Pseudocapacitive Charge Storage in Thick Composite MoS2 Nanocrystal-Based Electrodes

Cook, John B.; Kim, Hyung-Seok; Lin, Terri C.; Lai, Chun-Han; Dunn, Bruce; Tolbert, Sarah H.

doi:10.1002/aenm.201601283

Title: Pseudocapacitive Charge Storage in Thick Composite MoS₂ Nanocrystal-Based Electrodes

Journal Article · Fri Oct 07 00:00:00 EDT 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201601283· OSTI ID:1533064

Cook, John B. ^[1]; Kim, Hyung-Seok ^[1]; Lin, Terri C. ^[1]; Lai, Chun-Han ^[1]; Dunn, Bruce ^[1]; Tolbert, Sarah H. ^[1]

UCLA, Los Angeles, CA (United States)

A synthesis methodology is demonstrated to produce MoS₂ nanoparticles with an expanded atomic lamellar structure that are ideal for Faradaic–based capacitive charge storage. While much of the work on MoS₂ focuses on the high capacity conversion reaction, that process is prone to poor reversibility. The pseudocapacitive intercalation–based charge storage reaction of MoS₂ is investigated, which is extremely fast and highly reversible. A major challenge in the field of pseudocapacitive–based energy storage is the development of thick electrodes from nanostructured materials that can sustain the fast inherent kinetics of the active nanocrystalline material. Here a composite electrode comprised of a poly(acrylic acid) binder, carbon fibers, and carbon black additives is utilized. Here, these electrodes deliver a specific capacity of 90 mAh g^–1 in less than 20 s and can be cycled 3000 times while retaining over 80% of the original capacity. Quantitative kinetic analysis indicates that over 80% of the charge storage in these MoS₂ nanocrystals is pseudocapacitive. Asymmetric full cell devices utilizing a MoS₂ nanocrystal–based electrode and an activated carbon electrode achieve a maximum power density of 5.3 kW kg^–1 (with 6 Wh kg^–1 energy density) and a maximum energy density of 37 Wh kg^–1 (with 74 W kg^–1 power density).

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Research Organization:: Univ. of California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0014213

OSTI ID:: 1533064

Alternate ID(s):: OSTI ID: 1401883

Journal Information:: Advanced Energy Materials, Vol. 7, Issue 2; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 218 works

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Design of Carbon/Metal Oxide Hybrids for Electrochemical Energy Storage Fleischmann, Simon; Tolosa, Aura; Presser, Volker Chemistry - A European Journal, Vol. 24, Issue 47 https://doi.org/10.1002/chem.201800772	journal	June 2018
Targeted Construction of Amorphous MoS _x with an Inherent Chain Molecular Structure for Improved Pseudocapacitive Lithium‐Ion Response Wang, Yao‐Yao; Fan, Hong‐Hong; Wang, Zhi‐Wei Chemistry – A European Journal, Vol. 25, Issue 66 https://doi.org/10.1002/chem.201903585	journal	October 2019
MoS ₂ /MoO _x -Nanostructure-Decorated Activated Carbon Cloth for Enhanced Supercapacitor Performance Sari, Fitri Nur Indah; Ting, Jyh-Ming ChemSusChem, Vol. 11, Issue 5 https://doi.org/10.1002/cssc.201702295	journal	February 2018
Surface‐Confined SnS ₂ @C@rGO as High‐Performance Anode Materials for Sodium‐ and Potassium‐Ion Batteries Li, Deping; Sun, Qing; Zhang, Yamin ChemSusChem, Vol. 12, Issue 12 https://doi.org/10.1002/cssc.201900719	journal	May 2019
Bi‐Metal (Zn, Mn) Metal–Organic Framework–Derived ZnMnO ₃ Micro‐Sheets Wrapped Uniformly with Polypyrrole Conductive Network toward High‐Performance Li‐Ion Batteries Sun, Xuan; Zhang, Yanru; Zhang, Jinyang Energy Technology, Vol. 8, Issue 3 https://doi.org/10.1002/ente.201901218	journal	December 2019
In‐situ Grown SnO ₂ Nanospheres on Reduced GO Nanosheets as Advanced Anodes for Lithium‐ion Batteries Wang, Zhen; Chen, Lei; Feng, Jingjie ChemistryOpen, Vol. 8, Issue 6 https://doi.org/10.1002/open.201900120	journal	May 2019
A Pseudolayered MoS ₂ as Li-Ion Intercalation Host with Enhanced Rate Capability and Durability Gong, Shan; Zhao, Guangyu; Lyu, Pengbo Small, Vol. 14, Issue 48 https://doi.org/10.1002/smll.201803344	journal	October 2018
A Flexible Film toward High‐Performance Lithium Storage: Designing Nanosheet‐Assembled Hollow Single‐Hole Ni–Co–Mn–O Spheres with Oxygen Vacancy Embedded in 3D Carbon Nanotube/Graphene Network Li, Sesi; Zhao, Xuebing; Feng, Yuzhang Small, Vol. 15, Issue 27 https://doi.org/10.1002/smll.201901343	journal	April 2019
Advanced Materials for Sodium‐Ion Capacitors with Superior Energy–Power Properties: Progress and Perspectives Zhang, Hongwei; Hu, Mingxiang; Lv, Qian Small, Vol. 16, Issue 15 https://doi.org/10.1002/smll.201902843	journal	September 2019
Metal Chalcogenides: Paving the Way for High‐Performance Sodium/Potassium‐Ion Batteries Tan, Huiteng; Feng, Yuezhan; Rui, Xianhong Small Methods, Vol. 4, Issue 1 https://doi.org/10.1002/smtd.201900563	journal	October 2019
Holey graphene-wrapped porous TiNb24O62 microparticles as high-performance intercalation pseudocapacitive anode materials for lithium-ion capacitors Li, Shaohui; Chen, Jingwei; Gong, Xuefei NPG Asia Materials, Vol. 10, Issue 5 https://doi.org/10.1038/s41427-018-0042-5	journal	May 2018
Achieving high energy density and high power density with pseudocapacitive materials Choi, Christopher; Ashby, David S.; Butts, Danielle M. Nature Reviews Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41578-019-0142-z	journal	October 2019
Insights into the intrinsic capacity of interlayer-expanded MoS ₂ as a Li-ion intercalation host Gong, Shan; Zhao, Guangyu; Lyu, Pengbo Journal of Materials Chemistry A, Vol. 7, Issue 3 https://doi.org/10.1039/c8ta08120d	journal	January 2019
Heterostructures of Ni–Co–Al layered double hydroxide assembled on V ₄ C ₃ MXene for high-energy hybrid supercapacitors Wang, Xin; Li, Hui; Li, Han Journal of Materials Chemistry A, Vol. 7, Issue 5 https://doi.org/10.1039/c8ta11249e	journal	January 2019
Improved electrochemical performance of 2D accordion-like MnV ₂ O ₆ nanosheets as anode materials for Li-ion batteries Zhang, Xiaoyu; Li, Xinjian; Jiang, Fuyi Dalton Transactions, Vol. 49, Issue 6 https://doi.org/10.1039/c9dt03845k	journal	January 2020
An amorphous Zn–P/graphite composite with chemical bonding for ultra-reversible lithium storage Li, Wenwu; Yu, Jiale; Wen, Jiajun Journal of Materials Chemistry A, Vol. 7, Issue 28 https://doi.org/10.1039/c9ta01431d	journal	January 2019
Sulfur covalently bonded to porous graphitic carbon as an anode material for lithium-ion capacitors with high energy storage performance Sun, Yue; Ma, Junpeng; Yang, Xinyue Journal of Materials Chemistry A, Vol. 8, Issue 1 https://doi.org/10.1039/c9ta09347h	journal	January 2020
A Facile Synthesis of MoS2/g-C3N4 Composite as an Anode Material with Improved Lithium Storage Capacity Tran Huu, Ha; Nguyen Thi, Xuan Dieu; Nguyen Van, Kim Materials, Vol. 12, Issue 11 https://doi.org/10.3390/ma12111730	journal	May 2019
In-Plane Assembled Orthorhombic Nb ₂ O ₅ Nanorod Films with High-Rate Li ⁺ Intercalation for High-Performance Flexible Li-Ion Capacitors Deng, Bohua; Lei, Tianyu; Zhu, Weihua Advanced Functional Materials, Vol. 28, Issue 1 https://doi.org/10.1002/adfm.201704330	journal	November 2017
Controllable Design of MoS ₂ Nanosheets Anchored on Nitrogen-Doped Graphene: Toward Fast Sodium Storage by Tunable Pseudocapacitance Xu, Xin; Zhao, Ruisheng; Ai, Wei Advanced Materials, Vol. 30, Issue 27 https://doi.org/10.1002/adma.201800658	journal	May 2018
Rational Design of Nickel Hydroxide-Based Nanocrystals on Graphene for Ultrafast Energy Storage Zhao, Bote; Zhang, Lei; Zhang, Qiaobao Advanced Energy Materials, Vol. 8, Issue 9 https://doi.org/10.1002/aenm.201702247	journal	December 2017
Size‐Independent Fast Ion Intercalation in Two‐Dimensional Titania Nanosheets for Alkali‐Metal‐Ion Batteries Yang, Jinlin; Xiao, Xu; Gong, Wenbin Angewandte Chemie International Edition, Vol. 58, Issue 26 https://doi.org/10.1002/anie.201902478	journal	June 2019
Chemical Mass Production of MoS 2 /Graphene van der Waals Heterostructure as a High‐Performance Li‐ion Intercalation Host Gong, Shan; Zhao, Guangyu; Zhang, Naiqing ChemElectroChem, Vol. 6, Issue 13 https://doi.org/10.1002/celc.201900783	journal	July 2019
Two‐Dimensional Germanium Sulfide Nanosheets as an Ultra‐Stable and High Capacity Anode for Lithium Ion Batteries Wang, Bo; Du, Wencheng; Yang, Yang Chemistry – A European Journal, Vol. 26, Issue 29 https://doi.org/10.1002/chem.201904116	journal	November 2019
High-performance sodium-ion hybrid capacitors based on an interlayer-expanded MoS2/rGO composite: surpassing the performance of lithium-ion capacitors in a uniform system Zhan, Changzhen; Liu, Wei; Hu, Mingxiang NPG Asia Materials, Vol. 10, Issue 8 https://doi.org/10.1038/s41427-018-0073-y	journal	August 2018
Cellular carbon-wrapped FeSe ₂ nanocavities with ultrathin walls and multiple rooms for ion diffusion-confined ultrafast sodium storage Tang, Yongchao; Zhao, Zongbin; Hao, Xiaojuan Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/c8ta10614b	journal	January 2019
Towards fast-charging technologies in Li ⁺ /Na ⁺ storage: from the perspectives of pseudocapacitive materials and non-aqueous hybrid capacitors Huang, Haijian; Niederberger, Markus Nanoscale, Vol. 11, Issue 41 https://doi.org/10.1039/c9nr05732c	journal	January 2019
Tunable pseudocapacitive contribution by dimension control in nanocrystalline-constructed (Mg _0.2 Co _0.2 Ni _0.2 Cu _0.2 Zn _0.2 )O solid solutions to achieve superior lithium-storage properties Chen, Hong; Qiu, Nan; Wu, Baozhen RSC Advances, Vol. 9, Issue 50 https://doi.org/10.1039/c9ra05508h	journal	January 2019
Approaching the Lithiation Limit of MoS ₂ While Maintaining Its Layered Crystalline Structure to Improve Lithium Storage Zhu, Zhiqiang; Tang, Yuxin; Leow, Wan Ru Angewandte Chemie, Vol. 131, Issue 11 https://doi.org/10.1002/ange.201813698	journal	February 2019
Scalable Epitaxial Growth of WSe2 Thin Films on SiO2/Si via a Self-Assembled PtSe2 Buffer Layer Wu, Pei-Chen; Yang, Chun-Liang; Du, Yuanmin Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-44518-3	journal	May 2019
Design of Carbon/Metal Oxide Hybrids for Electrochemical Energy Storage Fleischmann, Simon; Tolosa, Aura; Presser, Volker Universität des Saarlandes https://doi.org/10.22028/d291-29131	collection	January 2018
Noncovalent Approach to Liquid-Crystalline Ion Conductors: High-Rate Performances and Room-Temperature Operation for Li-Ion Batteries Onuma, Taira; Hosono, Eiji; Takenouchi, Motokuni ACS Omega, Vol. 3, Issue 1 https://doi.org/10.1021/acsomega.7b01503	journal	January 2018

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