Article · Wed Jan 25 00:00:00 EST 2023 · Advanced Functional Materials · OSTI ID:1408540

Wu, Yanze; Wang, Lin; Bo, Tao; +3 more

Title: Electrocatalytic Metal–Organic Frameworks for Energy Applications

Citation Formats

References (140)

Similar Records

Related Subjects