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Title: Recent advances in understanding secondary organic aerosol: Implications for global climate forcing: Advances in Secondary Organic Aerosol

Journal Article · · Reviews of Geophysics (1985)
DOI:https://doi.org/10.1002/2016RG000540· OSTI ID:1392240
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [5];  [6]; ORCiD logo [1];  [7]; ORCiD logo [8];  [9];  [10]; ORCiD logo [1];  [11]; ORCiD logo [12]; ORCiD logo [13]; ORCiD logo [4]; ORCiD logo [14]; ORCiD logo [15];  [6] more »;  [16]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [17] « less
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  2. Univ. of California, Davis, CA (United States). Dept. of Civil and Environmental Engineering
  3. Univ. of California, Berkeley, CA (United States). Dept. of Environmental Science, Policy and Management and Dept. of Civil and Environmental Engineering
  4. Univ. of California, Irvine, CA (United States). Dept. of Earth System Science
  5. Univ. of Colorado, Boulder, CO (United States). Cooperative Inst. for Research in Environmental Sciences, Dept. of Chemistry and Biochemistry
  6. Brookhaven National Lab. (BNL), Upton, NY (United States)
  7. Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences, Dept. of Earth and Planetary Sciences
  8. Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemical and Biomolecular Engineering, School of Earth and Atmospheric Sciences
  9. Univ. of Helsinki (Finland). Dept. of Physics
  10. Colorado State Univ., Fort Collins, CO (United States). Dept. of Atmospheric Science
  11. Lund Univ. (Sweden). Dept. of Physics
  12. California Inst. of Technology (CalTech), Pasadena, CA (United States). Division of Chemistry and Chemical Engineering
  13. Pacific Northwest National Laboratory, Richland Washington USA
  14. Univ. of Washington, Seattle, WA (United States). Dept. of Atmospheric Sciences
  15. Cooperative Institute for Research in Environmental Sciences and Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder Colorado USA
  16. Aerodyne Research, Inc., Billerica, MA (United States)
  17. Univ. of California, Davis, CA (United States). Dept. of Environmental Toxicology

Abstract Anthropogenic emissions and land use changes have modified atmospheric aerosol concentrations and size distributions over time. Understanding preindustrial conditions and changes in organic aerosol due to anthropogenic activities is important because these features (1) influence estimates of aerosol radiative forcing and (2) can confound estimates of the historical response of climate to increases in greenhouse gases. Secondary organic aerosol (SOA), formed in the atmosphere by oxidation of organic gases, represents a major fraction of global submicron‐sized atmospheric organic aerosol. Over the past decade, significant advances in understanding SOA properties and formation mechanisms have occurred through measurements, yet current climate models typically do not comprehensively include all important processes. This review summarizes some of the important developments during the past decade in understanding SOA formation. We highlight the importance of some processes that influence the growth of SOA particles to sizes relevant for clouds and radiative forcing, including formation of extremely low volatility organics in the gas phase, acid‐catalyzed multiphase chemistry of isoprene epoxydiols, particle‐phase oligomerization, and physical properties such as volatility and viscosity. Several SOA processes highlighted in this review are complex and interdependent and have nonlinear effects on the properties, formation, and evolution of SOA. Current global models neglect this complexity and nonlinearity and thus are less likely to accurately predict the climate forcing of SOA and project future climate sensitivity to greenhouse gases. Efforts are also needed to rank the most influential processes and nonlinear process‐related interactions, so that these processes can be accurately represented in atmospheric chemistry‐climate models.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
Grant/Contract Number:
SC0012704; AC05-76RL01830; DE‐AC05‐76RL01830
OSTI ID:
1392240
Alternate ID(s):
OSTI ID: 1402338
Report Number(s):
BNL-114255-2017-JA; R&D Project: 2016-BNL-EE630EECA-Budg; KP1701000
Journal Information:
Reviews of Geophysics (1985), Vol. 55, Issue 2; ISSN 8755-1209
Publisher:
American Geophysical Union (AGU)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 426 works
Citation information provided by
Web of Science

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Oligomer and SOA formation through aqueous phase photooxidation of methacrolein and methyl vinyl ketone journal March 2012
Inferring absorbing organic carbon content from AERONET data journal January 2011
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Mass spectrometric approaches for chemical characterisation of atmospheric aerosols: critical review of the most recent advances journal January 2012
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Isoprene nitrates: preparation, separation, identification, yields, and atmospheric chemistry journal January 2010
Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO 3 Oxidation of Biogenic Hydrocarbons journal October 2014
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Rainforest Aerosols as Biogenic Nuclei of Clouds and Precipitation in the Amazon journal September 2010
Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 1: measurement and simulation of organic aerosol evolution journal January 2009
Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds journal January 2014
Molecular characterization of brown carbon (BrC) chromophores in secondary organic aerosol generated from photo-oxidation of toluene journal January 2015
Evidence for ambient dark aqueous SOA formation in the Po Valley, Italy journal January 2016
Oligomer formation within secondary organic aerosols: equilibrium and dynamic considerations journal January 2014
Effect of varying experimental conditions on the viscosity of α -pinene derived secondary organic material journal January 2016
Secondary Organic Aerosol Formation by Glyoxal Hydration and Oligomer Formation:  Humidity Effects and Equilibrium Shifts during Analysis journal November 2005
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The effect of physical and chemical aerosol properties on warm cloud droplet activation journal January 2006
A two-dimensional volatility basis set: 1. organic-aerosol mixing thermodynamics journal January 2011
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Aqueous Processing of Atmospheric Organic Particles in Cloud Water Collected via Aircraft Sampling journal June 2015
A product study of the OH radical-initiated oxidation of isoprene: formation of C5-unsaturated diols journal January 2000
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene journal August 2009
Heterogeneous Reactions of Glyoxal on Particulate Matter:  Identification of Acetals and Sulfate Esters journal March 2005
An absorption model of the gas/aerosol partitioning involved in the formation of secondary organic aerosol journal January 2007
Vapor–Wall Deposition in Chambers: Theoretical Considerations journal August 2014
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Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation journal July 2015
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Global modeling of secondary organic aerosol formation from aromatic hydrocarbons: high- vs. low-yield pathways journal January 2008
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Secondary organic aerosol formation from the β-pinene+NO 3 system: effect of humidity and peroxy radical fate journal January 2015
On the link between hygroscopicity, volatility, and oxidation state of ambient and water-soluble aerosol in the Southeastern United States journal January 2014
A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution journal January 2012
Secondary organic aerosol formation and primary organic aerosol oxidation from biomass-burning smoke in a flow reactor during FLAME-3 journal January 2013
Thermodynamics of the formation of atmospheric organic particulate matter by accretion reactions—Part 3: Carboxylic and dicarboxylic acids journal November 2006
Formation of Light Absorbing Organo-Nitrogen Species from Evaporation of Droplets Containing Glyoxal and Ammonium Sulfate journal November 2013
Global distribution and climate forcing of carbonaceous aerosols journal January 2002
Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes: UBIQUITY AND DOMINANCE OF OXYGENATED OA journal July 2007
Nonequilibrium atmospheric secondary organic aerosol formation and growth journal January 2012
Explicit modelling of SOA formation from α-pinene photooxidation: sensitivity to vapour pressure estimation journal January 2011
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  • Connolly, P. J.; Choularton, T. W.; Gallagher, M. W.
  • Quarterly Journal of the Royal Meteorological Society, Vol. 132, Issue 621C https://doi.org/10.1256/qj.05.86
journal October 2006
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The AeroCom evaluation and intercomparison of organic aerosol in global models journal January 2014
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High formation of secondary organic aerosol from the photo-oxidation of toluene journal January 2009
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Examining the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol formation during the 2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee ground site journal January 2015
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Chemical characterization of SOA formed from aqueous-phase reactions of phenols with the triplet excited state of carbonyl and hydroxyl radical journal January 2014
Direct kinetics study of the product-forming channels of the reaction of isoprene-derived hydroxyperoxy radicals with NO journal January 2007
Molecular Composition and Volatility of Organic Aerosol in the Southeastern U.S.: Implications for IEPOX Derived SOA journal February 2016
Gas Phase Production and Loss of Isoprene Epoxydiols journal February 2014
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere journal January 2011
Secondary organic aerosol formation in cloud and fog droplets: a literature evaluation of plausibility journal January 2000
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Organic aerosol formation photo-enhanced by the formation of secondary photosensitizers in aerosols journal January 2013
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Experimental Observation of Strongly Bound Dimers of Sulfuric Acid: Application to Nucleation in the Atmosphere journal June 2011
Properties and evolution of biomass burning organic aerosol from Canadian boreal forest fires journal January 2015
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Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere journal January 2015
Diagnosis of Aged Prescribed Burning Plumes Impacting an Urban Area journal March 2008
Airborne observations of IEPOX-derived isoprene SOA in the Amazon during SAMBBA journal January 2014
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Ion-induced nucleation of pure biogenic particles journal May 2016
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Aerosol Wall Losses in Electrically Charged Chambers journal January 1985
An absorption model of the gas/aerosol partitioning involved in the formation of secondary organic aerosol journal January 1994
Synergy between Secondary Organic Aerosols and Long-Range Transport of Polycyclic Aromatic Hydrocarbons journal November 2012
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  • Keskinen, H.; Virtanen, A.; Joutsensaari, J.
  • NUCLEATION AND ATMOSPHERIC AEROSOLS: 19th International Conference, AIP Conference Proceedings https://doi.org/10.1063/1.4803260
conference January 2013
Analysis of the growth of nucleation mode particles observed in Boreal forest journal November 1998
Über die Konstitution der Salzlösungen auf Grund ihres Verhaltens zu Kohlensäure journal January 1889
High formation of secondary organic aerosol from the photo-oxidation of toluene text January 2009
Seasonal characterization of submicron aerosol chemical composition and organic aerosol sources in the southeastern United States: Atlanta, Georgia,and Look Rock, Tennessee text January 2016
The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US journal January 2015
Emission factors for open and domestic biomass burning for use in atmospheric models journal January 2010
Examining the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol formation during the 2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee, ground site journal January 2015
On-line derivatization for hourly measurements of gas- and particle-phase Semi-Volatile oxygenated organic compounds by Thermal desorption Aerosol Gas chromatography (SV-TAG) journal January 2014
Diurnal cycle of fossil and nonfossil carbon using radiocarbon analyses during CalNex text January 2014
Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010 text January 2015
Quantification of the volatility of secondary organic compounds in ultrafine particles during nucleation events journal January 2011
A review of Secondary Organic Aerosol (SOA) formation from isoprene journal January 2009
Isoprene Epoxydiols as Precursors to Secondary Organic Aerosol Formation: Acid-Catalyzed Reactive Uptake Studies with Authentic Compounds text January 2012
Aerosol indirect effects - general circulation model intercomparison and evaluation with satellite data text January 2009
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations text January 2011
In situ vertical profiles of aerosol extinction, mass, and composition over the southeast United States during SENEX and SEAC4RS: observations of a modest aerosol enhancement aloft text January 2015
Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds journal January 2015
Epoxide as a precursor to secondary organic aerosol formation from isoprene photooxidation in the presence of nitrogen oxides text January 2013
Evaluation of regional isoprene emission factors and modeled fluxes in California journal January 2016
Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols journal January 2006

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