Metal–Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes

Vilanova, Sean P.; Alayoglu, Pinar; Heidarian, Mohammad; Huang, Patrick; Walensky, Justin R.

doi:10.1002/chem.201704782

Title: Metal–Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes

Journal Article · Tue Nov 07 00:00:00 EST 2017 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201704782· OSTI ID:1407832

Vilanova, Sean P. ^[1]; Alayoglu, Pinar ^[2]; Heidarian, Mohammad ^[2]; Huang, Patrick ^[2];

^[1]

Department of Chemistry University of Missouri Columbia MO 65211 USA
Department of Chemistry California State University East Bay Hayward CA 94542 USA

Abstract The complexes (C ₅ Me ₅ ) ₂ Th(EHTipp) ₂ , (E=P or As; Tipp=2,4,6‐triisopropylphenyl), provide a ligand framework that results in facile access to rare Th–E multiple bonds. The reaction of (C ₅ Me ₅ ) ₂ Th(EHTipp) ₂ with KN(SiMe ₃ ) ₂ , proceeds cleanly to the desired bridging phosphinidiide or arsinidiide complex, [{(C ₅ Me ₅ ) ₂ Th(μ ₂ ‐ETipp)(μ ₂ ‐EHTipp)}K] ₂ under ambient conditions. In the absence of a chelating agent, the potassium cation of one monomeric unit interacts with the aryl ring of a second monomer to form a bridged dimer. In the presence of 2,2,2‐cryptand, the terminal phosphinidene complex, [(C ₅ Me ₅ ) ₂ Th=PTipp(PHTipp)][K(2,2,2‐cryptand)] is isolated. Using X‐ray crystallographic analysis, we have determined these complexes display the shortest Th−P and Th−As bond lengths reported.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC-0014174

OSTI ID:: 1407832

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Vol. 23 Journal Issue: 66; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 28 works

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