Extended Ladder-Type Benzo[k]tetraphene-Derived Oligomers

Lee, Jongbok; Li, Huanbin; Kalin, Alexander J.; Yuan, Tianyu; Wang, Chenxu; Olson, Troy; Li, Hanying; Fang, Lei

doi:10.1002/anie.201707595

Title: Extended Ladder-Type Benzo[k]tetraphene-Derived Oligomers

Journal Article · Fri Sep 08 00:00:00 EDT 2017 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201707595· OSTI ID:1408109

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Texas A & M Univ., College Station, TX (United States)
Zhejiang Univ., Hangzhou (China)

Abstract Well‐defined, fused‐ring aromatic oligomers represent promising candidates for the fundamental understanding and application of advanced carbon‐rich materials, though bottom‐up synthesis and structure–property correlation of these compounds remain challenging. In this work, an efficient synthetic route was employed to construct extended benzo[ k ]tetraphene‐derived oligomers with up to 13 fused rings. The molecular and electronic structures of these compounds were clearly elucidated. Precise correlation of molecular sizes and crystallization dynamics was established, thus demonstrating the pivotal balance between intermolecular interaction and molecular mobility for optimized processing of highly ordered solids of these extended conjugated molecules.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357; CHE-1359175; CHE-0541587

OSTI ID:: 1408109

Alternate ID(s):: OSTI ID: 1395909

Journal Information:: Angewandte Chemie (International Edition), Vol. 56, Issue 44; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 37 works

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