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Title: On the nanosecond proton dynamics in phosphoric acid–benzimidazole and phosphoric acid–water mixtures

Abstract

Combining 1H-NMR, 17O-NMR, and high-resolution backscattering QENS hydrodynamic and structural proton transport in phosphoric acid is separated. The rate limiting steps for structural proton diffusion in mixtures of acid with Brønsted bases are found to occur below the nanosecond timescale.

Authors:
ORCiD logo [1]; ORCiD logo [2]
  1. Max Planck Inst. for Solid State Research, Stuttgart (Germany)
  2. Inst. Laue-Langevin (ILL), Grenoble (France)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1407718
Grant/Contract Number:
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 19; Journal Issue: 42; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Melchior, Jan-Patrick, and Frick, Bernhard. On the nanosecond proton dynamics in phosphoric acid–benzimidazole and phosphoric acid–water mixtures. United States: N. p., 2017. Web. doi:10.1039/C7CP04116K.
Melchior, Jan-Patrick, & Frick, Bernhard. On the nanosecond proton dynamics in phosphoric acid–benzimidazole and phosphoric acid–water mixtures. United States. doi:10.1039/C7CP04116K.
Melchior, Jan-Patrick, and Frick, Bernhard. Fri . "On the nanosecond proton dynamics in phosphoric acid–benzimidazole and phosphoric acid–water mixtures". United States. doi:10.1039/C7CP04116K. https://www.osti.gov/servlets/purl/1407718.
@article{osti_1407718,
title = {On the nanosecond proton dynamics in phosphoric acid–benzimidazole and phosphoric acid–water mixtures},
author = {Melchior, Jan-Patrick and Frick, Bernhard},
abstractNote = {Combining1H-NMR,17O-NMR, and high-resolution backscattering QENS hydrodynamic and structural proton transport in phosphoric acid is separated. The rate limiting steps for structural proton diffusion in mixtures of acid with Brønsted bases are found to occur below the nanosecond timescale.},
doi = {10.1039/C7CP04116K},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 42,
volume = 19,
place = {United States},
year = {Fri Sep 22 00:00:00 EDT 2017},
month = {Fri Sep 22 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
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