Simple guanidinium motif for the selective binding and extraction of sulfate

Seipp, Charles A.; Williams, Neil J.; Bryantsev, Vyacheslav S.; Moyer, Bruce A.

doi:10.1080/01496395.2017.1318922

Title: Simple guanidinium motif for the selective binding and extraction of sulfate

Journal Article · Fri Jun 30 00:00:00 EDT 2017 · Separation Science and Technology

DOI:https://doi.org/10.1080/01496395.2017.1318922· OSTI ID:1408027

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Texas at Austin, Austin, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

A simple bidentate anion receptor, shown previously to adopt a rigid pseudobicyclic conformation while binding anions in the solid state, selectively binds sulfate in aqueous solutions with log K₁ and log K₂ values of 3.78 ± 0.12 M-1 and 2.10 ± 0.23 M-1, respectively. This anion receptor has little to no affinity for nitrate and chloride in the same solutions. A lipophilic derivative was synthesized in four steps to yield an extractant that is capable of partitioning sulfate into 1,2 dichloroethane from water in the presence of large excesses of chloride. This extractant demonstrated D values as high as 2.5 with only 30 mM of anion receptor.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1408027

Journal Information:: Separation Science and Technology, Vol. 53, Issue 12; ISSN 0149-6395

Publisher:: Taylor & FrancisCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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Ion-pair induced supramolecular assembly formation for selective extraction and sensing of potassium sulfate Jagleniec, Damian; Dobrzycki, Łukasz; Karbarz, Marcin Chemical Science, Vol. 10, Issue 41 https://doi.org/10.1039/c9sc02923k	journal	January 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
guanidinium
anion binding
sulfate
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A Simple Guanidinium Motif for the Selective Binding and Extraction of Sulfate Seipp, Charles A.; Williams, Neil J.; Bryantsev, Vyacheslav S. https://doi.org/10.6084/m9.figshare.5162083.v1 The current record is supplemented by this dataset	dataset	June 2017
A Simple Guanidinium Motif for the Selective Binding and Extraction of Sulfate Seipp, Charles A.; Williams, Neil J.; Bryantsev, Vyacheslav S. https://doi.org/10.6084/m9.figshare.5162083.v1 The current record is a newer version of this dataset	dataset	June 2017