skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Selective epoxidation of cyclohexene with molecular oxygen on catalyst of nanoporous Au integrated with MoO3 nanoparticles

Journal Article · · Applied Catalysis. A, General

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0012573
OSTI ID:
1405509
Journal Information:
Applied Catalysis. A, General, Journal Name: Applied Catalysis. A, General Vol. 529 Journal Issue: C; ISSN 0926-860X
Publisher:
ElsevierCopyright Statement
Country of Publication:
Netherlands
Language:
English
Citation Metrics:
Cited by: 23 works
Citation information provided by
Web of Science

References (56)

Reactions of Gold(III) Oxo Complexes with Cyclic Alkenes journal October 2005
Integrated Networks of Mesoporous Silica Nanowires and Their Bifunctional Catalysis–Sorption Application for Oxidative Desulfurization journal December 2013
An efficient biomimetic Fe-catalyzed epoxidation of olefins using hydrogen peroxide journal January 2007
Recent advances in the synthesis and catalytic applications of ligand-protected, atomically precise metal nanoclusters journal September 2016
Targeted Synthesis of Silicomolybdic Acid (Keggin Acid) inside Mesoporous Silica Hollow Spheres for Friedel–Crafts Alkylation journal September 2012
Activities and stabilities of heterogeneous catalysts in selective liquid phase oxidations: recent developments journal April 2001
Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates journal September 2005
Epoxidation of alkenes with molecular oxygen catalyzed by a manganese porphyrin-based metal–organic framework journal January 2015
PtMo Bimetallic Catalysts Synthesized by Controlled Surface Reactions for Water Gas Shift journal January 2016
Reverse Water–Gas Shift on Interfacial Sites Formed by Deposition of Oxidized Molybdenum Moieties onto Gold Nanoparticles journal August 2015
Highly efficient aerobic oxidation of alkenes over unsupported nanogold journal January 2010
Olefin Epoxidation with Inorganic Peroxides. Solutions to Four Long-Standing Controversies on the Mechanism of Oxygen Transfer journal September 2004
Preparation of SnO 2 /graphene nanocomposite and its application to the catalytic epoxidation of alkenes with H 2 O 2 journal January 2015
Tunable Metal/Silicon Hybrid Dots Catalysts for Hydrocarbon Selective Oxidation journal September 2012
Epoxidation of olefins with molecular oxygen as the oxidant using gold catalysts supported on polyoxometalates journal January 2014
Formation of TiO 2 Nanoparticles by Reactive-Layer-Assisted Deposition and Characterization by XPS and STM journal July 2005
Soft, Oxidative Stripping of Alkyl Thiolate Ligands from Hydroxyapatite-Supported Gold Nanoclusters for Oxidation Reactions journal December 2015
Initiator-free hydrocarbon oxidation using supported gold nanoparticles journal January 2014
Oxidation of benzylic compounds by gold nanowires at 1 atm O 2 journal January 2011
Superior catalytic properties in aerobic oxidation of olefins over Au nanoparticles on pyrrolidone-modified SBA-15 journal July 2011
Establishing a Au Nanoparticle Size Effect in the Oxidation of Cyclohexene Using Gradually Changing Au Catalysts journal November 2013
Determination of Organic Peroxides by Iodine Liberation Procedures. journal January 1964
A direct method for ultrafine gold networks with nanometre scale ligaments journal January 2011
Surface area and pore size characteristics of nanoporous gold subjected to thermal, mechanical, or surface modification studied using gas adsorption isotherms, cyclic voltammetry, thermogravimetric analysis, and scanning electron microscopy journal January 2012
Gold on thiol-functionalized magnetic mesoporous silica sphere catalyst for the aerobic oxidation of olefins journal October 2014
Ductile-brittle transition in random porous Au journal February 1992
Mesoporous TUD-1 supported indium oxide nanoparticles for epoxidation of styrene using molecular O 2 journal January 2015
Tunable gold catalysts for selective hydrocarbon oxidation under mild conditions journal October 2005
Stabilizing a Platinum 1 Single-Atom Catalyst on Supported Phosphomolybdic Acid without Compromising Hydrogenation Activity journal May 2016
Oxidation of Olefins with Hydrogen Peroxide Catalyzed by Bismuth Salts: A Mechanistic Study journal May 2015
Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation journal January 2014
Immobilized Cu(ii) and Co(ii) salen complexes on graphene oxide and their catalytic activity for aerobic epoxidation of styrene journal January 2013
The direct epoxidation of higher olefins using molecular oxygen journal November 2001
Highly efficient room-temperature oxidation of cyclohexene and d-glucose over nanogold Au/SiO2 in water journal November 2012
The Formation of Byproducts in the Autoxidation of Cyclohexane journal January 2007
Highly selective epoxidation of styrene using a transition metal–aluminium( iii ) complex containing the [MeAl(2-py) 3 ] anion (2-py = 2-pyridyl) journal January 2005
Catalytic Epoxidation of Cyclohexene with Tert-butylhydroperoxide Using an Immobilized Molybdenum Catalyst journal March 2015
Effect of thermal coarsening on the thermal conductivity of nanoporous gold journal March 2012
Catalysis by Unsupported Skeletal Gold Catalysts journal November 2013
Mechanistic Studies on the Roles of the Oxidant and Hydrogen Bonding in Determining the Selectivity in Alkene Oxidation in the Presence of Molybdenum Catalysts journal January 2013
Preparation of mesoporous titanosilicate with isolated Ti active centers for cyclohexene oxidation journal January 2015
Switchable Alkene Epoxidation/Oxidative Cleavage with H 2 O 2 /NaHCO 3 : Efficient Heterogeneous Catalysis Derived from Biosourced Eco-Mn journal October 2015
Selective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters journal August 2008
PtMo Alloy and MoO x @Pt Core−Shell Nanoparticles as Highly CO-Tolerant Electrocatalysts journal May 2009
Tuning the selectivity of a supported gold catalyst in solvent- and radical initiator-free aerobic oxidation of cyclohexene journal January 2014
Solvent-free allylic oxidation of alkenes with O2 mediated by Fe- and Cr-MIL-101 journal February 2013
Solvent-free oxidation of cyclohexene over catalysts Au/OMS-2 and Au/La-OMS-2 with molecular oxygen journal November 2010
Selective Oxidation of Styrene on an Oxygen-Covered Au(111) journal December 2005
Epoxidation of stilbene using supported gold nanoparticles: cumyl peroxyl radical activation at the gold nanoparticle surface journal January 2014
Different morphologies of silver nanoparticles as catalysts for the selective oxidation of styrene in the gas phase journal January 2004
Cyclohexane oxidation using Au/MgO: an investigation of the reaction mechanism journal January 2012
Transition-metal-free microporous and mesoporous catalysts for the epoxidation of cyclooctene with hydrogen peroxide journal October 2007
One-pot fabrication of yolk–shell nanospheres with ultra-small Au nanoparticles for catalysis journal January 2015
Heterogeneous Catalysts for Liquid-Phase Oxidations:  Philosophers' Stones or Trojan Horses? journal August 1998
Synthesis and characterization of Au nanocatalyst on modifed bentonite and silica and their applications for solvent free oxidation of cyclohexene with molecular oxygen journal September 2015
Cyclohexene Epoxidation with Cyclohexyl Hydroperoxide: A Catalytic Route to Largely Increase Oxygenate Yield from Cyclohexane Oxidation journal August 2011

Similar Records

Selective epoxidation of cyclohexene with molecular oxygen on catalyst of nanoporous Au integrated with MoO3 nanoparticles
Journal Article · Sun Jan 01 00:00:00 EST 2017 · Applied Catalysis. A, General · OSTI ID:1405509

A dimeric molecular precursor [(tBuO)2Ti mu-O2Si[OSi(OtBu)3]2]2to Ti(IV)/SiO2 catalysts for selective cyclohexene epoxidation
Journal Article · Wed Apr 20 00:00:00 EDT 2005 · Journal of Molecular Catalysis A: Chemical · OSTI ID:1405509

Oxidation of Cyclohexene Catalyzed by Nanoporous Au(Ag) in Liquid Phase
Journal Article · Thu Dec 22 00:00:00 EST 2016 · Catalysis Letters · OSTI ID:1405509

Related Subjects